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• Kevin Hurtado Veliz

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UNIFAC HURTADO VELIZ ,Antonio Kevin ACETATO DE ETILO(1)+ETANOL(2) T=60°C 1. GRUPOS FUNCIONALES SUB GRUPO

K

CH3 CH2 COO OH

Rk 1 2 3 4

Vk1 (acetato de etilo)

Qk

0.9011 0.6744 1.38 1

0.848 0.54 1.2 1.2

Vk2 (etanol) 2 1 1 0

1 1 0 1

2. PARAMETROS DE INTERACCION BANARI SUB GRUPO CH3 CH2 OH COO

X1

CH3 GRUPO PRINC 1 1 5 41

X2 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95

CH2 1 0 0 156.4 529

r1 0.95 0.9 0.85 0.8 0.75 0.7 0.65 0.6 0.55 0.5 0.45 0.4 0.35 0.3 0.25 0.2 0.15 0.1 0.05

OH 1 0 0 156.4 529

5 986.5 986.5 0 88.63

41 387.1 387.1 190.3 0

3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436 3.436

PARTE COMBINATORIAL F1 2.588 2.449225 2.588 2.32795 2.588 2.211675 2.588 2.1004 2.588 1.994125 2.588 1.89285 2.588 1.796575 2.588 1.7053 2.588 1.619025 2.588 1.53775 2.588 1.461475 2.588 1.3902 2.588 1.323925 2.588 1.26265 2.588 1.206375 2.588 1.1551 2.588 1.108825 2.588 1.06755 2.588 1.031275

q1

r2 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566 3.8566

COO

2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755 2.5755

q2

CALCULO DEL COEFICIENTE DE ACTIVIDAD PARA EL GRUPO k EN EL COMPONENTE i PURO X Y X11 0.5 X12 0.33333333 Y11 1 Y12 X21 0.25 X22 0.33333333 Y21 1 Y22 X31 0.25 X32 0 Y31 0.62534099 Y32 X41 0 X42 0.33333333 Y41 0.20435976 Y42 CALCULOS PREVIOS PARA COEFICIENTE DE AC Q 0.49359721 Q12 0.32766615 Q11 ��∑▒ 〖 Θ×Ψ 〗 0.15715949 Q22 0.20865533 Q21 0.34924331 Q32 0 r11 r12 Q31 0 Q42 0.46367852 0.8691528469 0.63107871 Q41 Producto 0.859 Producto 0.86266667 0.8691528469 0.63107871 0.3829267761 0.3831287 0.4008743521 0.63148219

Xm X1

X2 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95

X1

X2 0.05 0.1 0.15

Xm1 Xm2 Xm3 0.95 0.3442623 0.32786885 0.9 0.35483871 0.32258065 0.85 0.36507937 0.31746032 0.8 0.375 0.3125 0.75 0.38461538 0.30769231 0.7 0.39393939 0.3030303 0.65 0.40298507 0.29850746 0.6 0.41176471 0.29411765 0.55 0.42028986 0.28985507 0.5 0.42857143 0.28571429 0.45 0.43661972 0.28169014 0.4 0.44444444 0.27777778 0.35 0.45205479 0.2739726 0.3 0.45945946 0.27027027 0.25 0.46666667 0.26666667 0.2 0.47368421 0.26315789 0.15 0.48051948 0.25974026 0.1 0.48717949 0.25641026 0.05 0.49367089 0.25316456

lngC1 lngC2 lngR1 0.95 81.2915158 0.09108374 0.9 38.5497789 0.24127417 0.85 24.2150918 0.44844645

Xm4 0.05 0.31147541 0.1 0.29032258 0.15 0.26984127 0.2 0.25 0.25 0.23076923 0.3 0.21212121 0.35 0.19402985 0.4 0.17647059 0.45 0.15942029 0.5 0.14285714 0.55 0.12676056 0.6 0.11111111 0.65 0.09589041 0.7 0.08108108 0.75 0.06666667 0.8 0.05263158 0.85 0.03896104 0.9 0.02564103 0.95 0.01265823

3.05 3.1 3.15 3.2 3.25 3.3 3.35 3.4 3.45 3.5 3.55 3.6 3.65 3.7 3.75 3.8 3.85 3.9 3.95

DETERMINCAION DEL COEFICIENTE DE ACTIVIDAD lngR2 g1 0.47223708 0.01335466 38.38886805 0.38324434 0.04696519 14.77398457 0.32354524 0.09368369 7.834677672

0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95

0.8 0.75 0.7 0.65 0.6 0.55 0.5 0.45 0.4 0.35 0.3 0.25 0.2 0.15 0.1 0.05

17.0242478 12.7053818 9.82861518 7.77870556 6.24686084 5.0609155 4.11723492 3.34968933 2.71410519 2.17987433 1.72514899 1.33395264 0.99437003 0.69737248 0.43603099 0.20497351

0.71208938 1.03346601 1.41589304 1.86520191 2.39048231 3.00527979 3.72955539 4.59298757 5.64077542 6.94442113 8.62326125 10.8917098 14.1769869 19.47106 29.7330595 59.6641729

0.28540411 0.26331509 0.25327005 0.25229786 0.25816402 0.26916855 0.28400647 0.30166911 0.32137289 0.34250711 0.36459497 0.38726411 0.41022422 0.43324963 0.45616586 0.47883909

0 1

0 1

0.14869788 0.20869474 0.27135813 0.33505405 0.39862627 0.46125949 0.52238519 0.58161546 0.63869555 0.69346935 0.74585382 0.79582002 0.84337878 0.88856986 0.93145373 0.9721053

4.858790292 3.345518755 2.489293858 1.962550765 1.612714708 1.362239288 1.169321355 1.010497797 0.872239827 0.746622458 0.628980645 0.516591981 0.40791467 0.30213637 0.198902449 0.098149329

DATOS EXPERIMENTALES P (kPa) P(mmHg) X1 49.996 375.001875 48.196 361.500728 51.862 388.998065 54.795 410.997435 56.195 421.498327 59.262 444.502783 60.528 453.99859 62.128 465.99961 63.061 472.997705 63.195 474.00279 63.928 479.500758 64.128 481.000885 64.661 484.998725 64.595 484.503683 63.795 478.503173 63.728 478.00063 61.862 464.00444 59.262 444.502783 59.195 444.00024 REFERENCIA:

Y1 0.0435 0.024 0.0753 0.106 0.1441 0.1936 0.2459 0.313 0.38 0.414 0.4771 0.4989 0.5563 0.6721 0.7714 0.7714 0.8681 0.9405 0.9495

0.1151 0.0607 0.1509 0.227 0.274 0.32 0.3715 0.412 0.4706 0.5135 0.5375 0.5422 0.5756 0.6743 0.7111 0.7199 0.7977 0.89 0.8893

http://www.ddbst.com/en/EED/VLE/VLE%20Ethanol%3BEthyl%20acetate.p

van Winkle M.: Vapor-Liquid Equilibria for Binary Systems of Methanol, Ethyl Alcohol, 1-Propanol, and 2-Propanol with Ethyl A

CONSTANTES DE ANTONIE ACETATO DE ETILO (1) A B C 7.09808 1238.71 217 ETANOL (2) A B C 8.04494 1554.3 222.65 T (k)

333.15

RTE COMBINATORIAL F2 q1 1.09533 1.19566 1.30099 1.41132 1.52665 1.64698 1.77231 1.90264 2.03797 2.1783 2.32363 2.47396 2.62929 2.78962 2.95495 3.12528 3.30061 3.48094 3.66627

2.4611 2.3392 2.2223 2.1104 2.0035 1.9016 1.8047 1.7128 1.6259 1.544 1.4671 1.3952 1.3283 1.2664 1.2095 1.1576 1.1107 1.0688 1.0319

q2

I1 1.0743 1.1536 1.2379 1.3272 1.4215 1.5208 1.6251 1.7344 1.8487 1.968 2.0923 2.2216 2.3559 2.4952 2.6395 2.7888 2.9431 3.1024 3.2667

I2 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536 -0.7536

-1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638 -1.638

lngC1 lngC2 81.291515808 0.09108374 38.54977889 0.24127417 24.215091747 0.44844645 17.024247805 0.71208938 12.70538181 1.03346601 9.8286151792 1.41589304 7.7787055563 1.86520191 6.2468608433 2.39048231 5.0609155041 3.00527979 4.1172349178 3.72955539 3.3496893253 4.59298757 2.7141051852 5.64077542 2.1798743332 6.94442113 1.7251489927 8.62326125 1.3339526367 10.8917098 0.9943700297 14.1769869 0.6973724834 19.47106 0.436030985 29.7330595 0.2049735108 59.6641729

Y

1 Y13 0.051760466 Y14 0.3128789 1 Y23 0.051760466 Y24 0.3128789 0.62534099 Y33 1 Y34 0.56483921 0.20435976 Y43 0.766411291 Y44 1 ARA COEFICIENTE DE ACTIVIDAD PARA EL GRUPO k EN EL COMPONENTE i PURO

r11 r21 r31 r41 0.29196943 0.18592393 0.695599336 1.27452316 r12 r22 r32 r42 0.32286604 0.20559866 1.215833357 0.66208861

CALCULO DEL COEFICIENTE DE ACTIVIDAD PARA EL GRUPO k EN LA MEZCLA rk Qm r1 r2 r3 Qm1 Qm2 Qm3 Qm4 0.323382 0.19612116 0.066463282 0.41403356 0.9027541 0.3506912998 0.22331757 1.012999019 0.31892779 0.18462801 0.127188184 0.36925602 0.94348387 0.3773527225 0.24029537 0.853705645 0.31435755 0.17407001 0.182773516 0.32879892 0.9848254 0.4028458328 0.25652919 0.726786504 0.30971512 0.16435354 0.233747261 0.29218408 1.02675 0.4271910667 0.27203205 0.624452041 0.30503597 0.15539568 0.28057554 0.25899281 1.06923077 0.4504211541 0.28682479 0.541110105 0.30034874 0.14712293 0.323670445 0.22885789 1.11224242 0.472575032 0.30093221 0.472649886 0.29567643 0.13947001 0.36339687 0.20145669 1.15576119 0.4936947662 0.3143811 0.415989347 0.29103746 0.1323789 0.400078447 0.1765052 1.19976471 0.5138238956 0.32719918 0.368779168 0.28644644 0.12579788 0.434002702 0.15375297 1.24423188 0.5330064672 0.3394145 0.329203239 0.28191489 0.11968085 0.465425532 0.13297872 1.28914286 0.5512864212 0.35105503 0.295840716 0.27745177 0.11398657 0.494575083 0.11398657 1.33447887 0.5687071634 0.36214843 0.267568467 0.27306392 0.10867815 0.521655128 0.0966028 1.38022222 0.5853112503 0.37272179 0.243490718 0.26875648 0.10372248 0.546847989 0.08067304 1.42635616 0.6011401474 0.38280151 0.222887425 0.26453318 0.09908984 0.570317087 0.06605989 1.47286486 0.6162340442 0.39241319 0.205175805 0.26039656 0.09475347 0.59220916 0.05264081 1.51973333 0.6306317146 0.40158152 0.189881283 0.25634825 0.09068924 0.612656187 0.04030633 1.56694737 0.6443704148 0.41033022 0.176615289 0.25238907 0.08687538 0.631777084 0.02895846 1.61449351 0.6574858151 0.418682 0.165058108 0.24851925 0.0832922 0.649679171 0.01850938 1.66235897 0.6700119603 0.42665856 0.154945499 0.24473848 0.07992185 0.666459462 0.00888021 1.71053165 0.6819812536 0.43428052 0.146058188

FICIENTE DE ACTIVIDAD TOTAL Pvp1 Pvp2 p y1 y2 g2 0.00121639 422.865977 351.4899684 812.073481 0.99949983 0.0005001668 0.01133149 422.865977 351.4899684 628.326155 0.99429498 0.0057050206 0.04201212 422.865977 351.4899684 509.504606 0.97536467 0.0246353266

0.10588618 0.21567892 0.38421409 0.62494345 0.95290905 1.38621382 1.9482645 2.67135258 3.60273816 4.81574321 6.43169234 8.66784071 11.9565699 17.3013971 27.6949692 57.9998587

422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977 422.865977

351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684 351.4899684

440.697765 410.533247 410.324482 433.243462 473.747654 527.20223 589.630822 657.546961 727.834857 797.658702 864.384762 925.501644 978.517465 1020.78884 1049.14855 1058.74724

0.93243818 0.86150517 0.7696136 0.67043962 0.57580205 0.49169005 0.41930153 0.35741603 0.30405844 0.25727645 0.21539269 0.17702495 0.14102414 0.10638705 0.072152 0.03724101

0.067561823 0.1384948311 0.2303863953 0.3295603818 0.4241979471 0.5083099497 0.5806984658 0.6425839676 0.6959415645 0.7427235457 0.7846073085 0.8229750531 0.8589758556 0.8936129506 0.9278479961 0.9627589947

l%3BEthyl%20acetate.php

2-Propanol with Ethyl Acetate and 1-Propanol-Water. Ind.Eng.Chem. Chem.Eng.Data Series 3 (1958) 72-81

r4 0.62989909 0.61987041 0.62486197 0.64002807 0.6620021 0.68840419 0.71753149 0.7481565 0.77939183 0.81059704 0.84131317 0.87121582 0.900081 0.92775989 0.95416009 0.97923145 1.00295534 1.02533652 1.04639683

1 0.64567717 0.65855285 0.6699166 0.67995107 0.68881475 0.6966454 0.70356304 0.70967237 0.71506492 0.7198209 0.72401068 0.72769613 0.73093175 0.73376565 0.73624035 0.7383935 0.7402585 0.74186504 0.74323951

suma y producto de Q Y 2 3 0.64567717 0.410673 0.65855285 0.43625445 0.6699166 0.46004996 0.67995107 0.48221845 0.68881475 0.50290271 0.6966454 0.52223106 0.70356304 0.54031893 0.70967237 0.55727025 0.71506492 0.57317867 0.7198209 0.58812871 0.72401068 0.60219671 0.72769613 0.61545175 0.73093175 0.62795641 0.73376565 0.63976743 0.73624035 0.6509364 0.7383935 0.66151023 0.7402585 0.67153166 0.74186504 0.68103968 0.74323951 0.69006992

4 lngR1 lngR2 0.6141162 0.47223708 0.01335466 0.59864888 0.38324434 0.04696519 0.58485525 0.32354524 0.09368369 0.57253978 0.28540411 0.14869788 0.56153222 0.26331509 0.20869474 0.55168409 0.25327005 0.27135813 0.54286563 0.25229786 0.33505405 0.53496324 0.25816402 0.39862627 0.52787727 0.26916855 0.46125949 0.52152015 0.28400647 0.52238519 0.51581477 0.30166911 0.58161546 0.51069311 0.32137289 0.63869555 0.50609504 0.34250711 0.69346935 0.50196732 0.36459497 0.74585382 0.49826272 0.38726411 0.79582002 0.49493927 0.41022422 0.84337878 0.49195962 0.43324963 0.88856986 0.48929045 0.45616586 0.93145373 0.48690201 0.47883909 0.9721053

UNIFAC 1

0.9

Y1

0.8

0.7

0.6 EXPERIMENTAL TEORICO DIAGONAL

0.5

0.4

0.3

0.2

0.1

0

0

0.1

0.2

0.3

0.4

0.5

X1

0.6

0.7

0.8

0.9

1

UNIFAC 1200

1000

P

800

X TEORICO Y TEORICO X EXPERIMENTAL Y EXPERIMENTAL

600

400

200

0

0

0.1

0.2

0.3

0.4

0.5

X1-Y1

0.6

0.7

0.8

0.9

1