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• Diego Bastarrachea

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Capacidades caloríficas de los gases y cálculo del calor gan "Mass and energy balances" de R. V. Reklaiti Cp's en kJ/kgmol, T en K

Constantes para el cálculo de la capacidad calorífica de diferentes compuestos, en fase gaseosa. Selecci

También se puede calcular el calor necesario para calentar o enfriar un compuesto, desde una temperatura

Num. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

Compuesto ACENAPHTHYLENE ACETALDEHYDE ACETIC ACID ACETONE ACETONITRILE ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA ANILINE ARGON BENZENE BIPHENYL BROMINE BROMOBENZENE CARBÓN DIOXIDE CARBÓN DISULFIDE

a -4.23583E+01 2.45377E+01 6.89949E+00 2.31317E+01 2.44795E+01 2.64542E+01 2.18212E+01 1.07482E+01 2.75500E+01 -2.25594E+00 2.07723E+01 1.85868E+01 -8.31984E+01 3.36874E+01 7.49152E-01 1.90223E+01 3.30999E+01

b 7.31681E-01 7.60130E-02 2.57068E-01 1.62824E-01 8.91399E-02 1.83863E-01 9.20580E-02 2.20682E-01 2.56278E-02 3.07834E-01 0.00000E+00 -1.17439E-02 1.02502E+00 1.02992E-02 3.47418E-01 7.96291E-02 1.06167E-02

c -1.90463E-04 1.36254E-04 -1.91771E-04 8.01548E-05 3.50089E-05 -1.13740E-04 -6.52231E-05 -1.57773E-04 9.90042E-06 2.41742E-04 0.00000E+00 1.27514E-03 -7.22383E-04 -8.90254E-06 -1.06396E-05 -7.37067E-05 2.75934E-04

d -3.22290E-07 -1.99942E-07 7.57676E-08 -1.60497E-07 -8.43081E-08 1.92063E-08 1.81959E-08 4.84219E-08 -6.68639E-09 -5.37543E-07 0.00000E+00 -2.07984E-06 1.42495E-07 2.67924E-09 -2.47154E-07 3.74572E-08 -3.42168E-07

18

CARBÓN MONOXIDE

2.90063E+01

2.49235E-03

-1.86440E-05

4.79892E-08

19 20

CARBÓN TET CHLORINE

8.97631E+00 2.85463E+01

4.02004E-01 2.38795E-02

-7.51639E-04 -2.13631E-05

6.27332E-07 6.47263E-09

21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53

CHLOROACETYL-CL CHLOROBENZENE CHLOROFORM CHRYSENE CIS-2-BUTENE CIS-2-PENTENE CYCLOHEXANE CYCLOPENTANE C3ALKYLBENZENE C3ALKYLNAPHTHALENE DICHLOROACETYL-CL DYCYCLOPENTADIENE DIETHYL ETHER DIETHYL KETONE DIETHYLENE GLYCOL DIMETHYL ACETAMIDE DIMETHYL ETHER DIMETHYL SULFIDE DIMETHYLACETYLENE DIMETHYLFORMAMIDE ETHANE ETHANOL ETHYL ACETATE ETHYL CHLORIDE ETHYL FORMATE ETHYL MERCAPTAN ETHYLACETYLENE ETHYLAMINE ETHYLBENZENE ETHYLCYCLOHEXANE ETHYLCYCLOPENTANE ETHYLENE ETHYLENE GLYCOL

2.00366E+01 -2.77932E+00 3.18924E+01 -8.13533E+01 2.42404E+01 1.11806E+01 7.04449E+00 -1.91083E+00 2.97401E+01 6.44864E+01 1.42774E+01 -3.39777E+01 4.67637E+01 2.67448E+01 4.46173E+01 2.57501E+01 4.89030E+01 3.34317E+01 1.32380E+01 2.76199E+01 3.38339E+01 1.76907E+01 4.67922E+01 9.29967E+00 3.81020E+01 2.15857E+01 7.70702E+00 2.75175E+01 4.49950E+01 1.87681E+01 -2.90029E+02 1.68346E+01 3.58417E+01

3.05402E-01 3.57786E-01 1.44743E-01 1.09414E+00 7.09338E-02 2.65029E-01 1.30074E-01 1.30865E-01 7.04306E-01 7.84466E-01 4.26942E-01 8.06270E-01 1.00949E-01 2.45037E-01 1.44518E-01 2.82595E-01 -8.81692E-03 1.13437E-01 2.60623E-01 2.21170E-01 -1.55175E-02 1.49532E-01 1.72055E-01 2.08358E-01 1.62629E-01 1.76887E-01 3.05514E-01 6.26593E-02 -4.58883E-02 2.17024E-01 2.72203E+00 5.15193E-02 1.08695E-01

-3.86004E-04 -2.31480E-05 -1.11583E-04 -1.66278E-04 5.71217E-04 2.58923E-04 1.08205E-03 8.53142E-04 -7.62473E-04 -5.33115E-04 -6.58268E-04 -3.41494E-04 5.69049E-04 3.35630E-04 6.82006E-04 1.70219E-04 4.24399E-04 1.39993E-04 -1.66393E-04 1.12943E-04 3.76892E-04 8.94815E-05 3.25949E-04 -1.00742E-04 2.10144E-04 1.30300E-05 -2.21103E-04 3.91900E-04 1.83228E-03 1.43654E-03 -6.38788E-03 2.16352E-04 2.90598E-04

2.65736E-07 -2.40458E-07 3.07210E-08 -6.42055E-07 -8.38061E-07 -4.92368E-07 -1.54513E-06 -1.30863E-06 8.82742E-07 6.39615E-07 5.12266E-07 -1.67598E-07 -7.74108E-07 -5.81970E-07 -9.75239E-07 -4.03253E-07 -5.12852E-07 -2.41217E-07 7.84123E-08 -2.86931E-07 -4.11770E-07 -1.97384E-07 -5.20729E-07 1.66708E-08 -3.82964E-07 -1.19652E-07 9.09705E-08 -5.27782E-07 -2.91974E-06 -2.29923E-06 7.80748E-06 -3.45618E-07 -4.52216E-07

54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

ETHYLENE OXIDE FLUORANTHENE FLUORENE FORMALDEHYDE FURFURAL HYDROGEN HYDROGEN CHLORIDE HYDROGEN CYANIDE HYDROGEN IODIDE HYDROGEN SULFIDE INDAN INDENE IODOBENZENE ISO-BUTANE ISO-BUTANOL ISO-BUTENE ISO-BUTYRALDEHYDE ISO-PENTANE ISO-PROPANOL M-DICHLOROBENZENE M-XYLENE MEK METHACRYLONITRILE METHANE METHANOL METHYL ACETATE METHYL CHLORIDE METHYL FORMATE METHYL IODIDE METHYL PROPIONATE METHYLACETYLENE METHYLAMINE METHYLCYCLOHEXANE

1.79573E+01 -6.16536E+01 -2.49539E+01 3.28011E+01 2.52110E+01 1.76386E+01 3.03088E+01 2.08414E+01 3.02697E+01 3.45234E+01 -2.28836E+01 -1.68550E+01 2.91636E+00 5.29035E+01 5.61796E+01 1.82591E+01 2.86774E+01 4.19952E+01 8.51074E+00 -9.90706E+00 4.64153E+01 4.00296E+01 3.57055E+01 3.83870E+01 3.44925E+01 4.80207E+01 1.94308E+01 1.92655E+01 1.66024E+01 4.67921E+01 1.36761E+01 1.25367E+01 8.14527E+00

3.43445E-02 1.03453E+00 6.97984E-01 -3.78277E-03 2.21301E-01 6.70055E-02 -7.60900E-03 6.79258E-02 -1.03319E-02 -1.76481E-02 5.40798E-01 5.17234E-01 3.40319E-01 -1.07178E-01 -1.63172E-01 2.29492E-01 1.84132E-01 7.44763E-02 2.81060E-01 4.95077E-01 -4.69727E-03 1.77012E-01 1.66377E-01 -7.36639E-02 -2.91887E-02 1.12261E-01 5.96368E-02 1.47245E-01 1.04367E-01 1.72055E-01 1.94142E-01 1.51044E-01 2.27701E-01

3.51051E-04 -4.26744E-04 -3.24458E-06 4.71752E-05 1.30942E-04 -1.31485E-04 1.32608E-05 -6.94727E-05 2.59460E-05 6.76664E-05 1.03708E-04 -8.03445E-06 -7.86309E-07 1.38044E-03 1.26597E-03 1.01034E-04 2.76595E-04 1.02577E-03 1.92642E-05 -3.31770E-04 1.53345E-03 2.01659E-04 7.99044E-05 2.90981E-04 2.86844E-04 2.66821E-04 7.06089E-05 1.03166E-04 -3.60895E-05 3.25949E-04 -1.39014E-04 -6.88093E-05 1.12022E-03

-4.78345E-07 -2.51405E-07 -5.28857E-07 -3.60606E-08 -3.37155E-07 1.05883E-07 -4.33363E-09 4.01373E-08 -1.59529E-08 -5.32454E-08 -5.39048E-07 -3.75556E-07 -2.53567E-07 -2.06667E-06 -1.46956E-06 -2.90919E-07 -4.63760E-07 -1.61216E-06 -2.26450E-07 3.99513E-08 -2.37511E-06 -3.37579E-07 -1.96546E-07 -2.63849E-07 -3.12501E-07 -4.03380E-07 -1.17502E-07 -2.50371E-07 -1.84273E-08 -5.20729E-07 5.77909E-08 1.23450E-08 -1.77270E-06

87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119

METHYLCYCLOPENTANE METHYLSTYRENE N-BUTANE N-BUTANOL N-BUTYLBENZENE N-BUTYLCYCLOHEXANE N-BUTYRIC ACID N-DECANE N-DODECANE N-HEPTANE N-HEXADECANE N-HEXANE N-NONANE N-OCTANE N-PENTADECANE N-PENTANE N-PROPANOL N-PROPYL ACETATE N-PROPYL BENZENE N-PROPYLCYCLOHEXANE N-PROPYLCYCLOPENTANE N-TETRADECANE N-TRIDECANE N-UNDECANE NAPHTHALENE NEO-PENTANE NEON NITRIC OXIDE NITROGEN NITROGEN DIOXIDE NITROUS OXIDE O-CRESOL O-DICHLOROBENZENE

9.34709E+00 9.38427E+01 6.67088E+01 -2.06995E+00 -4.87468E+01 -6.42985E+01 3.04306E+01 6.52974E+01 7.82111E+01 4.49544E+01 1.01669E+02 4.27147E+01 6.12326E+01 5.17608E+01 9.69035E+01 8.31454E+01 3.00764E+01 4.52996E+01 -4.61396E+01 -6.60979E+01 -6.80697E+01 9.16493E+01 8.19117E+01 7.29883E+01 -5.38889E+01 5.13986E+01 2.07723E+01 2.97657E+01 2.94119E+01 2.51165E+01 2.05437E+01 1.29178E+00 -9.90706E+00

1.58082E-01 1.58742E-01 -1.85523E-01 4.29749E-01 9.34403E-01 1.09466E+00 2.44352E-01 3.56879E-01 4.20932E-01 2.67290E-01 5.74850E-01 1.99102E-01 3.03023E-01 2.95555E-01 5.26624E-01 -2.41925E-01 1.46604E-01 2.32266E-01 8.29738E-01 1.01662E+00 9.26244E-01 4.82659E-01 4.78009E-01 3.79990E-01 7.53160E-01 -2.52905E-02 0.00000E+00 9.76049E-04 -3.00681E-03 4.39956E-02 8.12993E-02 3.61412E-01 4.95077E-01

1.00675E-03 7.43415E-04 1.52844E-03 -1.69148E-04 -6.94393E-04 -6.65463E-04 2.16458E-04 1.24104E-03 1.51657E-03 8.15496E-04 1.96889E-03 7.89486E-04 1.17647E-03 9.66806E-04 1.88708E-03 1.94653E-03 2.57793E-04 3.85041E-04 -6.20486E-04 -6.44339E-04 -6.73129E-04 1.79251E-03 1.57199E-03 1.40107E-03 -4.33264E-04 1.44716E-03 0.00000E+00 6.09872E-06 5.45064E-06 -9.61717E-06 -8.28968E-05 2.48838E-04 -3.31770E-04

-1.57819E-06 -9.37993E-07 -2.18792E-06 -7.37440E-08 2.67041E-07 1.71855E-07 -4.44626E-07 -2.08987E-06 -2.56729E-06 -1.36933E-06 -3.36510E-06 -1.27867E-06 -1.95748E-06 -1.62822E-06 -3.20860E-06 -2.80749E-06 -4.03837E-07 -6.38403E-07 2.39055E-07 1.85395E-07 2.69887E-07 -3.03677E-06 -2.68952E-06 -2.35145E-06 -5.52149E-09 -2.24820E-06 0.00000E+00 -3.58809E-09 5.13186E-09 -1.21653E-08 4.98739E-08 -5.91848E-07 3.99513E-08

120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152

O-XYLENE OXYGEN P-DICHLOROBENZENE P-XYLENE PHENANTHRENE PHENOL PHOSGENE PROPADIENE PROPANE PROPIONIC ACID PROPYL FORMATE PROPYLENE PYRENE STYRENE SULFUR DIOXIDE SULFUR TRIOXIDE T-BUTYL ALCOHOL TETRAETHENE GLYCOL THIOPHENE TOLUENE TRANS-2-BUTENE TRANS-2-PENTENE TRICHLOROACETYL-CL TRICHLOROETHYLENE TRIETHYLENE GLYCOL TRIMETHYLAMINE VINYLACETYLENE VINYL CHLORIDE WATER 1-BUTENE 1-ET-2-ME-BENZENE 1-HEPTENE 1-HEXENE

4.22847E+01 2.98832E+01 -9.90706E+00 5.59538E+01 -4.68426E-01 -3.61498E+01 2.21276E+01 1.11478E+01 4.72659E+01 3.22170E+01 4.67921E+01 2.43657E+01 -7.09537E+01 -3.24471E+01 2.57725E+01 1.55070E+01 3.04792E+00 7.77268E+01 -3.35167E+01 3.18200E+01 3.49574E+01 2.75152E+01 8.18900E+00 2.06617E+01 6.15213E+01 -7.21214E+00 3.29267E+01 4.98798E+00 3.40471E+01 9.23232E+00 -1.95616E+01 2.65593E+01 1.97547E+01

1.11693E-01 -1.13842E-02 4.95077E-01 -7.30386E-02 7.81941E-01 5.66519E-01 2.11087E-01 1.76641E-01 -1.31469E-01 1.82665E-01 1.72055E-01 7.12795E-02 1.02320E+00 6.31898E-01 5.78938E-02 1.45719E-01 4.22960E-01 3.67280E-01 4.71989E-01 -1.61654E-02 1.06178E-01 2.15429E-01 5.48481E-01 2.94520E-01 2.57110E-01 3.95019E-01 1.14721E-01 2.08934E-01 -9.65064E-03 2.54744E-01 7.24058E-01 3.95331E-01 3.67049E-01

1.09933E-03 4.33779E-05 -3.31770E-04 1.68891E-03 -9.67493E-08 -4.11357E-04 -3.49699E-04 -2.49984E-05 1.17000E-03 1.60153E-04 3.25949E-04 3.38448E-04 -3.41758E-04 -3.98206E-04 -3.80844E-05 -1.13253E-04 -1.57342E-04 9.86510E-04 -4.43715E-04 1.44465E-03 3.88818E-04 3.46773E-04 -9.30532E-04 -3.89705E-04 8.29146E-04 -2.23939E-04 7.98332E-05 -1.72199E-04 3.29983E-05 7.30443E-05 -4.70818E-04 2.91165E-04 1.39914E-04

-1.76777E-06 -3.70082E-08 3.99513E-08 -2.53135E-06 -6.03735E-07 9.39030E-08 2.86091E-07 -1.22238E-07 -1.69695E-06 -3.29308E-07 -5.20729E-07 -5.15275E-07 -3.62008E-07 4.65312E-08 8.60626E-09 3.24046E-08 -8.88132E-08 -1.52386E-06 2.01864E-07 -2.28948E-06 -5.79041E-07 -6.17649E-07 7.58795E-07 2.64566E-07 -1.24370E-06 5.02487E-08 -1.56727E-07 6.80458E-08 -2.04467E-08 -2.65873E-07 1.46400E-07 -6.63027E-07 -4.04223E-07

153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 1000

1-ME-4-ETH-NAPHTHA 1-METHYLINDENE 1-METHYLNAPHTHALEN 1-PENTENE 1-PHENYLINDENE 1-PHENYLNAPHTHALEN 1,1-DICHLOROETHANE 1,2-BUTADIENE 1,2-DICHLOROETHANE 1,2-DIME-3-ETHYLBENZENE 1,2,3-TRIME-INDENE 1,2,4-TRI-CL-BENZENE 1,3-BUTADIENE 1,1,2-TRI-CL-ETHANE 2-ETHYLFLUORENE 2-ME-1-BUTENE 2-ME-2-BUTENE 2-METHYLINDENE 2-METHYLNAPHTHALENE 2-METHYLPENTANE 2,2-DIMETHYLBUTANE 2,3-DIMETHYLBUTANE 2,3,5-TRIME-NAPHTHALENE 2,7-DIMETHYLNAPHTHALENE 3-ME-1-BUTENE 3-METHYLPENTANE VACÏO

-3.32280E+01 -1.92015E+01 -2.76113E+01 1.45912E+01 -5.11735E+01 -5.79301E+01 1.76541E+01 1.72814E+01 2.67689E+01 -7.76813E+00 -2.36187E+01 -1.70348E+01 -5.63223E+00 1.21138E+01 -5.39141E+01 1.85660E+01 1.95382E+01 -2.45876E+01 -2.76113E+01 4.86356E+01 3.15997E+01 2.56594E+01 -3.43677E+01 -3.10170E+01 -1.50488E+01 4.38881E+01 0.00000E+00

7.16826E-01 5.82742E-01 5.82115E-01 3.25234E-01 8.92518E-01 8.47170E-01 2.38989E-01 2.24295E-01 2.12604E-01 4.92779E-01 7.10688E-01 6.32368E-01 3.12606E-01 3.57330E-01 9.13378E-01 2.80716E-01 2.49456E-01 5.99261E-01 5.82115E-01 1.16230E-01 2.55900E-01 2.77678E-01 7.24621E-01 6.53611E-01 6.31168E-01 1.88198E-01 0.00000E+00

2.70672E-04 3.99649E-05 1.77289E-04 3.17391E-05 -6.02522E-05 1.92018E-04 -1.54594E-04 -1.89688E-05 -1.35500E-04 4.71543E-04 1.43321E-04 -6.40391E-04 -2.85818E-06 -3.97122E-04 3.48354E-05 2.65709E-04 2.53292E-04 3.42657E-05 1.77289E-04 1.16766E-03 6.52261E-04 6.66233E-04 2.57469E-04 2.16798E-04 -8.01119E-04 8.23668E-04 0.00000E+00

-8.82466E-07 -4.83219E-07 -6.66549E-07 -2.05695E-07 -6.02431E-07 -8.97733E-07 3.80267E-08 -1.02998E-07 3.01151E-08 -9.55000E-07 -7.05581E-07 3.20361E-07 -3.68547E-07 2.28305E-07 -7.42896E-07 -6.37393E-07 -4.99083E-07 -4.90222E-07 -6.66549E-07 -1.90141E-06 -1.03412E-06 -1.20240E-06 -8.72581E-07 -7.69003E-07 7.13030E-07 -1.32253E-06 0.00000E+00

ulo del calor ganado o perdido de R. V. Reklaitis T en K

n fase gaseosa. Seleccionar el compuesto deseado y sustituir los valores de las temperaturas inicial y final, en K.

desde una temperatura a otra, especificando la masa utilizada del compuesto. Cp = a + b*T + c*T 2 + d*T3 + e*T4 Tinicial

Tfinal

Cpmedia

Cp.∆T

Moles

Q

e 1.94553E-10 7.59551E-11 -1.23175E-11 5.81406E-11 3.40092E-11 6.51935E-12 0.00000E+00 -1.22867E-12 0.00000E+00 2.35694E-10 0.00000E+00 1.05329E-09 3.97897E-11 0.00000E+00 1.26969E-10 -8.13304E-12 1.30288E-10

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 578.221 273.150 273.150 273.150 273.150 273.150

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 353.261 373.150 373.150 373.150 373.150 373.150

kJ/kgmol.K 165.124 57.403 72.263 79.304 54.446 74.635 45.333 67.114 36.643 106.786 20.772 128.092 177.378 36.171 104.808 38.197 55.241

kJ/kgmol 16512.368 5740.270 7226.258 7930.408 5444.562 7463.548 4533.313 6711.361 3664.270 10678.596 2077.230 -28815.638 17737.768 3617.109 10480.844 3819.745 5524.128

kgmol 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 153.846 100.000 100.000 100.000 100.000 100.000

kJoules 1651236.805 574027.038 722625.815 793040.791 544456.246 746354.823 453331.327 671136.056 366426.988 1067859.638 207723.000 -4433176.386 1773776.844 361710.878 1048084.437 381974.485 552412.761

-2.87266E-11

273.150

373.150

29.179

2917.913

100.000

291791.336

-1.99811E-10 0.00000E+00

405.372 273.150

384.701 373.150

84.286 34.238

-1742.285 3423.795

1.000 100.000

-1742.285 342379.459

-7.54466E-11 1.25736E-10 0.00000E+00 3.54798E-10 3.70594E-10 1.96524E-10 6.51190E-10 5.87916E-10 -3.66217E-10 -2.84210E-10 -1.57413E-10 1.39284E-10 3.03364E-10 2.41068E-10 3.91107E-10 1.76476E-10 1.93182E-10 1.02266E-10 -2.11896E-11 1.26309E-10 1.38890E-10 8.31747E-11 2.11886E-10 0.00000E+00 1.62160E-10 5.62012E-11 -1.64356E-11 2.06496E-10 1.46346E-09 1.08485E-09 -3.64212E-09 1.58794E-10 1.86584E-10

273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

86.417 103.531 67.982 236.585 82.566 109.312 117.027 91.681 203.396 280.724 98.856 186.424 116.002 123.903 133.878 123.071 75.213 77.658 82.411 102.508 55.850 69.561 121.130 66.603 101.396 76.626 86.116 73.140 138.869 173.061 145.362 46.129 88.061

8641.653 10353.104 6798.246 23658.543 8256.612 10931.182 11702.653 9168.084 20339.554 28072.399 9885.635 18642.377 11600.209 12390.276 13387.782 12307.095 7521.282 7765.834 8241.115 10250.840 5585.011 6956.102 12112.958 6660.256 10139.575 7662.619 8611.622 7314.031 13886.917 17306.082 14536.152 4612.866 8806.146

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

864165.330 1035310.427 679824.631 2365854.300 825661.232 1093118.234 1170265.300 916808.420 2033955.425 2807239.930 988563.520 1864237.726 1160020.935 1239027.580 1338778.241 1230709.482 752128.161 776583.391 824111.501 1025084.013 558501.126 695610.237 1211295.807 666025.578 1013957.538 766261.891 861162.172 731403.125 1388691.670 1730608.173 1453615.249 461286.570 880614.589

1.90011E-10 1.94895E-10 2.70246E-10 8.85123E-12 1.52277E-10 -2.91803E-11 0.00000E+00 -9.26673E-12 3.18621E-12 1.40695E-11 2.58526E-10 1.91544E-10 1.28569E-10 1.00888E-09 5.48114E-10 1.40589E-10 1.90207E-10 7.79396E-10 1.13597E-10 3.23324E-11 1.15442E-09 1.33437E-10 8.38347E-11 8.00679E-11 1.09833E-10 1.61493E-10 4.67507E-11 1.14584E-10 1.38847E-11 2.11886E-10 -1.06635E-11 0.00000E+00 8.07157E-10

273.150 273.150 273.150 273.150 273.150 273.150 200.723 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 298.150 273.150 273.150 273.150 273.150 273.150 298.150 273.150 273.150 273.150 273.150 273.150 273.150

373.150 373.150 373.150 373.150 373.150 373.150 353.261 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 623.150 373.150 373.150 373.150 373.150 373.150 623.150 373.150 373.150 373.150 373.150 373.150 373.150

51.650 221.276 185.073 35.399 100.598 28.777 29.145 36.760 29.147 34.264 147.120 138.656 105.515 103.693 92.192 94.609 103.443 127.236 94.837 116.905 187.168 108.318 92.048 37.009 45.710 100.291 52.228 70.365 46.052 121.129 63.656 54.530 147.612

5165.026 22127.648 18507.287 3539.947 10059.777 2877.652 4445.755 3675.994 2914.719 3426.393 14712.019 13865.583 10551.546 10369.277 9219.169 9460.872 10344.320 12723.592 9483.667 11690.515 60829.721 10831.804 9204.771 3700.918 4571.046 10029.075 16973.973 7036.528 4605.180 12112.948 6365.557 5453.031 14761.238

100.000 100.000 100.000 100.000 100.000 100.000 255.791 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 27.995 100.000 100.000 100.000 100.000 100.000 27.996 100.000 100.000 100.000 100.000 100.000 100.000

516502.587 2212764.784 1850728.651 353994.716 1005977.660 287765.243 1137183.185 367599.446 291471.933 342639.255 1471201.894 1386558.325 1055154.558 1036927.716 921916.878 946087.193 1034432.032 1272359.151 948366.661 1169051.506 1702934.130 1083180.376 920477.051 370091.784 457104.639 1002907.545 475194.863 703652.844 460517.981 1211294.807 636555.684 545303.111 1476123.839

7.22705E-10 4.29737E-10 1.04577E-09 6.14903E-11 -4.17986E-11 -9.42921E-12 1.91743E-10 9.91165E-10 1.22846E-09 6.38953E-10 1.61483E-09 5.91511E-10 9.28605E-10 7.68379E-10 1.53970E-09 1.35276E-09 1.61597E-10 2.62455E-10 -3.72820E-11 -1.61900E-11 -4.71546E-11 1.45816E-09 1.28710E-09 1.11780E-09 6.75071E-11 1.10083E-09 0.00000E+00 5.85308E-13 -4.25308E-12 5.44943E-12 -1.12709E-11 2.63135E-10 3.23324E-11

273.150 273.150 333.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 353.150 273.150 273.150 273.150 273.150

373.150 373.150 298.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 298.150 373.150 373.150 373.150 373.150

120.129 195.892 102.015 117.154 188.864 225.225 119.005 250.369 299.199 177.155 396.856 152.733 225.964 201.556 372.443 128.310 92.480 141.826 164.512 200.821 169.180 348.033 323.625 274.782 144.470 130.451 20.772 30.606 29.142 37.963 39.684 126.832 116.905

12012.885 19589.201 -3570.516 11715.368 18886.366 22522.511 11900.521 25036.947 29919.948 17715.511 39685.552 15273.307 22596.405 20155.576 37244.349 12830.967 9247.951 14182.605 16451.237 20082.116 16917.954 34803.305 32362.470 27478.213 14447.040 13045.111 2077.230 3060.577 -1602.816 3796.331 3968.441 12683.153 11690.515

100.000 100.000 38.048 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 2533.460 100.000 100.000 100.000 100.000

1201288.518 1958920.101 -135851.356 1171536.826 1888636.558 2252251.054 1190052.132 2503694.690 2991994.756 1771551.055 3968555.212 1527330.708 2259640.537 2015557.633 3724434.944 1283096.676 924795.121 1418260.526 1645123.698 2008211.617 1691795.367 3480330.465 3236246.961 2747821.285 1444704.046 1304511.071 207723.000 306057.663 -4060670.626 379633.099 396844.062 1268315.274 1169051.506

8.56376E-10 1.01006E-11 3.23324E-11 1.21448E-09 3.08038E-10 1.80687E-11 -9.13495E-11 7.96623E-11 8.18910E-10 1.41924E-10 2.11886E-10 2.30475E-10 2.39540E-10 3.64421E-11 0.00000E+00 0.00000E+00 6.77124E-11 6.23029E-10 -3.11709E-11 1.13573E-09 2.47347E-10 2.77835E-10 -2.39379E-10 -7.22648E-11 5.04866E-10 -5.63138E-13 6.32532E-11 -7.87428E-12 4.30228E-12 1.24165E-10 -1.61041E-11 3.02972E-10 1.73590E-10

273.150 298.150 273.150 273.150 273.150 273.150 273.150 273.150 333.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 298.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 440.122 273.150 273.150 273.150 273.150

373.150 493.150 373.150 373.150 373.150 373.150 373.150 373.150 298.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 623.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 468.150 373.150 373.150 373.150 373.150

142.798 30.153 116.905 136.538 234.865 107.073 62.373 62.285 77.107 98.346 121.129 67.854 213.949 131.860 40.770 51.795 120.871 254.719 78.920 156.024 93.015 115.466 110.967 83.132 194.678 98.596 73.709 56.641 34.739 91.474 169.734 165.511 141.110

14279.779 5879.893 11690.515 13653.803 23486.501 10707.282 6237.269 6228.472 -2698.734 9834.609 12112.948 6785.400 21394.918 13186.014 4076.952 5179.485 12087.080 25471.861 7892.024 50707.692 9301.456 11546.560 11096.660 8313.151 19467.767 9859.641 7370.944 5664.067 973.653 9147.367 16973.433 16551.109 14111.048

100.000 383.823 100.000 100.000 100.000 100.000 100.000 100.000 25.365 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 111.980 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 1.000 100.000 100.000 100.000 100.000

1427977.920 2256840.404 1169051.506 1365380.296 2348650.068 1070728.159 623726.858 622847.158 -68454.478 983460.934 1211294.807 678540.039 2139491.841 1318601.351 407695.189 517948.481 1208707.974 2547186.061 789202.382 5678247.374 930145.649 1154655.952 1109665.980 831315.051 1946776.681 985964.107 737094.361 566406.692 973.653 914736.694 1697343.258 1655110.881 1411104.784

4.06741E-10 2.38784E-10 3.11404E-10 7.50234E-11 3.15825E-10 4.27089E-10 0.00000E+00 4.44247E-11 4.09951E-12 4.11215E-10 3.35677E-10 -6.10707E-11 2.46450E-10 -5.24231E-11 3.73867E-10 3.33393E-10 2.24537E-10 2.43351E-10 3.11404E-10 9.36742E-10 4.20348E-10 5.81274E-10 4.03928E-10 3.57471E-10 -2.87208E-10 6.11324E-10 0.00000E+00

273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.15

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.15

201.061 159.350 159.688 116.781 213.695 209.906 79.925 84.714 82.297 172.809 200.582 130.279 85.168 93.074 223.514 119.034 112.132 158.513 159.688 154.108 152.022 150.614 201.360 180.531 125.943 152.692 0.000

20106.141 15935.039 15968.790 11678.138 21369.502 20990.593 7992.489 8471.448 8229.667 17280.888 20058.214 13027.938 8516.757 9307.377 22351.399 11903.386 11213.241 15851.273 15968.790 15410.795 15202.203 15061.446 20136.033 18053.118 12594.310 15269.174 0.000

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

2010614.071 1593503.928 1596879.008 1167813.777 2136950.206 2099059.269 799248.868 847144.783 822966.737 1728088.752 2005821.379 1302793.833 851675.716 930737.723 2235139.896 1190338.616 1121324.063 1585127.311 1596879.008 1541079.456 1520220.297 1506144.619 2013603.335 1805311.774 1259430.978 1526917.416 0.000

Cálculo de temperatura de equilibrio entre una corriente fr -Qp = Qg Procedimiento de prueba y error, modelo iterativo.

En cada una de las tablas, colocar el número de identificación del compuesto, así como la composición en fracción molar

Colocar también el valor , en kgmol, de la mezcla gaseosa a enfriar o calentar. Comparar los resultados con la

Num. 128 89 16 18 148 115 121 1000 1000 1000 1000 1000

Num. 115

Nombre PROPANE N-BUTANE CARBÓN DIOXIDE CARBÓN MONOXIDE WATER NITROGEN OXYGEN VACÏO VACÏO VACÏO VACÏO VACÏO

Nombre NITROGEN

Fracción mol yi 0.00016 0.00030 0.05065 0.00381 0.06939 0.76072 0.11496 0.00000 0.00000 0.00000 0.00000 0.00000 0.99999

Fracción mol yi 0.76551

a 4.72659E+01 6.67088E+01 1.90223E+01 2.90063E+01 3.40471E+01 2.94119E+01 2.98832E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.92737E+01

b -1.31469E-01 -1.85523E-01 7.96291E-02 2.49235E-03 -9.65064E-03 -3.00681E-03 -1.13842E-02 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -2.99708E-04 Temp. Inicial, K

a 2.94119E+01

b -3.00681E-03

121 148 1000 1000 1000 1000 1000 1000 1000 1000 1000

OXYGEN WATER VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO

0.20349 0.03100 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

2.98832E+01 3.40471E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.96515E+01

-1.13842E-02 -9.65064E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -4.91748E-03 Temp. Inicial, K

Los valores en las celdas grises, debajo de las constantes a, b, c, d y e de c Las temperaturas iniciales de cada mezcla pueden ser diferentes, pero la temperatura final de cad Para calcular la temperatura de equilibrio térmico, suponer la temperatura final, calcular

entre una corriente fría y una caliente

r, modelo iterativo.

composición en fracción molar de cada componente de la mezcla. En las celdas amarillas poner los valores de las temperaturas inicial y final.

Comparar los resultados con la tabla de abajo, para comprobar la igualdad del balance de energía. Se obtienen las constantes medias de la me

c 1.17000E-03 1.52844E-03 -7.37067E-05 -1.86440E-05 3.29983E-05 5.45064E-06 4.33779E-05 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 8.26434E-06 1395.059

c 5.45064E-06

d -1.69695E-06 -2.18792E-06 3.74572E-08 4.79892E-08 -2.04467E-08 5.13186E-09 -3.70082E-08 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -6.17193E-10 Temp. Final, K

d 5.13186E-09

e 8.18910E-10 1.04577E-09 -8.13304E-12 -2.87266E-11 4.30228E-12 -4.25308E-12 1.01006E-11 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.85233E-12 693.150

e -4.25308E-12

Tinicial

Tfinal

Cpmedia

Cp.∆T

K 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1395.059 1,395.06

K 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.150 693.15

kJ/kgmol.K 279.38 357.10 54.36 29.37 41.68 32.73 34.93 0.00 0.00 0.00 0.00 0.00 34.823 34.823

kJ/kgmol -196,098.95 -250,649.08 -38,158.14 -20,616.07 -29,253.90 -22,973.45 -24,517.79 0.00 0.00 0.00 0.00 0.00 -24,442.68 -24,442.68

Tinicial

Tfinal

Cpmedia

Cp.∆T

K 388.630

K 319.080

kJ/kgmol.K 29.19

kJ/kgmol -2,030.46

4.33779E-05 3.29983E-05 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.40224E-05 388.630

-3.70082E-08 -2.04467E-08 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -4.23616E-09 Temp. Final, K

1.01006E-11 4.30228E-12 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.06703E-12 319.080

388.630 388.630 388.630 388.630 388.630 388.630 388.630 388.630 388.630 388.630 388.630 388.63 388.63

319.080 319.080 319.080 319.080 319.080 319.080 319.080 319.080 319.080 319.080 319.080 319.08 319.08

29.81 33.93 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 29.466 29.466

-2,073.26 -2,359.93 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -2,049.38 -2,049.38

as constantes a, b, c, d y e de cada compuesto, representan los valores de las respectivas constantes de la mezcla. ero la temperatura final de cada una de ellas debe ser igual, pues se obtiene una sola mezcla final a la temperatura de equilibrio térmico. r la temperatura final, calcular el calor perdido y el calor ganado y ver la diferencia entre ellos. Se busac una diferencia de cero.

emperaturas inicial y final. constantes medias de la mezcla. Moles

Q

kgmol 0.71 1.34 225.96 17.00 309.57 3,393.79 512.87 0.00 0.00 0.00 0.00 0.00 4461.245 4461.290

kJoules -139,976.69 -335,465.47 -8,622,378.37 -350,421.90 -9,056,098.85 -77,967,124.42 -12,574,438.29 0.00 0.00 0.00 0.00 0.00 -109044813.526 -109045903.985

Moles

Q

kgmol 918.61

kJoules -1,865,203.08

244.19 37.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1200.000 1200.000 Diferencia =

a de equilibrio térmico. encia de cero.

-506,265.88 -87,789.28 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -2459258.236 -2459258.236 -111505162.222

Capacidades caloríficas de los líqu "Mass and energy bala Cp's en kJ/k

Constantes para el cálculo de la capacidad calorífica de diferentes compue

También se puede calcular el calor necesario para calentar o enfriar un compu

Num. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

Compuesto ACENAPHTHYLENE ACETALDEHYDE ACETIC ACID ACETONE ACETONITRILE ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA ANILINE ARGON BENZENE BIPHENYL BROMINE BROMOBENZENE CARBÓN DIOXIDE CARBÓN DISULFIDE

a -5.67880E+01 1.68842E+01 -3.60814E+01 1.68022E+01 1.86216E+01 2.17323E+01 1.21476E+01 1.06528E+01 2.01494E+01 -1.36683E+01 -2.49300E+01 -7.27329E+00 -8.65504E+01 2.11979E+01 -9.93411E+00 1.10417E+01 1.74151E+01

b 1.31606E+00 8.10208E-01 6.04681E-01 8.48409E-01 7.30150E-01 1.52480E+00 1.11988E+00 9.77905E-01 8.45765E-01 9.31971E-01 1.41664E+00 7.70541E-01 1.53701E+00 5.17990E-01 8.95727E-01 1.15955E+00 5.54537E-01

18

CARBÓN MONOXIDE

1.49673E+01

2.14397E+00

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

CARBÓN TET CHLORINE CHLOROACETYL-CL CHLOROBENZENE CHLOROFORM CHRYSENE CIS-2-BUTENE CIS-2-PENTENE CYCLOHEXANE CYCLOPENTANE C3ALKYLBENZENE C3ALKYLNAPHTHALENE DICHLOROACETYL-CL DYCYCLOPENTADIENE DIETHYL ETHER DIETHYL KETONE DIETHYLENE GLYCOL DIMETHYL ACETAMIDE

1.22846E+01 1.54120E+01 2.68099E+00 -1.15494E+01 2.38419E+01 1.35514E+02 1.59891E+01 1.35240E+00 -1.12493E+01 -1.77539E+01 3.75668E+01 8.32082E+01 -1.24709E+01 -4.35702E+01 3.93869E+01 1.95218E+01 2.65129E+01 1.76679E+01

1.09475E+00 7.23104E-01 1.70293E+00 9.39618E-01 7.55531E-01 1.95374E+00 8.59807E-01 9.72143E-01 8.41499E-01 8.42309E-01 1.15081E+00 1.17658E+00 1.98455E+00 1.37958E+00 8.83221E-01 9.41566E-01 1.26205E+00 8.99258E-01

37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84

DIMETHYL ETHER DIMETHYL SULFIDE DIMETHYLACETYLENE DIMETHYLFORMAMIDE ETHANE ETHANOL ETHYL ACETATE ETHYL CHLORIDE ETHYL FORMATE ETHYL MERCAPTAN ETHYLACETYLENE ETHYLAMINE ETHYLBENZENE ETHYLCYCLOHEXANE ETHYLCYCLOPENTANE ETHYLENE ETHYLENE GLYCOL ETHYLENE OXIDE FLUORANTHENE FLUORENE FORMALDEHYDE FURFURAL HYDROGEN HYDROGEN CHLORIDE HYDROGEN CYANIDE HYDROGEN IODIDE HYDROGEN SULFIDE INDAN INDENE IODOBENZENE ISO-BUTANE ISO-BUTANOL ISO-BUTENE ISO-BUTYRALDEHYDE ISO-PENTANE ISO-PROPANOL M-DICHLOROBENZENE M-XYLENE MEK METHACRYLONITRILE METHANE METHANOL METHYL ACETATE METHYL CHLORIDE METHYL FORMATE METHYL IODIDE METHYL PROPIONATE METHYLACETYLENE

3.90853E+01 2.31559E+01 4.61307E+00 2.69989E+01 2.06881E+01 -3.25137E+02 4.29049E+01 1.79781E-01 3.20116E+01 1.17652E+01 -1.83773E+00 2.23571E+01 4.31428E+00 -9.49573E+00 -2.31040E+02 3.44364E+00 3.10224E+01 7.41259E+00 -8.37633E+01 -4.56808E+01 2.50990E+01 2.14163E+01 5.88663E+01 1.77227E+01 1.68791E+01 1.67440E+01 2.18238E+01 -3.71075E+01 -2.91550E+01 -1.06028E+01 3.87062E+01 5.15292E+01 8.45979E+00 2.53636E+01 2.81135E+01 9.14963E+00 -1.69119E+01 1.40673E+01 3.40321E+01 2.92563E+01 -5.70709E+00 -2.58250E+02 3.92701E+01 7.99608E+00 1.20769E+01 5.22773E+00 4.18960E+01 5.88685E+00

8.07754E-01 7.63756E-01 9.17069E-01 9.57414E-01 9.48588E-01 4.13787E+00 9.34378E-01 9.04849E-01 8.85757E-01 8.26110E-01 9.86905E-01 8.73964E-01 9.00174E-01 1.06190E+00 2.61156E+00 1.08420E+00 1.10034E+00 7.42687E-01 1.67596E+00 1.33975E+00 7.93671E-01 8.86185E-01 -2.30694E-01 9.04261E-01 8.50946E-01 6.72052E-01 7.74223E-01 1.14329E+00 1.09168E+00 8.50951E-01 7.46648E-01 9.09017E-01 1.00655E+00 9.66816E-01 8.68714E-01 1.44133E+00 1.00777E+00 8.70264E-01 8.64140E-01 8.12281E-01 1.02562E+00 3.35820E+00 7.96701E-01 7.98500E-01 8.63546E-01 6.85948E-01 9.10092E-01 1.01171E+00

85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132

METHYLAMINE METHYLCYCLOHEXANE METHYLCYCLOPENTANE METHYLSTYRENE N-BUTANE N-BUTANOL N-BUTYLBENZENE N-BUTYLCYCLOHEXANE N-BUTYRIC ACID N-DECANE N-DODECANE N-HEPTANE N-HEXADECANE N-HEXANE N-NONANE N-OCTANE N-PENTADECANE N-PENTANE N-PROPANOL N-PROPYL ACETATE N-PROPYL BENZENE N-PROPYLCYCLOHEXANE N-PROPYLCYCLOPENTANE N-TETRADECANE N-TRIDECANE N-UNDECANE NAPHTHALENE NEO-PENTANE NEON NITRIC OXIDE NITROGEN NITROGEN DIOXIDE NITROUS OXIDE O-CRESOL O-DICHLOROBENZENE O-XYLENE OXYGEN P-DICHLOROBENZENE P-XYLENE PHENANTHRENE PHENOL PHOSGENE PROPADIENE PROPANE PROPIONIC ACID PROPYL FORMATE PROPYLENE PYRENE

7.96131E+00 -1.36334E+01 -7.85540E+00 7.60375E+01 5.18583E+01 -5.10376E-01 -4.92918E+01 -6.50106E+01 2.95304E+01 4.36906E+01 4.29158E+01 3.38820E+01 2.80584E+01 3.14210E+01 4.34796E+01 3.82405E+01 3.32402E+01 6.54961E+01 -4.88104E+02 4.10176E+01 -4.72371E+01 -6.82123E+01 -7.05452E+01 3.78050E+01 4.02131E+01 4.51594E+01 -6.32700E+01 3.59838E+01 3.30532E+02 3.36324E+01 1.47141E+01 1.69925E+01 8.58935E+00 -8.59146E+00 -1.66105E+01 1.48871E+01 1.10501E+03 -1.63179E+01 2.20553E+01 -7.65516E+01 -3.61614E+01 1.35843E+01 -2.57486E+00 3.37507E+01 3.17072E+01 4.10551E+01 1.22887E+01 -9.33646E+01

9.72440E-01 9.73700E-01 8.99222E-01 8.32891E-01 6.56571E-01 1.44697E+00 1.49918E+00 1.68625E+00 1.07457E+00 1.31857E+00 1.51927E+00 1.07063E+00 2.04324E+00 9.76058E-01 1.21415E+00 1.14275E+00 1.92411E+00 6.28628E-01 5.78632E+00 9.93938E-01 1.40532E+00 1.61015E+00 1.53129E+00 1.78056E+00 1.67374E+00 1.41653E+00 1.24334E+00 8.14020E-01 -2.34614E+01 2.90498E+00 2.20257E+00 1.71499E+00 1.05171E+00 1.03316E+00 1.00462E+00 9.03295E-01 -3.33636E+01 1.01438E+00 8.11839E-01 1.47204E+00 1.15354E+00 9.04210E-01 9.04297E-01 7.46408E-01 9.30795E-01 8.90979E-01 9.18751E-01 1.70047E+00

133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 1000

STYRENE SULFUR DIOXIDE SULFUR TRIOXIDE T-BUTYL ALCOHOL TETRAETHENE GLYCOL THIOPHENE TOLUENE TRANS-2-BUTENE TRANS-2-PENTENE TRICHLOROACETYL-CL TRICHLOROETHYLENE TRIETHYLENE GLYCOL TRIMETHYLAMINE VINYLACETYLENE VINYL CHLORIDE WATER 1-BUTENE 1-ET-2-ME-BENZENE 1-HEPTENE 1-HEXENE 1-ME-4-ETH-NAPHTHA 1-METHYLINDENE 1-METHYLNAPHTHALEN 1-PENTENE 1-PHENYLINDENE 1-PHENYLNAPHTHALEN 1,1-DICHLOROETHANE 1,2-BUTADIENE 1,2-DICHLOROETHANE 1,2-DIME-3-ETHYLBENZENE 1,2,3-TRIME-INDENE 1,2,4-TRI-CL-BENZENE 1,3-BUTADIENE 1,1,2-TRI-CL-ETHANE 2-ETHYLFLUORENE 2-ME-1-BUTENE 2-ME-2-BUTENE 2-METHYLINDENE 2-METHYLNAPHTHALENE 2-METHYLPENTANE 2,2-DIMETHYLBUTANE 2,3-DIMETHYLBUTANE 2,3,5-TRIME-NAPHTHALENE 2,7-DIMETHYLNAPHTHALENE 3-ME-1-BUTENE 3-METHYLPENTANE VACÍO

-3.80191E+01 1.92884E+01 1.62291E+01 4.88045E+00 1.12812E+00 -3.93905E+01 1.80826E+00 2.52418E+01 1.69958E+01 -2.32210E+01 1.71931E+01 7.99807E+00 -1.62116E+01 2.32080E+01 -7.94162E+00 1.82964E+01 -7.03548E-01 -2.14660E+01 2.00903E+01 1.11256E+01 -5.45979E+01 -3.21486E+01 -4.88822E+01 5.45455E+00 -7.59414E+01 -9.05449E+01 1.01731E+01 6.25816E+00 1.99518E+01 -2.31556E+01 -3.79693E+01 -1.73071E+01 -1.61777E+01 6.30739E+00 -7.76821E+01 6.85913E+00 9.02049E+00 -3.81172E+01 -4.79704E+01 3.36802E+01 2.00732E+01 1.28551E+01 -5.74309E+01 -5.27406E+01 -2.38042E+01 3.17843E+01 0.00000E+00

1.19721E+00 8.45429E-01 1.37462E+00 1.54948E+00 1.90413E+00 1.04007E+00 8.12223E-01 8.87012E-01 9.34177E-01 2.14161E+00 9.31709E-01 1.76246E+00 1.13684E+00 8.21960E-01 8.86957E-01 4.72118E-01 1.02601E+00 1.28851E+00 1.14211E+00 1.05516E+00 1.49414E+00 1.18921E+00 1.20998E+00 1.02076E+00 1.59722E+00 1.64726E+00 8.73659E-01 9.13303E-01 8.14846E-01 1.20294E+00 1.40735E+00 1.10113E+00 1.08511E+00 8.91575E-01 1.68493E+00 1.00156E+00 9.50674E-01 1.20843E+00 1.21302E+00 9.38653E-01 9.87609E-01 1.02940E+00 1.50154E+00 1.34672E+00 1.26801E+00 9.58431E-01 0.00000E+00

oríficas de los líquidos y cálculo del calor ganado o perdido s and energy balances" de R. V. Reklaitis Cp's en kJ/kgmol, T en K

a de diferentes compuestos, en fase líquida. Seleccionar el compuesto deseado y sustituir los valores de las

ntar o enfriar un compuesto, desde una temperatura a otra, especificando la masa utilizada del compuesto. Tinicial

Tfinal

Cpmedia

c -1.71665E-03 -3.08085E-03 -3.93957E-04 -2.64114E-03 -2.33009E-03 -5.44935E-03 -6.78213E-03 -3.10778E-03 -4.06745E-03 -1.60401E-03 -2.86902E-03 -1.64818E-03 -2.04329E-03 -1.75921E-03 -1.68176E-03 -7.23130E-03 -1.72346E-03

d 1.09288E-06 4.42590E-06 -5.61602E-07 3.39139E-06 2.78250E-06 6.98035E-06 1.42930E-05 3.82102E-06 6.60687E-06 1.36715E-06 -4.27496E-05 1.89794E-06 1.28288E-06 1.95266E-06 1.47666E-06 1.55019E-05 2.07575E-06

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 261.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 276.766 373.150 373.150 352.533 373.150 373.150 373.150 373.150 373.150

kJ/kgmol.K 225.566 107.344 98.449 130.144 105.450 182.070 154.022 131.568 81.961 165.901 -1346.265 130.657 239.387 70.884 153.522 160.228 86.927

-3.24703E-02

1.58042E-04

273.150

373.150

2750.834

-3.18255E-03 -3.39726E-03 -5.18598E-03 -1.89850E-03 -2.40701E-03 -2.04051E-03 -3.12594E-03 -2.73959E-03 -1.58331E-03 -2.00426E-03 -2.08788E-03 -1.49715E-03 -6.07564E-03 -2.11522E-03 -2.83840E-03 -2.19928E-03 -2.69832E-03 -1.75431E-03

3.42524E-06 5.26236E-06 5.61119E-06 1.79189E-06 2.84262E-06 9.41273E-07 4.92443E-06 3.71880E-06 1.96493E-06 2.64122E-06 2.00092E-06 1.26197E-06 6.56868E-06 1.69221E-06 4.18044E-06 2.53543E-06 2.56288E-06 1.64643E-06

384.701 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

349.150 373.150 373.150 405.443 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

154.767 73.321 200.994 158.584 112.853 584.606 134.956 155.629 161.918 134.734 258.820 349.436 216.287 238.066 170.479 179.901 238.877 180.495

-3.70090E-03 -2.47469E-03 -2.87254E-03 -2.39927E-03 -5.98221E-03 -1.40307E-02 -2.63999E-03 -3.14990E-03 -2.67612E-03 -2.61295E-03 -3.18071E-03 -3.21587E-03 -1.45005E-03 -1.53490E-03 -5.57507E-03 -7.13595E-03 -2.84571E-03 -2.71320E-03 -1.87334E-03 -1.64621E-03 -3.82691E-03 -1.93931E-03 -8.04213E-02 -5.64496E-03 -3.53136E-03 -3.22257E-03 -4.20204E-03 -1.72505E-03 -1.71677E-03 -1.45253E-03 -2.89544E-03 -2.75500E-03 -3.65636E-03 -2.87136E-03 -2.50761E-03 -4.60994E-03 -1.85017E-03 -1.47733E-03 -2.40262E-03 -2.28011E-03 -1.66566E-03 -1.16388E-02 -2.47205E-03 -3.50758E-03 -2.87339E-03 -2.25547E-03 -2.50667E-03 -4.23564E-03

6.32701E-06 3.21702E-06 3.70322E-06 2.58304E-06 1.31546E-05 1.70354E-05 3.34258E-06 4.36155E-06 3.44613E-06 3.35734E-06 4.26588E-06 4.79241E-06 1.43360E-06 1.57500E-06 4.90973E-06 1.65631E-05 2.88921E-06 3.90092E-06 9.46409E-07 1.00531E-06 6.10492E-06 1.85001E-06 1.37776E-03 1.13383E-05 5.04830E-06 4.96454E-06 7.38677E-06 1.40023E-06 1.38016E-06 1.15835E-06 5.19378E-06 3.69657E-06 5.66411E-06 3.75743E-06 3.76751E-06 5.88221E-06 1.52520E-06 1.51193E-06 2.94373E-06 2.65682E-06 -1.97507E-05 1.40516E-05 3.23224E-06 5.51501E-06 3.83072E-06 2.73291E-06 3.12247E-06 6.74784E-06

273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

129.175 120.638 126.560 173.094 152.074 123.781 182.462 111.731 155.632 119.692 129.681 131.871 192.110 226.516 195.704 174.985 186.891 96.611 293.338 248.717 89.700 167.580 39125.127 107.524 94.588 66.253 84.946 199.151 190.604 151.514 154.675 183.017 144.573 165.384 175.068 192.925 166.702 192.032 162.096 143.544 -532.052 87.387 148.202 87.387 121.044 83.913 180.033 120.139

-3.92527E-03 -1.60323E-03 -1.87221E-03 -1.37884E-03 -2.53079E-03 -3.83339E-03 -2.39414E-03 -2.51655E-03 -2.48619E-03 -2.03714E-03 -2.03948E-03 -2.25615E-03 -2.42726E-03 -2.35368E-03 -2.03819E-03 -2.13030E-03 -2.36868E-03 -1.89880E-03 -1.88720E-02 -2.44653E-03 -2.43735E-03 -2.57929E-03 -2.73757E-03 -2.23443E-03 -2.20936E-03 -2.03836E-03 -1.76851E-03 -2.52756E-03 5.74438E-01 -3.26583E-02 -3.52146E-02 -7.83962E-03 -6.39280E-03 -1.74432E-03 -1.81232E-03 -1.55098E-03 3.50211E-01 -1.86814E-03 -1.36670E-03 -1.67258E-03 -2.12291E-03 -3.41229E-03 -3.68515E-03 -3.64966E-03 -2.33049E-03 -2.39549E-03 -4.34735E-03 -1.94567E-03

5.93717E-06 1.79689E-06 2.34232E-06 1.44784E-06 4.49879E-06 4.28849E-06 1.94687E-06 2.06802E-06 2.53277E-06 2.00524E-06 1.77265E-06 2.72250E-06 1.75525E-06 3.09273E-06 2.15001E-06 2.39204E-06 1.79436E-06 3.18651E-06 2.20035E-05 2.91793E-06 2.10281E-06 2.24600E-06 2.55774E-06 1.76082E-06 1.83719E-06 1.89124E-06 1.21897E-06 4.22057E-06 -4.24012E-03 1.20828E-04 1.79960E-04 1.20017E-05 1.33260E-05 1.47766E-06 1.46252E-06 1.51201E-06 -1.21262E-03 1.54201E-06 1.44216E-06 9.13405E-07 1.74183E-06 4.65981E-06 5.83225E-06 7.10670E-06 2.45740E-06 2.93524E-06 7.94316E-06 1.03340E-06

273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

114.182 194.351 166.595 250.078 153.087 211.759 250.433 286.467 202.598 324.646 380.444 236.446 493.489 205.951 295.583 265.939 467.692 178.875 155.582 205.512 222.997 258.220 224.514 438.840 412.007 353.703 194.482 178.819 -93295.444 1709.772 3237.990 160.695 136.003 192.726 167.804 195.777 -14713.283 168.121 190.374 254.645 173.335 107.616 103.275 136.351 172.099 178.249 126.045 287.050

-2.19565E-03 -3.72748E-03 -5.17738E-03 -4.66330E-03 -3.04611E-03 -2.38173E-03 -1.51267E-03 -3.30491E-03 -2.72023E-03 -6.34230E-03 -2.74646E-03 -3.52085E-03 -3.67488E-03 -3.04898E-03 -3.33590E-03 -1.33878E-03 -3.63907E-03 -2.22048E-03 -2.55737E-03 -2.59179E-03 -1.84755E-03 -1.74392E-03 -1.53729E-03 -2.93262E-03 -1.82973E-03 -1.84168E-03 -2.60121E-03 -3.10142E-03 -2.29913E-03 -1.70706E-03 -1.87484E-03 -1.91718E-03 -3.68261E-03 -2.15051E-03 -1.97725E-03 -2.83730E-03 -2.68985E-03 -1.73213E-03 -1.56000E-03 -2.24842E-03 -2.39907E-03 -2.41758E-03 -1.82573E-03 -1.66099E-03 -3.55766E-03 -2.31456E-03 0.00000E+00

1.93312E-06 5.65365E-06 6.88634E-06 5.85875E-06 2.26240E-06 2.34822E-06 1.63001E-06 5.18957E-06 3.74189E-06 6.61378E-06 3.08927E-06 3.09510E-06 5.27623E-06 4.36824E-06 4.82845E-06 1.31424E-06 5.58528E-06 1.91681E-06 3.01294E-06 3.20045E-06 1.23156E-06 1.35295E-06 1.03385E-06 3.93623E-06 1.04060E-06 1.04703E-06 3.11481E-06 4.38633E-06 2.56998E-06 1.43219E-06 1.38180E-06 1.42793E-06 5.41041E-06 2.08369E-06 1.19039E-06 3.82462E-06 3.60341E-06 1.30948E-06 1.06587E-06 3.06594E-06 3.26302E-06 3.13353E-06 1.18242E-06 1.09319E-06 4.48758E-06 3.07474E-06 0.00000E+00

273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 298.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.15

373.150 373.150 373.150 373.150 373.150 373.150 352.533 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 493.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.15

184.542 95.488 153.415 217.177 373.989 127.147 157.777 143.323 161.840 229.781 135.928 313.880 146.653 118.827 94.382 77.616 140.795 227.422 224.083 189.876 276.316 215.330 216.032 162.637 283.560 284.091 126.321 126.500 130.065 235.377 267.217 186.062 133.793 140.057 299.811 164.014 157.608 215.311 216.642 206.277 199.442 199.306 276.473 245.391 166.536 204.114 0.000

do y sustituir los valores de las temperaturas inicial y final, en K. masa utilizada del compuesto. Cp = a + b*T + c*T 2 + d*T3 + e*T4 Cp.∆T

Moles

Q

kJ/kgmol 22556.589 10734.355 9844.855 13014.422 10545.007 18206.971 15402.249 13156.832 1279.898 16590.052 -134626.540 10371.974 23938.669 7088.371 15352.246 16022.791 8692.724

kgmol 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 0.007 100.000 100.000 100.000 100.000 100.000

kJoules 2255658.924 1073435.546 984485.478 1301442.154 1054500.668 1820697.086 1540224.930 1315683.221 127989.838 1659005.166 -13462654.048 73.136 2393866.928 708837.124 1535224.621 1602279.105 869272.364

275083.449

100.000

27508344.947

-5502.130 7332.091 20099.450 20979.527 11285.303 58460.643 13495.599 15562.932 16191.752 13473.371 25882.037 34943.612 21628.742 23806.572 17047.911 17990.127 23887.668 18049.504

1.000 100.000 100.000 1.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

-5502.130 733209.118 2009944.996 20979.527 1128530.281 5846064.281 1349559.945 1556293.181 1619175.156 1347337.073 2588203.690 3494361.227 2162874.222 2380657.153 1704791.053 1799012.731 2388766.816 1804950.376

12917.491 12063.768 12656.027 17309.393 15207.370 12378.073 18246.231 11173.073 15563.209 11969.202 12968.088 13187.116 19210.967 22651.597 19570.434 17498.473 18689.115 9661.141 29333.818 24871.716 8970.007 16758.026 3912512.673 10752.390 9458.845 6625.259 8494.625 19915.149 19060.428 15151.439 15467.490 18301.679 14457.332 16538.387 17506.846 19292.523 16670.186 19203.234 16209.598 14354.362 -53205.227 8738.741 14820.184 8738.685 12104.419 8391.328 18003.307 12013.949

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

1291749.094 1206376.755 1265602.695 1730939.294 1520737.046 1237807.314 1824623.085 1117307.304 1556320.902 1196920.185 1296808.819 1318711.623 1921096.653 2265159.744 1957043.445 1749847.303 1868911.504 966114.062 2933381.757 2487171.618 897000.685 1675802.578 391251267.333 1075239.015 945884.488 662525.897 849462.491 1991514.880 1906042.822 1515143.859 1546749.028 1830167.904 1445733.162 1653838.727 1750684.610 1929252.258 1667018.643 1920323.416 1620959.797 1435436.220 -5320522.654 873874.098 1482018.350 873868.518 1210441.934 839132.774 1800330.662 1201394.924

11418.200 19435.110 16659.520 25007.793 15308.734 21175.888 25043.324 28646.743 20259.827 32464.594 38044.433 23644.626 49348.917 20595.098 29558.335 26593.880 46769.157 17887.480 15558.203 20551.230 22299.704 25821.982 22451.446 43884.034 41200.722 35370.304 19448.248 17881.911 -9329544.365 170977.173 323799.001 16069.503 13600.283 19272.612 16780.362 19577.653 -1471328.259 16812.121 19037.436 25464.459 17333.477 10761.559 10327.496 13635.055 17209.878 17824.915 12604.516 28704.969

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

1141819.960 1943510.994 1665952.029 2500779.318 1530873.407 2117588.754 2504332.391 2864674.336 2025982.714 3246459.371 3804443.271 2364462.615 4934891.743 2059509.831 2955833.459 2659387.955 4676915.742 1788747.997 1555820.286 2055122.992 2229970.399 2582198.157 2245144.588 4388403.354 4120072.231 3537030.400 1944824.812 1788191.056 -932954436.499 17097717.315 32379900.146 1606950.338 1360028.344 1927261.201 1678036.156 1957765.293 -147132825.940 1681212.148 1903743.637 2546445.850 1733347.710 1076155.916 1032749.555 1363505.496 1720987.782 1782491.451 1260451.558 2870496.900

18454.214 9548.821 15341.486 21717.747 37398.942 12714.730 12524.797 14332.315 16183.966 22978.117 13592.842 31388.030 14665.328 11882.729 9438.216 15135.210 14079.459 22742.168 22408.274 18987.617 27631.593 21532.952 21603.157 16263.674 28356.019 28409.145 12632.096 12650.021 13006.538 23537.722 26721.708 18606.154 13379.331 14005.674 29981.084 16401.368 15760.821 21531.085 21664.170 20627.667 19944.222 19930.625 27647.306 24539.051 16653.644 20411.425 0.000

100.000 100.000 100.000 100.000 100.000 100.000 0.005 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 614.118 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 0.000

1845421.380 954882.113 1534148.633 2171774.684 3739894.180 1271473.014 61.263 1433231.533 1618396.558 2297811.734 1359284.194 3138803.046 1466532.773 1188272.935 943821.560 9294804.826 1407945.880 2274216.844 2240827.362 1898761.742 2763159.333 2153295.228 2160315.703 1626367.406 2835601.930 2840914.474 1263209.553 1265002.144 1300653.784 2353772.170 2672170.793 1860615.444 1337933.103 1400567.426 2998108.447 1640136.801 1576082.126 2153108.486 2166416.992 2062766.687 1994422.205 1993062.509 2764730.604 2453905.130 1665364.411 2041142.496 0.000

Cálculo de la temperatura d

Procedimiento de En cada una de las tablas, colocar el número de identificación del compuesto, así como la composi

Colocar también el valor , en kgmol, de la mezcla líquida a enfriar o calentar. Compara

Num. 12 139 74 1000 1000 1000 1000 1000 1000 1000 1000 1000

Num. 12 139 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000

Nombre BENZENE TOLUENE M-XYLENE VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

0.4 0.25 0.35 0 0 0 0 0 0 0 0 0 1.00000

Nombre BENZENE TOLUENE VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

Fracción mol yi

Fracción mol yi 0.864 0.136 0 0 0 0 0 0 0 0 0 0 1.00000

a -7.27329E+00 1.80826E+00 1.40673E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.46630E+00 Temp. Inicial, K

a -7.27329E+00 1.80826E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -6.03820E+00 Temp. Inicial, K

Los valores en las celdas grises, debajo de las const Las temperaturas iniciales de cada mezcla pueden ser diferentes, pero la te Para calcular la temperatura de equilibrio térmico, suponer la temp

de la temperatura de equilibrio entre una corriente fría y una caliente -Qp = Qg

Procedimiento de prueba y error, modelo iterativo. uesto, así como la composición en fracción molar de cada componente de la mezcla. En las celdas amarillas

enfriar o calentar. Comparar los resultados con la tabla de abajo, para comprobar la igualdad del balance de

b 7.70541E-01 8.12223E-01 8.70264E-01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 8.15865E-01 305.650

b 7.70541E-01 8.12223E-01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 7.76210E-01 373.150

c -1.64818E-03 -1.51267E-03 -1.47733E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.55451E-03 Temp. Final, K

c -1.64818E-03 -1.51267E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.62975E-03 Temp. Final, K

d 1.89794E-06 1.63001E-06 1.51193E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.69585E-06 381.400

d 1.89794E-06 1.63001E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.86150E-06 273.150

Tinicial

Tfinal

K 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650 305.650

K 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400 381.400

Tinicial

Tfinal

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

grises, debajo de las constantes a, b, c y d de cada compuesto, representan los valores de las respectivas co en ser diferentes, pero la temperatura final de cada una de ellas debe ser igual, pues se obtiene una sola me io térmico, suponer la temperatura final, calcular el calor perdido y el calor ganado y ver la diferencia entre e

una caliente

cla. En las celdas amarillas poner los valores de las temperaturas inicial y final. la igualdad del balance de energía. Se obtienen las constantes medias de la mezcla. Cpmedia

Cp.∆T

Moles

Q

kJ/kgmol.K 140.01 168.48 200.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 168.131 168.131

kJ/kgmol 10,606.07 12,762.14 15,151.28 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 12,735.91 12735.912

kgmol 480.00 300.00 420.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1200.000 1200.000

kJoules 5,090,914.66 3,828,641.41 6,363,538.93 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 15283094.998 15283094.998

Cpmedia

Cp.∆T

Moles

Q

kJ/kgmol.K 133.82 161.38 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 137.568 137.568

kJ/kgmol -13,382.06 -16,137.75 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -13,756.83 -13756.831

kgmol 1,123.20 176.80 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1300.000 1300.000

kJoules -15,030,726.08 -2,853,154.59 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -17883880.669 -17883880.669

Diferencia =

-2600785.672

valores de las respectivas constantes de la mezcla. ues se obtiene una sola mezcla final a la temperatura de equilibrio térmico. do y ver la diferencia entre ellos. Se busac una diferencia de cero.

En cada una de las tablas, colocar el número de identificación del compuesto, así com Colocar también el valor , en kgmol, de la mezcla líquida a enfriar o calentar. Com

Num. 12 139 123 1000 1000 1000 1000 1000 1000 1000

Num. 115 121 16 18 33 1000 1000 1000 1000 1000

Nombre BENZENE TOLUENE P-XYLENE VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO VACÏO

Nombre NITROGEN OXYGEN CARBÓN DIOXIDE CARBÓN MONOXIDE DIETHYL ETHER VACÍO VACÍO VACÍO VACÍO VACÍO

Fracción mol yi 0.98570 0.01430 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

Fracción mol yi 0.36513 0.20285 0.16228 0.08114 0.18860 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

a 1.85868E+01 3.18200E+01 5.59538E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.87760E+01

a 2.94119E+01 2.98832E+01 1.90223E+01 2.90063E+01 4.67637E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 3.10611E+01

Num. 12 16 121 115 1000 1000 1000 1000 1000 1000

Num. 12 16 121 115 1000 1000 1000 1000 1000 1000

Nombre BENZENE CARBÓN DIOXIDE OXYGEN NITROGEN VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

Nombre BENZENE CARBÓN DIOXIDE OXYGEN NITROGEN VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

Fracción mol yi 0.03861 0.18746 0.16339 0.61054 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

Fracción mol yi 0.03861 0.18746 0.16339 0.61054 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

a -7.27329E+00 1.10417E+01 1.10501E+03 1.47141E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.91320E+02

a -7.27329E+00 1.10417E+01 1.10501E+03 1.47141E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.91320E+02

Los valores en las celdas grises, debajo de las constan Las temperaturas iniciales de cada mezcla pueden ser diferentes, pero la tem Para calcular la temperatura de equilibrio térmico, suponer la tempe

Capacidades caloríficas de las mezclas y cálculo del calor perdido o "Mass and energy balances" de R. V. Reklaitis Cp's en kJ/kgmol, T en K

tificación del compuesto, así como la composición en fracción molar de cada componente de la mezcla. En l a líquida a enfriar o calentar. Comparar los resultados con la tabla de abajo, para comprobar la igualdad del b

GASES Tinicial b -1.17439E-02 -1.61654E-02 -7.30386E-02 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.18071E-02 Temp. Inicial, K

c 1.27514E-03 1.44465E-03 1.68891E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.27756E-03 349.032

d -2.07984E-06 -2.28948E-06 -2.53135E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -2.08284E-06 Temp. Final, K

e 1.05329E-09 1.13573E-09 1.21448E-09 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.05447E-09 328.150

K 349.032 349.032 349.032 349.032 349.032 349.032 349.032 349.032 349.032 349.032 349.032 349.032

Tinicial b -3.00681E-03 -1.13842E-02 7.96291E-02 2.49235E-03 1.00949E-01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.87563E-02 Temp. Inicial, K

c 5.45064E-06 4.33779E-05 -7.37067E-05 -1.86440E-05 5.69049E-04 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.04638E-04 318.150

d 5.13186E-09 -3.70082E-08 3.74572E-08 4.79892E-08 -7.74108E-07 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.41658E-07 Temp. Final, K

e -4.25308E-12 1.01006E-11 -8.13304E-12 -2.87266E-11 3.03364E-10 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 5.40597E-11 328.150

LÍQUIDOS

K 318.150 318.150 318.150 318.150 318.150 318.150 318.150 318.150 318.150 318.150 318.150 318.150

Tinicial b 7.70541E-01 1.15955E+00 -3.33636E+01 2.20257E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -3.85940E+00 Temp. Inicial, K

c -1.64818E-03 -7.23130E-03 3.50211E-01 -3.52146E-02 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 3.43018E-02 273.150

d 1.89794E-06 1.55019E-05 -1.21262E-03 1.79960E-04 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -8.52779E-05 Temp. Final, K

e

373.150

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

Tinicial b 7.70541E-01 1.15955E+00 -3.33636E+01 2.20257E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -3.85940E+00 Temp. Inicial, K

c -1.64818E-03 -7.23130E-03 3.50211E-01 -3.52146E-02 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 3.43018E-02 273.150

d 1.89794E-06 1.55019E-05 -1.21262E-03 1.79960E-04 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -8.52779E-05 Temp. Final, K

e

373.150

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

as grises, debajo de las constantes a, b, c, d y e de cada compuesto, representan los valores de las respectiv ueden ser diferentes, pero la temperatura final de cada una de ellas debe ser igual, pues se obtiene una sola ilibrio térmico, suponer la temperatura final, calcular el calor perdido y el calor ganado y ver la diferencia en

l calor perdido o ganado

ente de la mezcla. En las celdas amarillas poner los valores de las temperaturas inicial y final. probar la igualdad del balance de energía. Se obtienen las constantes medias de la mezcla.

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150

kJ/kgmol.K 93.903 118.019 142.547 0.000 0.000 0.000 0.000 0.000 0.000 0.000 94.248 94.248

kJ/kgmol -1960.882 -2464.467 -2976.663 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -1968.083 -1968.083

kgmol 67.239 0.975 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 68.214 68.214

kJoules -131846.834 -2403.989 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -134250.823 -134250.823

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150 328.150

kJ/kgmol.K 29.136 29.596 38.233 29.171 115.995 0.000 0.000 0.000 0.000 0.000 47.090 47.090

kJ/kgmol 291.363 295.956 382.325 291.710 1159.946 0.000 0.000 0.000 0.000 0.000 470.899 470.899

kgmol 71.839 39.911 31.929 15.964 37.107 0.000 0.000 0.000 0.000 0.000 196.750 196.750

kJoules 20931.321 11811.815 12207.102 4656.947 43042.162 0.000 0.000 0.000 0.000 0.000 92649.348 92649.348

Diferencia:

-41601.475

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

kJ/kgmol.K 133.821 160.228 -14713.283 3237.990 0.000 0.000 0.000 0.000 0.000 0.000 -391.878 -391.878

kJ/kgmol 13382.057 16022.791 -1471328.259 323799.001 0.000 0.000 0.000 0.000 0.000 0.000 -39187.768 -39187.768

kgmol 30.888 149.968 130.712 488.432 0.000 0.000 0.000 0.000 0.000 0.000 800.000 800.000

kJoules 413344.967 2402905.928 -192320259.443 158153793.882 0.000 0.000 0.000 0.000 0.000 0.000 -31350214.666 -31350214.666

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

kJ/kgmol.K 133.821 160.228 -14713.283 3237.990 0.000 0.000 0.000 0.000 0.000 0.000 -391.878 -391.878

kJ/kgmol 13382.057 16022.791 -1471328.259 323799.001 0.000 0.000 0.000 0.000 0.000 0.000 -39187.768 -39187.768

kgmol 30.888 149.968 130.712 488.432 0.000 0.000 0.000 0.000 0.000 0.000 800.000 800.000

kJoules 413344.967 2402905.928 -192320259.443 158153793.882 0.000 0.000 0.000 0.000 0.000 0.000 -31350214.666 -31350214.666

Diferencia:

-62700429.332

valores de las respectivas constantes de la mezcla. es se obtiene una sola mezcla final a la temperatura de equilibrio térmico. o y ver la diferencia entre ellos. Se busac una diferencia de cero.

cial y final. mezcla.

Presiones de vapor y temperaturas "Mass and energy balances" de R Pv en kPa, T en K

Colocar en las casillas amarillas la temperatura, en K, a la cual

Colocar en las casillas azules la presión de vapor, en kPa, a la cual se

Num. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

Compuesto ACENAPHTHYLENE ACETALDEHYDE ACETIC ACID ACETONE ACETONITRILE ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA ANILINE ARGON BENZENE BIPHENYL BROMINE BROMOBENZENE CARBÓN DIOXIDE CARBÓN DISULFIDE

A 14.2943 15.1206 15.8667 14.7171 14.8766 13.7462 14.8321 14.2095 15.4940 15.0205 13.9153 14.1603 14.4481 14.7812 14.2978 15.3768 15.2388

B 4470.9200 2845.2500 4097.8600 2975.9500 3366.4900 2452.0600 1836.6600 3033.1000 2363.2400 4103.5200 832.7800 2948.7800 4415.3600 3090.8600 3650.7700 1956.2500 3549.9000

18

CARBÓN MONOXIDE

13.8722

769.9300

19

CARBÓN TET

14.6247

3394.4600

20 21 22 23 24 25 26 27

CHLORINE CHLOROACETYL-CL CHLOROBENZENE CHLOROFORM CHRYSENE CIS-2-BUTENE CIS-2-PENTENE CYCLOHEXANE

14.1372 14.4140 14.3050 14.5014 14.5890 13.8005 13.7943 13.7865

2055.1500 3068.0900 3457.1700 2938.5500 5915.2600 2209.7600 2451.2800 2794.5800

28 29 30 31 32 33 34 35

CYCLOPENTANE C3ALKYLBENZENE C3ALKYLNAPHTHALENE DICHLOROACETYL-CL DYCYCLOPENTADIENE DIETHYL ETHER DIETHYL KETONE DIETHYLENE GLYCOL

13.8440 14.1013 14.4603 14.8731 14.0053 14.1675 14.3864 17.6738

2590.0300 3634.7200 4553.6500 3393.3900 3599.6900 2563.7300 3128.3600 6034.0800

36

DIMETHYL ACETAMIDE

13.1131

2885.8800

37 38

DIMETHYL ETHER DIMETHYL SULFIDE

14.3448 14.2291

2176.8400 2649.4900

39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84

DIMETHYLACETYLENE DIMETHYLFORMAMIDE ETHANE ETHANOL ETHYL ACETATE ETHYL CHLORIDE ETHYL FORMATE ETHYL MERCAPTAN ETHYLACETYLENE ETHYLAMINE ETHYLBENZENE ETHYLCYCLOHEXANE ETHYLCYCLOPENTANE ETHYLENE ETHYLENE GLYCOL ETHYLENE OXIDE FLUORANTHENE FLUORENE FORMALDEHYDE FURFURAL HYDROGEN HYDROGEN CHLORIDE HYDROGEN CYANIDE HYDROGEN IODIDE HYDROGEN SULFIDE INDAN INDENE IODOBENZENE ISO-BUTANE ISO-BUTANOL ISO-BUTENE ISO-BUTYRALDEHYDE ISO-PENTANE ISO-PROPANOL M-DICHLOROBENZENE M-XYLENE MEK METHACRYLONITRILE METHANE METHANOL METHYL ACETATE METHYL CHLORIDE METHYL FORMATE METHYL IODIDE METHYL PROPIONATE METHYLACETYLENE

14.1712 13.7554 13.8797 16.1952 14.5813 14.2656 14.4017 14.2423 14.0641 14.4758 13.9698 13.8180 13.8290 13.8182 16.1847 14.5116 14.4374 16.2019 14.3483 16.7802 12.7844 14.7081 15.4856 14.3749 14.5513 14.2465 14.4233 14.1448 13.8137 15.4994 13.9102 14.8510 13.6106 15.6491 19.6415 14.1146 14.2173 14.0891 13.5840 16.4948 14.7074 14.3114 14.7233 14.1329 14.5705 13.8153

2490.4100 3147.6900 1582.1800 3423.5300 3022.2500 2458.2100 2758.6100 2616.5100 2279.5200 2407.6000 3257.1700 3195.0300 2983.2000 1427.2200 4493.7900 2478.1200 5438.7700 6462.5900 2161.3300 5365.8800 232.3200 1802.2400 3151.5300 2133.5200 1964.3700 3789.8500 3994.9700 3807.9800 2150.2300 3246.5100 2196.4900 2998.0500 2345.0900 3109.3400 8584.1600 3360.8100 2831.8200 2951.9100 968.1300 3593.3900 2917.7000 2170.0200 2726.0500 2688.8900 3034.7100 1927.9900

85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132

METHYLAMINE METHYLCYCLOHEXANE METHYLCYCLOPENTANE METHYLSTYRENE N-BUTANE N-BUTANOL N-BUTYLBENZENE N-BUTYLCYCLOHEXANE N-BUTYRIC ACID N-DECANE N-DODECANE N-HEPTANE N-HEXADECANE N-HEXANE N-NONANE N-OCTANE N-PENTADECANE N-PENTANE N-PROPANOL N-PROPYL ACETATE N-PROPYL BENZENE N-PROPYLCYCLOHEXANE N-PROPYLCYCLOPENTANE N-TETRADECANE N-TRIDECANE N-UNDECANE NAPHTHALENE NEO-PENTANE NEON NITRIC OXIDE NITROGEN NITROGEN DIOXIDE NITROUS OXIDE O-CRESOL O-DICHLOROBENZENE O-XYLENE OXYGEN P-DICHLOROBENZENE P-XYLENE PHENANTHRENE PHENOL PHOSGENE PROPADIENE PROPANE PROPIONIC ACID PROPYL FORMATE PROPYLENE PYRENE

14.8909 13.7630 13.8064 14.2319 13.9836 14.6961 14.0579 13.8938 15.8498 13.9899 14.0587 13.9008 14.1586 14.0568 13.9548 14.2368 14.1466 13.9778 15.2175 14.4147 13.9908 13.8648 13.8962 14.1267 14.1069 14.7851 13.7520 13.7626 13.4710 16.9196 13.4477 21.9837 14.2447 14.2678 14.3011 14.1257 13.6835 15.0839 14.0891 13.5159 15.2767 14.5141 10.9901 13.7097 15.4276 14.2663 13.8782 14.4694

2342.6500 2965.7600 2742.4700 3687.8300 2292.4400 2902.9600 3630.4800 3538.8700 4096.0700 3452.2200 3744.0100 2932.7200 4205.3200 2825.4200 3290.5600 3304.1600 4111.2800 2554.6000 3008.3100 3109.0600 3433.5100 3377.5600 3196.7100 4001.9300 3886.5000 4152.9200 3701.4800 2304.4600 264.7300 1319.1100 658.2200 6615.3600 1547.5600 3552.7400 3776.9700 3412.0200 780.2600 4318.4700 3351.6900 4397.2200 4027.9800 2525.4300 1017.7800 1872.8200 3761.1400 2903.2700 1875.2500 5203.0800

133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 1000

STYRENE SULFUR DIOXIDE SULFUR TRIOXIDE T-BUTYL ALCOHOL TETRAETHENE GLYCOL THIOPHENE TOLUENE TRANS-2-BUTENE TRANS-2-PENTENE TRICHLOROACETYL-CL TRICHLOROETHYLENE TRIETHYLENE GLYCOL TRIMETHYLAMINE VINYLACETYLENE VINYL CHLORIDE WATER 1-BUTENE 1-ET-2-ME-BENZENE 1-HEPTENE 1-HEXENE 1-ME-4-ETH-NAPHTHA 1-METHYLINDENE 1-METHYLNAPHTHALEN 1-PENTENE 1-PHENYLINDENE 1-PHENYLNAPHTHALEN 1,1-DICHLOROETHANE 1,2-BUTADIENE 1,2-DICHLOROETHANE 1,2-DIME-3-ETHYLBENZENE 1,2,3-TRIME-INDENE 1,2,4-TRI-CL-BENZENE 1,3-BUTADIENE 1,1,2-TRI-CL-ETHANE 2-ETHYLFLUORENE 2-ME-1-BUTENE 2-ME-2-BUTENE 2-METHYLINDENE 2-METHYLNAPHTHALENE 2-METHYLPENTANE 2,2-DIMETHYLBUTANE 2,3-DIMETHYLBUTANE 2,3,5-TRIME-NAPHTHALENE 2,7-DIMETHYLNAPHTHALENE 3-ME-1-BUTENE 3-METHYLPENTANE VACÍO

14.3284 14.9404 13.8467 14.4678 18.5419 14.0097 14.2515 13.8064 13.8847 14.0716 14.3346 17.8140 13.8650 13.7861 13.6163 16.5362 13.8817 14.2225 13.8747 13.7987 14.6221 14.2498 14.2604 13.7564 14.4020 14.9544 13.8796 14.4754 14.3572 14.2290 14.3343 14.8831 14.0719 15.3614 14.5052 13.8288 13.9011 14.2838 14.2625 13.7266 13.5436 13.6654 14.6112 14.7849 13.7142 13.7492 0.0000

3516.4300 2385.0000 1777.6600 2490.4400 8215.2800 2869.3000 3242.3800 2213.5600 2495.4000 3195.5400 3131.2100 6589.0300 2239.1000 2155.4600 2027.8000 3985.4400 2189.4500 3633.9400 2895.9000 2657.3400 4574.4900 3939.2200 4265.0000 2409.1100 4872.8800 5351.0400 2607.8100 2580.4800 3069.0800 3799.0400 4165.4200 4452.4900 2280.9600 3865.8300 4789.4400 2435.9270 2517.6000 4013.0500 4238.9700 2611.4700 2492.3200 2595.9900 4648.0000 4734.1700 2338.9800 2650.2900 0.0000

r y temperaturas de saturación y balances" de R. V. Reklaitis v en kPa, T en K

peratura, en K, a la cual se desea la presión de vapor de alguno de los componentes de la tabla.

por, en kPa, a la cual se desea la temperatura de saturación de alguno de los componentes de la tabla. Tsaturación

Pvapor

Pvapor

C -81.1694 -22.0670 -27.4937 -34.5228 -26.6513 -55.2968 -8.4521 -34.9326 -22.6207 -62.7983 2.3608 -44.5633 -79.1919 -27.9733 -52.4382 -2.1117 15.1796

K 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 276.766 373.150 373.150 306.656 373.150 373.150 373.150 373.150 373.150

kPa 0.361 1114.756 55.224 375.712 174.315 416.447 17961.512 188.972 490.402 6.040 120279.583 18.346 0.564 339.262 18.439 24451.167 444.673

mmHg 2.711 8363.423 414.316 2818.764 1307.792 3124.377 134755.671 1417.757 3679.223 45.312 902393.714 137.638 4.233 2545.300 138.338 183444.099 3336.143

1.6369

373.150

135657.138

1017763.323

-10.2163

373.150

194.778

1461.318

-23.3117 -65.9202 -48.5524 -36.9972 -127.8828 -36.2080 -42.9501 -49.1081

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

3876.271 83.738 38.643 317.250 0.000 1397.192 584.453 174.577

29081.596 628.244 289.918 2380.160 0.001 10482.390 4384.837 1309.762

-41.6716 -54.9383 -87.2011 -50.2758 -59.0556 -39.3707 -54.4122 -53.2122

373.150 373.150 373.150 373.150 373.150 285.150 373.150 373.150

415.893 14.570 0.231 78.504 12.740 41.950 96.695 0.305

3120.227 109.311 1.735 588.977 95.583 314.727 725.451 2.291

-100.3239

373.150

12.621

94.690

-24.6733 -34.8672

373.150 373.150

3288.115 599.997

24668.974 4501.461

-39.4293 -81.3422 -13.7622 -55.7152 -47.8833 -30.6994 -45.7813 -36.3192 -39.9148 -45.7539 -61.0096 -57.6333 -52.7198 -14.3080 -82.1026 -33.1582 -112.2578 -13.1696 -31.9756 5.6186 8.0800 -9.6678 -8.8383 -19.6195 -15.2417 -56.8344 -49.2317 -61.9621 -27.6228 -82.6994 -29.8630 -44.6533 -40.2128 -73.5459 123.8591 -58.3463 -57.3831 -51.7254 -3.7200 -35.2249 -41.3724 -25.2701 -35.3556 -33.1607 -48.3091 -40.3166

373.150 373.150 373.150 315.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

819.457 19.463 13059.472 20.067 198.283 1196.683 393.502 648.249 1371.316 1238.946 34.290 40.111 91.745 18786.736 2.106 1370.370 0.002 0.174 3020.957 13.647 193881.824 17151.449 929.790 4188.104 8628.510 9.634 8.085 6.739 1979.617 75.332 1829.491 306.257 711.204 194.598 10.696 31.147 190.419 134.999 57722.094 351.114 369.909 3208.496 775.226 504.794 186.486 3049.223

6147.952 146.024 97978.270 150.554 1487.610 8978.079 2952.233 4863.469 10288.254 9295.156 257.258 300.934 688.316 140946.885 15.798 10281.156 0.012 1.303 22664.630 102.390 1454592.163 128678.197 6975.716 31421.117 64735.119 72.277 60.659 50.558 14852.015 565.176 13725.694 2297.683 5335.785 1459.968 80.246 233.677 1428.615 1012.825 433058.156 2634.225 2775.227 24071.638 5816.107 3787.203 1399.107 22876.700

-38.7081 -49.7775 -46.5148 -59.6117 -27.8623 -102.9116 -71.8524 -72.5651 -71.7697 -78.8993 -92.8311 -55.6356 -119.1482 -42.7089 -71.5056 -55.2278 -112.2870 -36.2529 -86.4909 -57.6803 -66.0278 -64.5934 -59.5494 -105.7783 -98.9840 -60.4933 -85.8319 -30.6944 2.8276 -14.1427 -2.8540 86.8780 -23.9090 -95.9752 -63.6069 -58.6824 -4.1758 -35.3413 -57.6000 -119.2937 -76.7014 -26.1643 -78.9447 -25.1011 -66.0009 -53.5214 -22.9101 -106.9889

373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 308.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

2660.436 98.658 223.693 11.822 1547.480 52.137 7.452 8.335 9.571 9.561 2.019 106.092 0.091 30.343 21.032 46.703 0.199 598.885 112.519 95.523 16.630 18.513 40.554 0.431 0.933 4.493 2.385 1133.854 350420.417 565391.449 117025.726 2004.917 18278.680 4.264 8.161 26.458 105749.292 9.975 32.052 0.022 5.415 1388.395 1864.371 4141.401 24.102 178.224 5034.214 0.006

19959.837 740.177 1678.250 88.691 11609.917 391.159 55.905 62.537 71.808 71.729 15.145 795.951 0.682 227.645 157.794 350.391 1.494 4493.114 844.167 716.656 124.762 138.894 304.253 3.236 7.004 33.705 17.892 8506.700 2629017.936 4241831.208 877981.753 15041.825 137135.207 31.987 61.226 198.499 793380.669 74.840 240.469 0.167 40.629 10416.390 13987.383 31070.729 180.821 1337.117 37769.032 0.047

-56.1529 -32.2139 -125.1972 -102.7144 -11.3276 -51.7869 -47.1806 -33.1109 -40.2073 -53.3269 -37.7666 -57.0789 -33.8347 -43.4786 -33.5344 -38.9974 -30.5161 -59.9427 -53.9388 -47.1749 -90.9617 -64.3544 -75.4697 -39.4834 -97.1067 -81.5154 -48.9442 -22.2012 -42.3468 -71.7621 -76.5467 -52.7852 -27.5956 -26.6188 -97.7600 -39.9270 -40.5046 -66.1650 -74.6666 -46.7064 -43.6494 -44.1960 -93.0922 -71.3275 -36.0646 -46.1716 0.0000

373.150 373.150 373.150 373.150 373.150 373.150 321.750 373.150 373.150 373.150 294.260 373.150 373.150 373.150 373.150 308.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150 373.150

25.418 2821.303 794.213 192.252 0.016 160.962 11.502 1475.391 595.688 59.146 8.388 0.048 1430.991 1405.140 2091.071 5.634 1792.996 13.738 121.833 283.363 0.204 4.451 0.935 689.722 0.039 0.034 342.377 1239.586 160.700 5.073 1.337 2.678 1756.413 67.061 0.056 677.629 562.663 3.358 1.063 306.998 395.309 321.742 0.137 0.406 875.999 282.535 1.000

190.698 21166.738 5958.557 1442.362 0.117 1207.615 86.295 11069.070 4469.128 443.743 62.933 0.362 10735.967 10542.021 15688.195 42.270 13451.898 103.068 914.047 2125.919 1.532 33.392 7.016 5174.617 0.291 0.252 2568.674 9299.953 1205.646 38.057 10.032 20.088 13177.434 503.126 0.419 5083.887 4221.359 25.193 7.973 2303.243 2965.795 2413.858 1.030 3.049 6572.154 2119.709 7.502

omponentes de la tabla.

e los componentes de la tabla. Pvapor

Pvapor

Tsaturación

Tsaturación

psía 0.052 161.766 8.014 54.521 25.295 60.432 2606.458 27.422 71.164 0.876 17454.194 2.662 0.082 49.231 2.676 3548.195 64.528

kPa 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 534.740 101.300 101.300 86.638 101.300 101.300 101.300 101.300 101.300

K 543.222 292.978 391.793 329.200 354.817 323.924 188.270 351.163 279.154 457.276 87.212 348.606 528.363 332.099 429.595 183.941 319.063

°C 270.072 19.828 118.643 56.050 81.667 50.774 -84.880 78.013 6.004 184.126 -185.938 75.456 255.213 58.949 156.445 -89.209 45.913

19685.685

101.300

81.562

-191.588

28.265

259.914

384.701

111.551

562.499 12.152 5.608 46.037 0.000 202.751 84.812 25.334

101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300

239.209 379.121 405.443 334.322 721.134 276.859 310.084 353.913

-33.941 105.971 132.293 61.172 447.984 3.709 36.934 80.763

60.352 2.114 0.034 11.392 1.849 6.087 14.032 0.044

101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300

322.406 438.218 549.866 381.176 442.523 307.841 374.668 515.391

49.256 165.068 276.716 108.026 169.373 34.691 101.518 242.241

1.831

101.300

440.038

166.888

477.150 87.068

101.300 101.300

248.473 310.539

-24.677 37.389

118.914 2.824 1895.106 2.912 28.774 173.655 57.102 94.070 198.996 179.788 4.976 5.821 13.313 2726.209 0.306 198.859 0.000 0.025 438.382 1.980 28134.875 2488.907 134.925 607.751 1252.113 1.398 1.173 0.978 287.269 10.932 265.484 44.442 103.205 28.239 1.552 4.520 27.632 19.590 8376.256 50.951 53.679 465.596 112.496 73.252 27.062 442.484

101.300 101.300 101.300 3.576 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 91.170 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300

300.120 425.830 184.594 285.161 351.224 285.502 327.744 308.187 281.236 289.989 409.306 404.922 376.596 169.439 470.616 283.637 666.143 571.068 254.101 435.578 20.369 188.284 298.834 238.289 212.999 450.445 456.665 461.678 261.455 381.056 266.245 337.634 300.995 355.418 447.526 408.362 352.389 363.404 111.699 337.783 330.560 249.138 305.122 315.761 353.231 249.944

26.970 152.680 -88.556 12.011 78.074 12.352 54.594 35.037 8.086 16.839 136.156 131.772 103.446 -103.711 197.466 10.487 392.993 297.918 -19.049 162.428 -252.781 -84.866 25.684 -34.861 -60.151 177.295 183.515 188.528 -11.695 107.906 -6.905 64.484 27.845 82.268 174.376 135.212 79.239 90.254 -161.451 64.633 57.410 -24.012 31.972 42.611 80.081 -23.206

386.065 14.317 32.461 1.715 224.560 7.566 1.081 1.210 1.389 1.387 0.293 15.395 0.013 4.403 3.052 6.777 0.029 86.906 16.328 13.862 2.413 2.686 5.885 0.063 0.135 0.652 0.346 164.537 50850.742 82045.946 16982.015 290.941 2652.484 0.619 1.184 3.839 15345.652 1.448 4.651 0.003 0.786 201.475 270.545 600.973 3.497 25.863 730.533 0.001

101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 206.735 101.300 101.300 86.638 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300

266.752 374.085 344.989 443.209 272.637 390.960 456.445 454.085 436.458 447.261 489.417 371.569 559.934 342.053 423.938 398.742 543.758 309.189 370.309 375.041 432.358 429.865 404.092 526.652 508.572 468.963 491.078 282.699 27.076 121.374 77.401 294.068 184.668 464.146 453.668 446.665 90.246 447.968 405.742 613.485 454.610 281.361 238.671 231.095 413.948 354.434 225.418 635.150

-6.398 100.935 71.839 170.059 -0.513 117.810 183.295 180.935 163.308 174.111 216.267 98.419 286.784 68.903 150.788 125.592 270.608 36.039 97.159 101.891 159.208 156.715 130.942 253.502 235.422 195.813 217.928 9.549 -246.074 -151.776 -195.749 20.918 -88.482 190.996 180.518 173.515 -182.904 174.818 132.592 340.335 181.460 8.211 -34.479 -42.055 140.798 81.284 -47.732 362.000

3.689 409.409 115.251 27.898 0.002 23.358 1.669 214.099 86.442 8.583 1.217 0.007 207.656 203.905 303.443 0.818 260.188 1.994 17.680 41.120 0.030 0.646 0.136 100.088 0.006 0.005 49.684 179.881 23.320 0.736 0.194 0.389 254.879 9.732 0.008 98.333 81.650 0.487 0.154 44.550 57.365 46.689 0.020 0.059 127.119 41.000 0.145

101.300 101.300 101.300 101.300 101.300 101.300 86.638 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 735.480 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300 101.300

418.286 263.267 317.822 355.558 601.344 357.304 378.382 274.021 309.497 391.354 360.023 556.402 275.980 278.585 258.890 440.122 266.866 438.304 366.785 336.626 548.227 473.339 517.791 303.111 595.157 599.209 330.519 283.984 357.476 467.046 505.255 486.539 268.870 386.455 582.172 304.394 311.710 481.349 514.193 333.413 322.885 331.131 558.213 536.977 293.205 336.420 0.000

145.136 -9.883 44.672 82.408 328.194 84.154 105.232 0.871 36.347 118.204 86.873 283.252 2.830 5.435 -14.260 166.972 -6.284 165.154 93.635 63.476 275.077 200.189 244.641 29.961 322.007 326.059 57.369 10.834 84.326 193.896 232.105 213.389 -4.280 113.305 309.022 31.244 38.560 208.199 241.043 60.263 49.735 57.981 285.063 263.827 20.055 63.270 -273.150

Presión de vapor y temperat

Colocar en la celda Num, el número de i Tsaturación °F 518.130 67.691 245.557 132.890 179.000 123.393 -120.784 172.424 42.807 363.427 -302.688 167.821 491.384 138.107 313.601 -128.576 114.644

Num 12 139 123 1000 1000 1000 1000 1000 1000 1000

celda amarilla la temperatura, en K, o en la ce Compuesto yi BENZENE 0.4513 TOLUENE 0.3826 P-XYLENE 0.1661 VACÍO 0.0000 VACÍO 0.0000 VACÍO 0.0000 VACÍO 0.0000 VACÍO 0.0000 VACÍO 0.0000 VACÍO 0.0000 1.0000

Cálculo de la presión parcial, conocien la saturación porcentual:

-312.859

SP =

0.65000

kPa

232.792

PT =

dato

230.000

-29.094 222.748 270.128 142.109 838.372 38.677 98.482 177.374

PV =

dato

45.82400 32.01831

120.661 329.122 530.089 226.447 336.871 94.443 214.733 468.035 332.399

p =

Elegir la columna con las unidades de presión que se dese

Temperatura de saturación

Num 12

Colocar en la celda amarilla Num, el núme celdas amarillas la temperatura, en K, y el núme real del volumen que se tie Compuesto yi BENZENE 1.0000

V

=

(

-12.418 99.301 80.546 306.823 -127.400 53.620 172.534 54.233 130.268 95.066 46.554 62.310 277.081 269.190 218.204 -154.680 387.440 50.877 739.387 568.252 -2.288 324.370 -423.007 -120.759 78.231 -30.749 -76.271 351.132 362.327 371.351 10.949 226.231 19.571 148.072 82.122 180.083 345.877 275.382 174.629 194.457 -258.612 148.339 135.337 -11.222 89.550 108.700 176.146 -9.770

Tsaturación =

20.483 213.682 161.309 338.106 31.076 244.059 361.931 357.683 325.954 345.400 421.280 209.154 548.211 156.025 303.418 258.065 519.095 96.869 206.887 215.404 318.575 314.087 267.696 488.304 455.759 384.464 424.270 49.188 -410.934 -241.196 -320.348 69.652 -127.268 375.792 356.933 344.327 -297.228 346.672 270.666 644.603 358.628 46.780 -30.062 -43.698 285.437 178.311 -53.917 683.600

293.246 14.210 112.410 180.335 622.749 183.477 221.417 33.568 97.424 244.766 188.372 541.854 37.095 41.783 6.332 332.549 20.688 329.277 200.544 146.257 527.139 392.340 472.354 85.929 611.612 618.906 135.264 51.502 183.787 381.013 449.789 416.100 24.295 235.948 588.240 88.239 101.407 406.758 465.877 140.473 121.523 136.366 545.113 506.888 68.099 145.886 -459.670

apor y temperatura de saturación de una mezcla multicomponente

a Num, el número de identificación de cada uno de los componentes de la tabla. Colocar en la

atura, en K, o en la celda azul la presión de vapor, en kPa, según se tenga y calcular la otra variable. A B C Tsat, K Pv, kPa Pv, mmHg 14.1603 2948.78 -44.5633 298.150 12.579 94.372 14.2515 3242.38 -47.1806 298.15 3.789 28.426 14.0891 3351.69 -57.6 298.15 1.168 8.766 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 0 0 0 298.15 1.000 7.502 298.150 7.321 54.923 Tsat, K

ón parcial, conociendo ón porcentual: atm

mmHg

psía

14.47370

###

212.76310

0.74304 0.49181

564.71076 373.77806

10.92270 7.22966

presión que se desean y trabajar con ella.

a de saturación y presión de una mezcla gas - vapor que se enfría.

marilla Num, el número de identificación de la tabla, del componente vapor. Colocar en las otras atura, en K, y el número de gmol de la mezcla gaseosa. Comparar el valor del V calculado, con el valor del volumen que se tiene. Iterar con los valores de la temperatura de saturación. A B C Tsat, K Pv, kPa Pv, mmHg 14.1603 2948.78 -44.5633 313.150 24.081 180.667

22.4

)

l

* ( 14.560

) gmol

*

Tsat. en K) *

101.3

gmol 313.150

K

Pvapor = 24.081

kPa

V

273.15

K

1572.878

l.

Pvapor a Tsat.

ponente

ocar en la

r la otra variable. Pv, psía 1.825 0.550 0.170 0.145 0.145 0.145 0.145 0.145 0.145 0.145 1.062

enfría.

r en las otras culado, con el valor Pv, psía 3.494

kPa

Pv, kPa 310.984 310.984 310.984 310.984 310.984 310.984 310.984 310.984 310.984 310.984 310.984 Pv, kPa

Tsat, K 394.75 428.11 459.03 0.00 0.00 0.00 0.00 0.00 0.00 0.00 418.189

Tsat, °C 121.60 154.96 185.88 -273.15 -273.15 -273.15 -273.15 -273.15 -273.15 -273.15 145.039

Tsat, °F 250.88 310.93 366.59 -459.67 -459.67 -459.67 -459.67 -459.67 -459.67 -459.67 293.071

Pvapor a Tsat.

Propiedades generales de los "Mass and en

Tabla de diversas propiedades para diversos compues

Num. 1 2 3 4 5 6 7 8 9

Compuesto ACENAPHTHYLENE ACETALDEHYDE ACETIC ACID ACETONE ACETONITRILE ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA

10 11

ANILINE ARGON

12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39

BENZENE BIPHENYL BROMINE BROMOBENZENE CARBÓN DIOXIDE CARBÓN DISULFIDE CARBÓN MONOXIDE CARBÓN TET CHLORINE CHLOROACETYL-CL CHLOROBENZENE CHLOROFORM CHRYSENE CIS-2-BUTENE CIS-2-PENTENE CYCLOHEXANE CYCLOPENTANE C3ALKYLBENZENE C3ALKYLNAPHTHALENE DICHLOROACETYL-CL DYCYCLOPENTADIENE DIETHYL ETHER DIETHYL KETONE DIETHYLENE GLYCOL DIMETHYL ACETAMIDE DIMETHYL ETHER DIMETHYL SULFIDE DIMETHYLACETYLENE

Tb

Peso molecular 152.180 78.108 92.134 106.160 41.052 78.500 26.036 53.060 17.032

K 543.161 353.261 383.786 411.511 354.761 324.081 188.401 350.461 239.731

93.116 39.944

457.291 87.291

78.108 154.200 159.830 157.020 44.011 76.130 28.010 153.840 70.914 112.950 112.557 119.389 228.270 56.100 70.130 84.160 70.130 120.200 170.200 147.390 132.196 74.120 86.140 106.120 87.120 46.068 62.134 54.090

353.261 528.361 331.921 429.361 194.681 319.400 81.691 349.700 239.111 382.161 405.361 334.891 721.161 276.883 310.106 353.900 322.422 438.161 549.861 380.661 443.161 307.711 374.961 518.800 440.161 248.321 310.501 300.200

40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87

DIMETHYLFORMAMIDE ETHANE ETHANOL ETHYL ACETATE ETHYL CHLORIDE ETHYL FORMATE ETHYL MERCAPTAN ETHYLACETYLENE ETHYLAMINE ETHYLBENZENE ETHYLCYCLOHEXANE ETHYLCYCLOPENTANE ETHYLENE ETHYLENE GLYCOL ETHYLENE OXIDE FLUORANTHENE FLUORENE FORMALDEHYDE FURFURAL HYDROGEN HYDROGEN CHLORIDE HYDROGEN CYANIDE HYDROGEN IODIDE HYDROGEN SULFIDE INDAN INDENE IODOBENZENE ISO-BUTANE ISO-BUTANOL ISO-BUTENE ISO-BUTYRALDEHYDE ISO-PENTANE ISO-PROPANOL M-DICHLOROBENZENE M-XYLENE MEK METHACRYLONITRILE METHANE METHANOL METHYL ACETATE METHYL CHLORIDE METHYL FORMATE METHYL IODIDE METHYL PROPIONATE METHYLACETYLENE METHYLAMINE METHYLCYCLOHEXANE METHYLCYCLOPENTANE

73.094 30.068 46.068 88.100 64.517 74.080 62.134 54.088 45.084 106.160 112.210 98.180 28.056 62.070 44.052 202.258 166.223 30.010 96.080 2.016 36.465 27.030 127.910 34.082 118.170 116.163 204.020 58.120 74.120 56.100 72.110 72.150 60.094 147.010 106.160 72.104 67.090 16.042 32.042 74.080 50.491 60.050 141.950 88.100 40.062 31.058 98.180 84.160

426.161 184.531 351.481 350.261 285.431 327.500 308.161 281.251 289.741 409.344 404.944 376.628 169.451 470.600 283.661 666.161 571.061 253.961 434.861 20.381 188.127 298.861 237.781 212.820 450.161 455.161 461.491 261.431 381.600 266.261 337.161 301.011 355.421 446.161 412.267 352.751 363.461 111.671 337.671 330.411 248.941 304.941 315.661 353.100 249.894 266.711 374.094 344.972

88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135

METHYLSTYRENE N-BUTANE N-BUTANOL N-BUTYLBENZENE N-BUTYLCYCLOHEXANE N-BUTYRIC ACID N-DECANE N-DODECANE N-HEPTANE N-HEXADECANE N-HEXANE N-NONANE N-OCTANE N-PENTADECANE N-PENTANE N-PROPANOL N-PROPYL ACETATE N-PROPYL BENZENE N-PROPYLCYCLOHEXANE N-PROPYLCYCLOPENTANE N-TETRADECANE N-TRIDECANE N-UNDECANE NAPHTHALENE NEO-PENTANE NEON NITRIC OXIDE NITROGEN NITROGEN DIOXIDE NITROUS OXIDE O-CRESOL O-DICHLOROBENZENE O-XYLENE OXYGEN P-DICHLOROBENZENE P-XYLENE PHENANTHRENE PHENOL PHOSGENE PROPADIENE PROPANE PROPIONIC ACID PROPYL FORMATE PROPYLENE PYRENE STYRENE SULFUR DIOXIDE SULFUR TRIOXIDE

118.200 58.120 74.120 134.212 140.260 88.104 142.280 170.328 100.200 226.430 86.172 128.250 114.220 212.410 72.150 60.094 102.130 120.186 126.234 112.208 198.380 184.350 156.300 128.164 72.146 20.183 30.010 28.016 46.010 44.020 108.134 147.010 106.160 32.000 147.010 106.160 178.220 94.108 98.930 40.060 44.094 74.078 88.100 42.080 202.258 104.144 64.066 80.066

443.161 272.661 390.891 456.467 454.108 436.431 447.283 489.439 371.589 559.956 341.901 423.961 398.828 543.789 309.233 370.371 374.711 432.378 429.885 404.111 526.733 508.600 469.050 491.116 282.664 27.300 121.400 77.361 294.500 183.700 464.165 452.161 417.572 90.181 447.061 411.511 612.761 455.000 280.721 238.661 231.091 414.151 354.500 225.461 635.161 418.301 263.145 317.911

136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 1000

T-BUTYL ALCOHOL TETRAETHENE GLYCOL THIOPHENE TOLUENE TRANS-2-BUTENE TRANS-2-PENTENE TRICHLOROACETYL-CL TRICHLOROETHYLENE TRIETHYLENE GLYCOL TRIMETHYLAMINE VINYLACETYLENE VINYL CHLORIDE WATER 1-BUTENE 1-ET-2-ME-BENZENE 1-HEPTENE 1-HEXENE 1-ME-4-ETH-NAPHTHA 1-METHYLINDENE 1-METHYLNAPHTHALEN 1-PENTENE 1-PHENYLINDENE 1-PHENYLNAPHTHALEN 1,1-DICHLOROETHANE 1,2-BUTADIENE 1,2-DICHLOROETHANE 1,2-DIME-3-ETHYLBENZENE 1,2,3-TRIME-INDENE 1,2,4-TRI-CL-BENZENE 1,3-BUTADIENE 1,1,2-TRI-CL-ETHANE 2-ETHYLFLUORENE 2-ME-1-BUTENE 2-ME-2-BUTENE 2-METHYLINDENE 2-METHYLNAPHTHALENE 2-METHYLPENTANE 2,2-DIMETHYLBUTANE 2,3-DIMETHYLBUTANE 2,3,5-TRIME-NAPHTHALENE 2,7-DIMETHYLNAPHTHALENE 3-ME-1-BUTENE 3-METHYLPENTANE VACÏO

74.120 194.230 84.130 92.134 56.100 70.130 181.830 131.400 150.170 59.110 52.072 62.501 18.016 56.100 120.186 98.180 84.160 182.350 130.190 142.190 70.130 192.240 204.260 98.966 54.090 98.966 134.212 158.229 181.455 54.090 133.415 194.279 70.130 70.130 130.190 142.190 86.170 86.170 86.170 182.350 156.216 70.130 86.170 0.001

355.581 592.100 357.361 383.786 274.039 309.517 391.161 360.061 560.400 276.031 278.711 259.461 373.161 266.900 438.161 366.806 336.644 548.161 473.161 517.803 303.128 595.161 598.161 330.441 284.011 356.631 467.071 505.161 486.641 268.750 386.931 582.161 304.322 311.728 481.161 514.213 333.433 322.900 331.150 558.161 536.161 293.222 336.444

generales de los gases y cálculo del calor latente de vaporización "Mass and energy balances" de R. V. Reklaitis

para diversos compuestos. Cálculo del calor latente de vaporización, utilizando la ecuación de Watson; colo λb

Tc

Pc

Treal

KJ/Kgmol 48485.800 30763.400 33460.600 35928.900 31510.700 46227.900 16419.100 32630.100 23351.000

K 796.917 461.161 594.761 509.461 547.861 507.921 308.341 519.161 405.661

Kpa 3220.950 5552.630 5785.680 4782.560 4833.220 5741.600 6138.290 3536.250 11402.140

K 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000

43165.800 6527.000

698.761 150.651

5299.320 4863.620

300.000 130.000

30763.400 49212.900 29413.800 37823.600 16560.900 26334.400 6065.300 36882.100 20410.000 57030.500 36449.700 29470.100 68034.600 23462.900 25617.700 29975.300 27246.000 38267.800 48678.500 58136.700 37279.400 26693.300 33178.100 52314.600 39293.600 21510.100 26998.900 26485.000

562.611 788.861 584.161 670.161 304.201 552.000 132.951 556.400 417.161 585.991 632.361 536.561 993.611 433.161 478.111 552.961 511.761 653.161 774.861 577.291 660.372 466.761 560.961 681.040 656.672 400.061 503.061 488.700

4924.410 3840.230 10335.190 4519.110 7380.540 7903.380 3498.650 4559.640 7710.860 5106.900 4523.110 5471.570 2388.270 4205.800 3530.120 4078.250 4514.000 3141.110 2583.810 4609.390 3060.650 3607.190 3738.900 4605.440 4024.680 5268.920 5532.370 5084.500

349.032 300.000 300.000 300.000 300.000 300.000 120.000 384.701 300.000 300.000 405.443 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 285.150 300.000 300.000 300.000 300.000 300.000 300.000

38080.700 14715.600 38577.300 32269.400 24685.800 30058.900 26778.300 24726.100 27565.200 35998.200 34659.600 32094.100 13544.100 49629.600 25526.500 61549.700 50840.000 23304.000 43124.700 1334.600 16150.300 26891.500 20542.700 18678.300 39007.400 39732.000 39496.100 21291.800 41253.900 22050.600 31272.900 24710.200 39874.900 38593.900 36247.600 31268.600 31798.300 8179.500 35270.400 27932.300 21400.000 28066.700 27173.500 32214.200 22282.100 25815.500 31284.900 29127.600

596.900 305.561 516.261 523.261 460.361 508.500 499.161 463.722 456.161 619.722 602.611 569.461 283.061 645.200 468.161 936.589 822.259 415.161 657.122 33.191 324.561 456.661 423.161 373.561 681.056 691.944 721.161 408.141 547.700 417.889 505.383 461.000 508.331 683.961 619.222 535.661 554.567 191.061 513.161 506.861 416.261 487.161 528.161 530.600 402.391 430.061 572.333 532.772

4709.800 4894.020 6379.440 3830.100 5268.920 4691.370 5491.830 4710.640 5623.560 3723.170 3129.530 3397.740 5116.940 7528.480 7194.100 2606.560 2993.500 6788.800 4924.440 1315.230 8263.080 4954.810 8207.350 9007.820 3630.710 3817.140 4521.240 3647.710 4295.160 3997.580 4198.910 3330.170 4764.320 3880.760 3516.330 4154.340 3883.820 4640.700 7954.040 4694.560 6677.340 6003.530 7315.690 3982.090 5627.500 7457.550 3477.720 3785.220

300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 250.000 300.000 300.000 500.000 300.000 300.000 300.000 30.000 200.723 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 353.826 300.000 300.000 180.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000

38478.600 22416.000 43803.900 39243.500 38492.900 45140.900 39938.800 43685.100 32128.700 51142.900 28851.300 37537.900 34940.800 50070.200 25937.300 41221.700 34213.200 38241.800 36063.800 34107.800 48051.100 46495.900 42150.300 42180.900 22752.400 1738.800 13778.000 5577.500 38117.000 15594.800 45192.300 39937.000 36617.000 6820.500 39193.400 35928.900 55728.700 45693.000 24402.800 19092.800 18773.100 41833.900 32400.700 18372.600 58685.200 36901.100 24915.700 41797.100

662.561 425.172 562.901 660.461 645.761 628.161 618.889 660.161 540.172 725.000 507.861 595.000 569.389 710.000 469.778 536.861 549.361 638.311 619.161 590.261 695.000 677.222 640.000 748.361 433.761 44.500 180.000 126.271 431.000 309.700 697.561 697.261 632.222 154.781 684.761 618.222 878.782 695.061 455.161 400.967 369.971 612.661 538.100 365.111 892.050 636.861 430.661 490.861

3445.030 3796.940 4415.760 2886.760 2439.940 4468.450 2109.800 1803.600 2736.800 1378.950 3033.680 2282.160 2496.590 1516.850 3374.980 5082.200 3334.610 3199.860 2546.200 2802.840 1585.790 1723.690 1944.320 3971.950 3198.840 2725.650 6484.820 3398.450 10132.540 7265.030 5005.470 4104.690 3654.220 5080.450 3906.090 3447.380 2898.580 6130.180 5674.220 5151.420 4256.680 5370.240 4063.350 4598.730 2606.560 1854.630 7893.240 8251.940

300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 40.000 170.000 120.000 300.000 300.000 300.000 300.000 442.807 150.000 300.000 349.032 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000

39037.500 73005.500 34206.400 33460.600 22991.800 25456.400 60524.500 31448.300 60807.500 22950.700 245.354 20801.200 40656.200 22080.600 38867.200 31735.200 28207.400 51463.200 41368.800 45481.600 25412.200 54288.800 55494.900 28976.900 22849.500 31617.200 41790.000 44997.300 43598.600 22472.500 34231.500 53803.200 24937.000 25817.600 42317.400 45202.000 28021.400 26394.500 27404.500 52402.000 48772.100 23173.800 28294.300

506.661 795.750 590.161 593.961 428.161 476.089 589.691 544.161 712.320 433.261 456.251 431.561 647.301 419.611 651.111 535.500 511.111 774.128 703.478 769.161 473.889 843.667 840.083 523.161 450.861 561.561 680.061 720.217 734.961 425.000 612.161 811.061 472.222 483.333 714.567 761.861 498.056 489.389 500.278 788.250 778.161 461.667 504.333 1.00E+100

3971.950 2099.050 4863.620 4053.010 4102.380 3505.160 4099.320 5015.600 3316.380 4073.280 4859.560 5339.840 22109.190 4019.640 3040.590 2842.020 3252.260 2817.130 3327.750 3568.390 4040.330 2695.920 2632.350 5066.270 3985.650 5370.240 3127.750 2648.000 3986.360 4329.910 4834.690 2464.880 3546.660 3637.670 3354.640 3502.920 3034.380 3106.090 3139.870 2817.130 3222.410 3495.640 3124.010 0.000

300.000 300.000 300.000 349.032 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 440.122 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000

e vaporización

ilizando la ecuación de Watson; colocar la temperatura a la que se desea calcular el calor de vaporización en Tr1

Tr2

λreal

λreal

K 0.681578 0.766025 0.645278 0.807738 0.647538 0.638054 0.611015 0.675053 0.590964

K 0.376451 0.650532 0.504404 0.588858 0.547584 0.590643 0.972949 0.577855 0.739534

kJ/kgmol 62592.778 35829.848 37994.834 47960.250 34646.543 48441.584 5962.191 36041.654 19670.781

kJ/kg 411.308 458.722 412.387 451.773 843.967 617.090 228.998 679.262 1154.931

0.654431 0.579425

0.429331 0.862922

52230.310 4262.864

560.917 106.721

0.627896 0.669777 0.568201 0.640683 0.639975 0.578623 0.614444 0.628505 0.573186 0.652162 0.641028 0.624143 0.725798 0.639215 0.648607 0.640009 0.630025 0.670832 0.709625 0.659392 0.671078 0.659247 0.668426 0.761776 0.670290 0.620708 0.617223 0.614283

0.620379 0.380295 0.513557 0.447654 0.986190 0.543478 0.902588 0.691411 0.719147 0.511953 0.641158 0.559116 0.301929 0.692583 0.627469 0.542534 0.586211 0.459305 0.387166 0.519669 0.454289 0.610912 0.534797 0.440503 0.456849 0.749886 0.596349 0.613874

30998.084 62511.867 30776.295 44537.091 4796.787 27148.381 3595.934 34371.462 17409.032 64863.324 36444.696 31312.397 97038.688 22078.206 26192.695 32832.893 28429.747 46210.059 64655.147 66248.958 45187.594 28073.301 37734.215 72365.524 47500.880 18362.214 27549.203 26495.675

396.862 405.395 192.556 283.640 108.991 356.606 128.380 223.423 245.495 574.266 323.789 262.272 425.105 393.551 373.488 390.125 405.386 384.443 379.877 449.481 341.823 378.755 438.057 681.922 545.235 398.589 443.384 489.844

0.713957 0.603909 0.680820 0.669381 0.620016 0.644051 0.617358 0.606508 0.635173 0.660528 0.671982 0.661376 0.598638 0.729386 0.605905 0.711263 0.694503 0.611717 0.661766 0.614052 0.579635 0.654448 0.561916 0.569706 0.660975 0.657800 0.639928 0.640541 0.696732 0.637157 0.667140 0.652952 0.699192 0.652319 0.665782 0.658534 0.655396 0.584478 0.658022 0.651877 0.598041 0.625955 0.597661 0.665473 0.621023 0.620170 0.653630 0.647504

0.502597 0.981801 0.581101 0.573328 0.651662 0.589971 0.601008 0.646939 0.657663 0.484088 0.497834 0.526814 0.883202 0.464972 0.640805 0.533852 0.364849 0.722611 0.456536 0.903859 0.618445 0.656942 0.708950 0.803082 0.440492 0.433561 0.415996 0.735040 0.547745 0.717894 0.593609 0.650759 0.590167 0.438622 0.571404 0.560056 0.540963 0.942107 0.584612 0.591878 0.720702 0.615813 0.568009 0.565398 0.745544 0.697575 0.524170 0.563093

46990.532 4564.957 42775.967 35553.492 23883.408 31718.711 27207.457 23728.082 26906.712 42204.059 40747.855 36445.569 8472.897 64302.945 24642.698 73836.988 67142.274 20508.213 51640.252 787.000 15566.626 26817.575 17586.258 13878.269 47187.311 48118.531 47463.989 18961.559 48019.367 20039.371 33737.058 24769.421 44847.728 46300.669 39840.636 34429.248 35458.835 3867.743 37975.494 29672.104 18635.049 28353.501 27917.783 35582.668 19152.096 23673.974 35297.262 31603.418

642.878 151.821 928.540 403.558 370.188 428.168 437.884 438.694 596.813 397.551 363.139 371.212 301.999 1035.975 559.400 365.063 403.929 683.379 537.471 390.377 426.892 992.141 137.489 407.202 399.317 414.233 232.644 326.248 647.860 357.208 467.855 343.305 746.293 314.949 375.289 477.494 528.526 241.101 1185.179 400.541 369.077 472.165 196.673 403.890 478.061 762.250 359.516 375.516

0.668861 0.641296 0.694422 0.691134 0.703214 0.694776 0.722719 0.741393 0.687909 0.772353 0.673218 0.712539 0.700449 0.765900 0.658253 0.689882 0.682085 0.677378 0.694302 0.684631 0.757889 0.751009 0.732891 0.656255 0.651658 0.613483 0.674444 0.612658 0.683295 0.593155 0.665411 0.648482 0.660483 0.582636 0.652872 0.665636 0.697284 0.654619 0.616751 0.595214 0.624619 0.675987 0.658799 0.617514 0.712024 0.656817 0.611026 0.647660

0.452788 0.705597 0.532953 0.454228 0.464568 0.477585 0.484740 0.454435 0.555379 0.413793 0.590713 0.504202 0.526881 0.422535 0.638600 0.558804 0.546089 0.469990 0.484527 0.508250 0.431655 0.442986 0.468750 0.400876 0.691625 0.898876 0.944444 0.950337 0.696056 0.968679 0.430070 0.430255 0.700398 0.969111 0.438109 0.564574 0.341382 0.431617 0.659107 0.748191 0.810874 0.489667 0.557517 0.821668 0.336304 0.471060 0.696604 0.611171

46570.849 20794.879 51466.357 48721.345 48168.107 55368.280 50542.381 58013.901 36753.815 73263.092 31428.079 46177.050 41568.360 70564.535 26494.329 47130.924 39170.983 46180.921 43984.424 40379.920 66455.454 63138.479 54735.917 52095.784 21722.770 1044.647 7036.960 2555.386 37525.924 5885.892 55330.218 47981.501 34917.447 2535.975 47064.608 39721.729 74880.126 55215.351 23340.574 15941.555 14467.776 49716.329 35764.433 13748.133 80597.484 43494.439 22670.817 43391.920

394.000 357.792 694.365 363.018 343.420 628.442 355.232 340.601 366.805 323.557 364.713 360.055 363.932 332.209 367.212 784.287 383.540 384.245 348.436 359.867 334.991 342.492 350.198 406.478 301.095 51.759 234.487 91.212 815.604 133.709 511.682 326.383 328.913 79.249 320.146 374.169 420.156 586.723 235.930 397.942 328.112 671.135 405.953 326.714 398.488 417.637 353.867 541.952

0.701812 0.744078 0.605531 0.646147 0.640037 0.650124 0.663332 0.661681 0.786725 0.637101 0.610872 0.601215 0.576488 0.636065 0.672944 0.684979 0.658651 0.708101 0.672602 0.673205 0.639660 0.705445 0.712026 0.631624 0.629930 0.635071 0.686808 0.701401 0.662132 0.632353 0.632074 0.717777 0.644447 0.644955 0.673360 0.674943 0.669469 0.659802 0.661932 0.708101 0.689010 0.635137 0.667107

0.592112 0.377003 0.508336 0.587635 0.700671 0.630134 0.508741 0.551307 0.421159 0.692423 0.657533 0.695151 0.679934 0.714948 0.460751 0.560224 0.586957 0.387533 0.426453 0.390035 0.633060 0.355591 0.357108 0.573437 0.665394 0.534225 0.441137 0.416541 0.408185 0.705882 0.490067 0.369886 0.635294 0.620690 0.419835 0.393773 0.602342 0.613009 0.599667 0.380590 0.385524 0.649819 0.594845

43972.543 102371.564 37192.612 35464.040 21435.403 25999.588 69870.295 35010.130 88865.367 21552.599 233.729 18782.785 36551.790 20123.021 47000.950 36024.663 30326.768 68202.455 51191.823 57653.653 25588.096 73098.549 75299.385 30637.597 21991.355 34688.941 52076.301 58041.261 53948.481 20645.509 38751.797 73006.638 25179.008 26474.388 52640.791 57281.543 30060.962 27719.267 29222.719 69744.745 63177.116 22814.938 30487.312

593.262 527.064 442.085 384.918 382.093 370.734 384.262 266.439 591.765 364.618 4.489 300.520 2028.852 358.699 391.068 366.925 360.347 374.019 393.209 405.469 364.867 380.246 368.645 309.577 406.570 350.514 388.015 366.818 297.311 381.688 290.461 375.782 359.033 377.504 404.338 402.852 348.856 321.681 339.129 382.477 404.422 325.324 353.804

a calcular el calor de vaporización en la columna Treal. Masa kgmol 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

∆Hv kJ 6259277.830 3582984.800 3799483.423 4796025.011 3464654.255 4844158.401 596219.117 3604165.434 1967078.126

∆Hv kcal 1495341.473 855975.069 907696.590 1145770.375 827705.902 1157269.442 142436.747 861035.122 469934.964

∆Hv BTU 5933894.736 3396726.463 3601970.594 4546707.838 3284547.229 4592339.055 565225.187 3416806.041 1864821.287

100.000 100.000

5223030.982 426286.384

1247782.102 101839.817

4951516.277 404126.259

7.996 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 51.807 100.000 100.000 100.000 100.000 100.000 100.000

247860.682 6251186.704 3077629.461 4453709.123 479678.716 2714838.150 359593.368 3437146.244 1740903.184 6486332.367 3644469.604 3131239.682 9703868.809 2207820.629 2619269.457 3283289.258 2842974.697 4621005.880 6465514.669 6624895.839 4518759.414 1454390.719 3773421.538 7236552.359 4750088.042 1836221.372 2754920.297 2649567.479

59213.917 1493408.503 735245.678 1063991.110 114595.245 648574.834 85906.856 821134.238 415901.771 1549584.803 870663.788 748053.160 2318254.258 527448.348 625743.473 784377.804 679186.655 1103958.305 1544611.454 1582687.616 1079531.624 347453.943 901470.405 1728812.359 1134796.033 438673.286 658150.459 632981.671

234975.860 5926224.220 2917641.580 4222186.943 454743.036 2573709.659 340900.221 3258469.197 1650403.852 6149146.042 3455015.033 2968464.921 9199421.661 2093049.001 2483109.021 3112610.332 2695185.139 4380786.924 6129410.534 6280506.412 4283855.651 1378785.487 3577263.514 6860366.503 4503158.862 1740767.007 2611708.171 2511832.027

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

4699053.173 456495.732 4277596.715 3555349.179 2388340.817 3171871.084 2720745.731 2372808.193 2690671.211 4220405.896 4074785.494 3644556.892 847289.713 6430294.492 2464269.818 7383698.777 6714227.446 2050821.302 5164025.243 78699.983 1556662.612 2681757.526 1758625.835 1387826.931 4718731.091 4811853.068 4746398.898 1896155.851 4801936.732 2003937.095 3373705.760 2476942.052 4484772.845 4630066.914 3984063.644 3442924.809 3545883.474 386774.311 3797549.360 2967210.393 1863504.856 2835350.102 2791778.262 3558266.812 1915209.570 2367397.376 3529726.183 3160341.827

1122603.803 109056.830 1021917.855 849372.919 570574.621 757760.002 649986.155 566863.877 642801.352 1008254.969 973466.254 870684.642 202417.512 1536197.354 588714.059 1763965.638 1604028.937 489941.209 1233685.630 18801.426 371886.698 640671.873 420135.712 331551.854 1127304.858 1149551.698 1133914.697 452991.633 1147182.685 478740.572 805978.306 591741.456 1071412.233 1106122.986 951792.805 822514.737 847111.562 92400.383 907234.542 708866.563 445191.310 677365.139 666955.827 850069.941 457543.566 565571.233 843251.585 755005.662

4454776.996 432765.200 4055229.584 3370527.456 2264185.004 3006984.134 2579310.140 2249459.830 2550799.018 4001011.780 3862961.327 3455097.784 803244.097 6096021.247 2336166.902 6999863.642 6365194.194 1944211.147 4895577.899 74608.833 1475740.865 2542348.702 1667205.206 1315681.960 4473431.974 4561713.087 4499661.495 1797585.844 4552312.243 1899764.174 3198326.611 2348180.382 4251635.844 4389376.927 3776955.574 3263947.368 3361553.817 366668.186 3600137.072 2812962.551 1766632.182 2687956.902 2646650.106 3373293.418 1815649.072 2244330.291 3346236.449 2996054.216

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

4657084.931 2079487.943 5146635.661 4872134.531 4816810.682 5536828.012 5054238.116 5801390.077 3675381.458 7326309.180 3142807.851 4617704.977 4156836.010 7056453.467 2649432.895 4713092.379 3917098.330 4618092.116 4398442.386 4037991.993 6645545.392 6313847.876 5473591.703 5209578.409 2172277.016 104464.704 703696.006 255538.565 3752592.420 588589.162 5533021.829 4798150.146 3491744.685 253597.507 4706460.822 3972172.937 7488012.629 5521535.147 2334057.375 1594155.481 1446777.597 4971632.939 3576443.315 1374813.289 8059748.357 4349443.884 2267081.708 4339192.020

1112577.590 496789.670 1229531.259 1163952.940 1150736.072 1322748.212 1207457.486 1385952.089 878048.630 1750255.263 750816.796 1103169.719 993068.123 1685786.733 632949.519 1125957.769 935794.791 1103262.207 1050787.886 964676.287 1587620.794 1508378.258 1307641.058 1244568.282 518956.979 24956.618 168112.976 61048.163 896494.329 140613.951 1321838.915 1146278.070 834177.805 60584.444 1124373.490 948952.115 1788886.217 1319094.747 557606.307 380843.744 345635.168 1187723.109 854412.308 328442.895 1925473.882 1039082.144 541605.820 1036632.973

4414990.437 1971387.577 4879092.299 4618860.871 4566412.984 5249000.841 4791497.960 5499809.879 3484319.962 6945457.394 2979431.729 4377657.615 3940746.519 6689629.894 2511704.439 4468086.387 3713471.393 4378024.629 4169793.199 3828080.504 6300082.516 5985628.006 5189051.817 4938763.023 2059353.092 99034.197 667114.984 242254.616 3557517.179 557991.869 5245392.520 4548722.499 3310229.386 240414.462 4461799.565 3765682.995 7098754.829 5234502.963 2212723.440 1511284.700 1371568.127 4713186.941 3390525.031 1303344.821 7640769.375 4123341.841 2149229.444 4113622.911

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

4397254.342 10237156.366 3719261.153 3546403.954 2143540.278 2599958.840 6987029.507 3501013.023 8886536.710 2155259.879 23372.935 1878278.477 3655178.978 2012302.072 4700094.996 3602466.279 3032676.833 6820245.523 5119182.256 5765365.262 2558809.559 7309854.923 7529938.472 3063759.681 2199135.525 3468894.063 5207630.076 5804126.055 5394848.075 2064550.851 3875179.683 7300663.755 2517900.821 2647438.844 5264079.112 5728154.302 3006096.213 2771926.675 2922271.894 6974474.537 6317711.559 2281493.792 3048731.207

1050504.062 2445656.656 888531.489 847235.905 512091.772 621130.167 1669201.349 836392.011 2122993.620 514891.585 5583.794 448720.728 873222.258 480738.965 1122852.695 860629.194 724506.495 1629356.655 1222972.641 1377345.761 611299.604 1746324.341 1798902.301 731932.188 525373.477 828718.792 1244102.825 1386605.714 1288829.205 493221.198 925780.426 1744128.571 601526.506 632473.140 1257588.500 1368456.063 718156.385 662213.283 698130.755 1666201.967 1509301.292 545048.867 728341.885

4168666.914 9704986.730 3525918.609 3362047.241 2032110.208 2464802.249 6623814.877 3319015.917 8424577.857 2043220.576 22157.913 1780637.810 3465167.690 1907694.306 4455764.661 3415195.214 2875025.775 6465701.014 4853066.035 5465657.782 2425792.078 6929858.497 7138501.194 2904492.808 2084815.384 3288566.634 4936915.973 5502403.629 5114401.608 1957226.977 3673731.850 6921145.123 2387009.945 2509814.047 4990430.555 5430381.201 2849826.926 2627830.486 2770360.141 6611912.567 5989290.839 2162892.329 2890245.576

Num. 1 2 3 4 5 6 7 8 9 1000

Compuesto ACENAPHTHYLENE ACETALDEHYDE ACETIC ACID ACETONE ACETONITRILE ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA VACÏO Total =

Colocar en la columna Num el número de iden

Colocar la te

Cálculo del calor latente de evaporación Peso

Tb

λb

0.20000 0.10000 0.10000 0.10000 0.10000 0.10000 0.10000 0.10000 0.10000 0.00000

molecular 152.18000 78.10800 92.13400 106.16000 41.05200 78.50000 26.03600 53.06000 17.03200 0.00100

K 543.161 353.261 383.786 411.511 354.761 324.081 188.401 350.461 239.731

KJ/Kgmol 48485.800 30763.400 33460.600 35928.900 31510.700 46227.900 16419.100 32630.100 23351.000

1.00000

79.644

yi

n la columna Num el número de identificación de cada uno de los compuestos de la mezcla, así como la frac

Colocar la temperatura a la que se desea el valor del calor latente de vaporización e

or latente de evaporación de una mezcla Tc

Pc

Treal

K 796.917 461.161 594.761 509.461 547.861 507.921 308.341 519.161 405.661 1.000E+100

Kpa 3220.950 5552.630 5785.680 4782.560 4833.220 5741.600 6138.290 3536.250 11402.140 0.000 Treal

K 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000 300.000

Tr1 K 0.681578 0.766025 0.645278 0.807738 0.647538 0.638054 0.611015 0.675053 0.590964 0.000000 λreal de la mezcla =

uestos de la mezcla, así como la fracción molar de dicho componente en la mezcla, en la columna y i.

or del calor latente de vaporización en la celda Trea,l de color café.

λreal

Tr2 K 0.376451 0.650532 0.504404 0.588858 0.547584 0.590643 0.972949 0.577855 0.739534 0.000000 de la mezcla =

la mezcla, en la columna y i.

λreal

λreal

Masa

kJ/kgmol 62592.778 35829.848 37994.834 47960.250 34646.543 48441.584 5962.191 36041.654 19670.781 0.000

kJ/kg 411.308 458.722 412.387 451.773 843.967 617.090 228.998 679.262 1154.931 0.000

kgmol 200.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 0.000

39173.324 491.854 Masa total en kgmol =

1000.000 1000.000

∆Hv

∆Hv

∆Hv

kJ 12518555.659 3582984.800 3799483.423 4796025.011 3464654.255 4844158.401 596219.117 3604165.434 1967078.126 0.000

kcal 2990682.947 855975.069 907696.590 1145770.375 827705.902 1157269.442 142436.747 861035.122 469934.964 0.000

BTU 11867789.472 3396726.463 3601970.594 4546707.838 3284547.229 4592339.055 565225.187 3416806.041 1864821.287 0.000

39173324.227

9358507.158

37136933.166

Capacidades caloríficas d

Num. 115 121 16 18 12 1000 1000 1000 1000 1000

Num. 12 139 1000 1000 1000 6 7 8 9 10

Nombre NITROGEN OXYGEN CARBÓN DIOXIDE CARBÓN MONOXIDE BENZENE VACÏO VACÏO VACÏO VACÏO VACÏO

Nombre BENZENE TOLUENE VACÏO VACÏO VACÏO ACETYL CHLORIDE ACETYLENE ACRYLONITRILE AMMONIA ANILINE

Fracción mol yi 0.63015 0.11909 0.12327 0.05032 0.07718 0.00000 0.00000 0.00000 0.00000 0.00000 1.00001

Fracción mol yi 0.10000 0.10000 0.00000 0.00000 0.00000 0.10000 0.15000 0.20000 0.25000 0.10000 1.00000

a 2.94119E+01 2.98832E+01 1.90223E+01 2.90063E+01 1.85868E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.73317E+01

a 1.85868E+01 3.18200E+01 0.00000E+00 0.00000E+00 0.00000E+00 2.64542E+01 2.18212E+01 1.07482E+01 2.75500E+01 -2.25594E+00 1.97708E+01

Calor latente de evaporación de una mezcla líquida Colocar en la columna Num el número de identificación del compuesto deseado, pero en la hoja de Propiedades generales hay que colocar el valor de la temperatura a la que se desea el calor latente de evaporación de la mezcla. Colocar en la celda gris la masa total de la mezcla que se va a evaporar.

Num. 12 139 123 1000

Nombre BENZENE TOLUENE P-XYLENE VACÏO

1000

Fracción mol yi

λreal

0.98570 0.01430 0.00000 0.00000

kJ/kgmol 30998.084 35464.040 39721.729 0.000

VACÏO

0.00000

0.000

1000 1000 1000 1000

VACÏO VACÏO VACÏO VACÏO

0.00000 0.00000 0.00000 0.00000

0.000 0.000 0.000 0.000

1000

VACÏO

0.00000 1.00000

0.000 31061.947

Temperatura de saturación de una mezcla líquida Colocar en la columna Num el número de identificación del compuesto deseado, pero en la hoja de Presión de vapor hay que colocar el valor de la presión a la que se desea la temperatura de saturación de la mezcla. Fracción mol Temperatura yi Nombre K

Num. 12 BENZENE

0.03123

348.606

139

TOLUENE

0.94110

378.382

123 1000 1000

P-XYLENE VACÏO VACÏO

0.02770 0.00000 0.00000

405.742 0.000 0.000

1000 1000 1000 1000 1000

VACÏO VACÏO VACÏO VACÏO VACÏO

0.00000 0.00000 0.00000 0.00000 0.00000 1.00003

0.000 0.000 0.000 0.000 0.000 378.221

pacidades caloríficas de las mezclas gaseosas y cálculo del calor perdido o g "Mass and energy balances " de R. V. Reklaitis Cp's en kJ/kgmol, T en K

GASES Tinicial b -3.00681E-03 -1.13842E-02 7.96291E-02 2.49235E-03 -1.17439E-02 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 5.78441E-03 Temp. Inicial, K

c 5.45064E-06 4.33779E-05 -7.37067E-05 -1.86440E-05 1.27514E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 9.69919E-05 342.499

d 5.13186E-09 -3.70082E-08 3.74572E-08 4.79892E-08 -2.07984E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.54663E-07 Temp. Final, K

e -4.25308E-12 1.01006E-11 -8.13304E-12 -2.87266E-11 1.05329E-09 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 7.73676E-11 303.150

K 342.499 342.499 342.499 342.499 342.499 342.499 342.499 342.499 342.499 342.499 342.499 342.499

Tinicial b -1.17439E-02 -1.61654E-02 0.00000E+00 0.00000E+00 0.00000E+00 1.83863E-01 9.20580E-02 2.20682E-01 2.56278E-02 3.07834E-01 1.10731E-01 Temp. Inicial, K

una mezcla líquida de identificación del piedades generales hay a la que se desea el de la mezcla. ezcla que se va a evaporar.

c 1.27514E-03 1.44465E-03 0.00000E+00 0.00000E+00 0.00000E+00 -1.13740E-04 -6.52231E-05 -1.57773E-04 9.90042E-06 2.41742E-04 2.45916E-04 273.150

d -2.07984E-06 -2.28948E-06 0.00000E+00 0.00000E+00 0.00000E+00 1.92063E-08 1.81959E-08 4.84219E-08 -6.68639E-09 -5.37543E-07 -4.78024E-07 Temp. Final, K

e 1.05329E-09 1.13573E-09 0.00000E+00 0.00000E+00 0.00000E+00 6.51935E-12 0.00000E+00 -1.22867E-12 0.00000E+00 2.35694E-10 2.42878E-10 323.150

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

Capacidad caloríica de ace Escribir los valores de los °API y de Definir las temperaturas inic Colocar la cantidad de calor a interca Se obtiene como resultado la mas

Masa kgmol 38140.565 553.323 0.000 0.000

∆Hv kJ 1182284459.27 19623054.51 0.00 0.00

0.000

0.00

Tinicial

=

50.00

0.000 0.000 0.000 0.000

0.00 0.00 0.00 0.00

Tfinal

=

110.00

Cp = a + bT a =

0.409630

0.000 38693.888

0.00 1201907513.78 1201907513.78

a líquida ificación del de vapor hay desea la la. Temperatura

Cp=[(0.355+0.128e-2*ºAPI)+(0.503+0.11 ºAPI = Tb = K =

45.00 180.00 11.656

b =

0.000552

Capacidad caloríica de ace Escribir los valores de los °API y de Definir las temperaturas inic Colocar la cantidad aceite a cale Se obtiene como resultado la cantidad d

Cp=[(0.355+0.128e-2*ºAPI)+(0.503+0.11 ºAPI

=

45.00

°C 75.456

Tb = K =

105.232

Tinicial

=

50.00

132.592 -273.150 -273.150

Tfinal

=

110.00

-273.150 -273.150 -273.150 -273.150 -273.150 105.063

180.00 11.656

Cp = a + bT a = b =

0.409630 0.000552

Cálculo de la presió la saturació SP =

0.90000

PT =

dato

PV =

dato

p =

Elegir la columna con las unidades de p

calor perdido o ganado

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 303.150 303.150 303.150 303.150 303.150 303.150 303.150 303.150 303.150 303.150 303.150 303.150

kJ/kgmol.K 29.137 29.595 38.213 29.172 89.142 0.000 0.000 0.000 0.000 0.000 34.943 34.943

kJ/kgmol -1146.487 -1164.525 -1503.644 -1147.862 -3507.587 0.000 0.000 0.000 0.000 0.000 -1374.972 -1374.972

kgmol 0.630 0.119 0.123 0.050 0.077 0.000 0.000 0.000 0.000 0.000 1.000 1.000

kJoules -722.459 -138.683 -185.354 -57.760 -270.716 0.000 0.000 0.000 0.000 0.000 -1374.972 -1374.972

Tfinal

Cpmedia

Cp.∆T

Moles

Q

K 323.150 323.150 323.150 323.150 323.150 323.150 323.150 323.150 323.150 323.150 323.150 323.150

kJ/kgmol.K 81.632 103.716 0.000 0.000 0.000 71.703 43.942 63.769 35.895 98.606 63.885 63.885

kJ/kgmol 4081.604 5185.799 0.000 0.000 0.000 3585.169 2197.122 3188.461 1794.731 4930.305 3194.231 3194.231

kgmol 100.000 100.000 0.000 0.000 0.000 100.000 150.000 200.000 250.000 100.000 1000.000 1000.000

kJoules 408160.358 518579.884 0.000 0.000 0.000 358516.877 329568.353 637692.179 448682.677 493030.484 3194230.812 3194230.812

Diferencia =

3192855.840

cidad caloríica de aceites minerales alores de los °API y de la Tb del aceite, en °C. ir las temperaturas inicial y final en °C idad de calor a intercambiar con el aceite, en kJ. como resultado la masa de aceite necesario.

*ºAPI)+(0.503+0.117e-2*ºAPI)e-3*t]*(0.05*K+0.41) G = ºC = ºC

=

ºC

= Cp = Cp = Q = Maceite =

0.801700 816.00

ºR

122.00

ºF

230.00 ºF 0.50672 kcal/kg.ºC 2.12106 kJ/kg.ºC 486905.76 kJ 3825.964

kg

cidad caloríica de aceites minerales alores de los °API y de la Tb del aceite, en °C. ir las temperaturas inicial y final en °C cantidad aceite a calentar o enfriar, en kg. resultado la cantidad de calor a intercambiar, en kj.

*ºAPI)+(0.503+0.117e-2*ºAPI)e-3*t]*(0.05*K+0.41) G =

0.801700

°C

=

816.00

°R

°C

=

122.00

°F

= Cp = Cp = Maceite =

230.00 0.50672 2.12106

°C

Q

=

°F kcal/kg.°C kJ/kg.°C

3825.964 kg 486905.760 kJ

Cálculo de la presión parcial, conociendo la saturación porcentual: kPa

atm

mmHg

psía

557.150

14.47370

11000.00000

212.76310

30.34300 27.45824

0.74304 0.67219

564.71076 510.86232

10.92270 9.88116

on las unidades de presión que se desean y trabajar con ella.

Capacidades caloríficas de las mezclas l

Num. 12 139 1000 1000 1000 1000 1000 1000 1000 1000

Num. 12 139 1000 1000 1000 1000 1000 1000 1000 1000

Nombre BENZENE TOLUENE VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

Nombre BENZENE TOLUENE VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO VACÍO

Fracción mol yi 0.01500 0.98500 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

Fracción mol yi 0.01500 0.98500 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

a -7.27329E+00 1.80826E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.67204E+00 Temp. Inicial, K

a -7.27329E+00 1.80826E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.67204E+00 Temp. Inicial, K

aloríficas de las mezclas líquidas y cálculo del calor perdido o ganado "Mass and energy balances" de R. V. Reklaitis Cp's en kJ/kgmol, T en K

LÍQUIDOS b 7.70541E-01 8.12223E-01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 8.11598E-01 273.150

b 7.70541E-01 8.12223E-01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 8.11598E-01 273.150

c -1.64818E-03 -1.51267E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.51470E-03 Temp. Final, K

c -1.64818E-03 -1.51267E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.51470E-03 Temp. Final, K

d 1.89794E-06 1.63001E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.63403E-06 325.150

d 1.89794E-06 1.63001E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 1.63403E-06 325.150

Tinicial

Tfinal

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

K 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150

Tinicial

Tfinal

K 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150 273.150

K 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150 325.150

do o ganado

Cpmedia

Cp.∆T

Moles

Q

kJ/kgmol.K 126.560 153.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 152.644 152.644

kJ/kgmol 6581.104 7958.124 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7937.469 7937.469

kgmol 37.500 2462.500 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2500.000 2500.000

kJoules 246791.393 19596881.523 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 19843672.916 19843672.916

Cpmedia

Cp.∆T

Moles

Q

kJ/kgmol.K 126.560 153.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 152.644 152.644

kJ/kgmol 6581.104 7958.124 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7937.469 7937.469

kgmol 37.500 2462.500 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2500.000 2500.000

kJoules 246791.393 19596881.523 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 19843672.916 19843672.916

Diferencia =

39687345.832

Co Conversión de temperaturas Temp. °C °F K °R

°C °F K 80.000 176.000 353.150 78.889 174.000 352.039 100.000 212.000 373.150 100.000 212.000 373.150 Se llenan las celdas blancas y se lee en línea horizontal

Conversión de superficies Área

cm

m2

pulg2

cm2

10000.000

1.000

1550.003

m2

10000.000

1.000

1550.003

pulg2

10000.000

1.000

1550.003

pie

10000.000

1.000

1550.003

2

2

Se llenan las celdas blancas y se lee en línea horizontal

Cambio de fracción peso a mol y de fracción mol a peso. Llenar las columnas de color amarillo o café, según los datos que se tenga porcentaje peso o porcentaje molar. Componente Peso molecular de % Peso a % Molar Nitrógeno 28.00 0.76699 0.79000 Oxígeno 32.00 0.23301 0.21000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 vacío 1.00 0.00000 0.00000 Total = 1.00000 1.00000 Extra 1 = 0.03467 Extra 2 =

1

Pulgadas 1/64

Pulgadas 0.015625

cm. 0.039688

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43

1/32 3/64 1/16 5/64 3/32 7/64 1/8 9/64 5/32 11/64 3/16 13/64 7/32 15/64 1/4 17/64 9/32 19/64 5/16 21/64 11/32 23/64 3/8 25/64 13/32 27/64 7/16 29/64 15/32 31/64 1/2 33/64 17/32 35/64 9/16 37/64 19/32 39/64 5/8 41/64 21/32 43/64

0.031250 0.046875 0.062500 0.078125 0.093750 0.109375 0.125000 0.140625 0.156250 0.171875 0.187500 0.203125 0.218750 0.234375 0.250000 0.265625 0.281250 0.296875 0.312500 0.328125 0.343750 0.359375 0.375000 0.390625 0.406250 0.421875 0.437500 0.453125 0.468750 0.484375 0.500000 0.515625 0.531250 0.546875 0.562500 0.578125 0.593750 0.609375 0.625000 0.640625 0.656250 0.671875

0.079375 0.119063 0.158750 0.198438 0.238125 0.277813 0.317500 0.357188 0.396875 0.436563 0.476250 0.515938 0.555625 0.595313 0.635000 0.674688 0.714375 0.754063 0.793750 0.833438 0.873125 0.912813 0.952500 0.992188 1.031875 1.071563 1.111250 1.150938 1.190625 1.230313 1.270000 1.309688 1.349375 1.389063 1.428750 1.468438 1.508125 1.547813 1.587500 1.627188 1.666875 1.706563

44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64

11/16 45/64 23/32 47/64 3/4 49/64 25/32 51/64 13/16 53/64 27/32 55/64 7/8 57/64 29/32 59/64 15/16 61/64 31/32 63/64 1

0.687500 0.703125 0.718750 0.734375 0.750000 0.765625 0.781250 0.796875 0.812500 0.828125 0.843750 0.859375 0.875000 0.890625 0.906250 0.921875 0.937500 0.953125 0.968750 0.984375 1.000000

1.746250 1.785938 1.825625 1.865313 1.905000 1.944688 1.984375 2.024063 2.063750 2.103438 2.143125 2.182813 2.222500 2.262188 2.301875 2.341563 2.381250 2.420938 2.460625 2.500313 2.540000

Conversión de unidades

Convers °R 636.000 634.000 672.000 672.000

ea horizontal

Presión atm kPa mmHg psía bar kgf /cm2

atm 1.0000 3.9487 1.0000 1.0000 1.0000 1.0000

Se llenan las celdas bla

pie2 10.764

C

10.764

Volumen

cm3

10.764

cm3

1000000.0000

10.764

m

1000000.0000

ea horizontal

acción mol a peso. os datos que se tengan, ya sea molar. de % Molar a % Peso 0.79000 0.76699 0.21000 0.23301 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000 1.00000 28.84000

3

pulg3

1000000.0001

pie litros galones barriles

499990.5603 500000.0000 1000000.0280 1000001.8800

3

Se llenan las ce

Conversión de e Energía kJ kcal BTU J cal

kJ 418.5852 418.5852 418.5852 418.5852 418.5852

Se llenan las ce

Dimensiones de un círculo o de una esfera Diámetro Perímetro Área Área sup. Volumen cm 0.250 0.500 0.750 1.000 1.250 1.500 1.750 2.000 2.250 2.500 2.750 3.000 3.250 3.500 3.750 4.000 4.250 4.500 4.750 5.000 5.250 5.500 5.750 6.000 6.250 6.500 6.750 7.000 7.250 7.500 7.750 8.000 8.250 8.500 8.750 9.000 9.250 9.500 9.750 10.000

cm 0.785 1.571 2.356 3.142 3.927 4.712 5.498 6.283 7.068 7.854 8.639 9.425 10.210 10.995 11.781 12.566 13.351 14.137 14.922 15.708 16.493 17.278 18.064 18.849 19.634 20.420 21.205 21.991 22.776 23.561 24.347 25.132 25.918 26.703 27.488 28.274 29.059 29.844 30.630 31.415

cm2 0.0491 0.1963 0.4418 0.7854 1.2272 1.7671 2.4052 3.1415 3.9760 4.9086 5.9394 7.0684 8.2956 9.6209 11.0444 12.5661 14.1859 15.9039 17.7201 19.6345 21.6470 23.7577 25.9666 28.2736 30.6789 33.1823 35.7838 38.4836 41.2815 44.1776 47.1718 50.2643 53.4549 56.7436 60.1306 63.6157 67.1990 70.8805 74.6601 78.5379

cm2 0.1964 0.7854 1.7672 3.1416 4.9088 7.0686 9.6212 12.5664 15.9044 19.6350 23.7584 28.2744 33.1832 38.4846 44.1788 50.2656 56.7452 63.6174 70.8824 78.5400 86.5904 95.0334 103.8692 113.0976 122.7188 132.7326 143.1392 153.9384 165.1304 176.7150 188.6924 201.0624 213.8252 226.9806 240.5288 254.4696 268.8032 283.5294 298.6484 314.1600

cm3 0.0082 0.0655 0.2209 0.5236 1.0227 1.7672 2.8062 4.1888 5.9641 8.1813 10.8892 14.1372 17.9742 22.4494 27.6117 33.5104 40.1945 47.7131 56.1152 65.4500 75.7666 87.1140 99.5413 113.0976 127.8320 143.7937 161.0315 179.5948 199.5325 220.8938 243.7276 268.0832 294.0096 321.5559 350.7711 381.7044 414.4049 448.9216 485.3036 523.6000

Conversión de presiones kPa mmHg psía bar 101.3000 760.0000 14.7000 1.0130 400.0000 3000.9872 58.0454 4.0000 101.3000 760.0000 14.7000 1.0130 101.3000 760.0000 14.7000 1.0130 101.3000 760.0000 14.7000 1.0130 101.3000 760.0000 14.7000 1.0130 Se llenan las celdas blancas y se lee en línea horizontal

kgf /cm2 1.0330 4.0790 1.0330 1.0330 1.0330 1.0330

Conversión de volúmenes m3

pulg3

pie3

litros

galones

1.0000

61023.7441

35.3147

1000.0000

264.2008

1.0000

61023.7441

35.3147

1000.0000

264.2008

1.0000

61023.7441

35.3147

1000.0000

264.2008

0.5000 30511.2960 17.6570 499.9906 0.5000 30511.8720 17.6573 500.0000 1.0000 61023.7458 35.3147 1000.0000 1.0000 61023.8588 35.3147 1000.0019 Se llenan las celdas blancas y se lee en línea horizontal

Conversión de energía kcal BTU J cal 100.0000 396.8254 418585.2000 100000.0043 100.0000 396.8254 418585.1821 100000.0000 100.0000 396.8254 418585.1854 100000.0008 100.0000 396.8254 418585.1854 100000.0008 100.0000 396.8254 418585.1821 100000.0000 Se llenan las celdas blancas y se lee en línea horizontal

132.0979 132.1004 264.2008 264.2013

barriles 6.2893 6.2893 6.2893 3.1446 3.1447 6.2893 6.2893

Combustión de 4 hidrocarburos, con una conversió y una selectividad. Balance de materia.

Se llenan las celdas amarillas con los datos solicitados. Se obtienen los resu

M1 (kgmol) Y CH4 Y C 2H 6 Y C 3H 8 Y C4H10

1000.00 0.100 0.300 0.400 0.200 1.000

QUEMADOR

n= S=

M1

95.00 90.00

% %

M3

M2 Presion (Kpa)

709.100 EXCESO

Reacciones posibles:

AIRE SECO 85.00 %

CH4 + 2O2 CH4 + 2O2

CO2 + 2H2O CO + 2H2O

C2H6 + 3.5O2 C2H6 + 2.5O2

2CO2 + 3H2O 2CO + 3H2O

C3H6 + 5O2 C3H6 + 3.5O2

3CO2 + 4H2O 3CO + 4H2O

C4H10 + 6.5O2 C4H10 + 4.5O2

4CO2 + 5H2O 4CO + 5H 2O

Balance de materia

CH4 C 2H 6 C 3H 8 C4H10 TOTAL

M1 100.00 300.00 400.00 200.00 1000.00

kgmol kgmol kgmol kgmol kgmol

Y 0.10000 0.30000 0.40000 0.20000 1.00000

MASA 1600.00 9000.00 17600.00 11600.00 39800.00

kg kg kg kg kg

O2 ESTQ O2 ALIM N2

M2 4550.00 8417.50 31665.83

kgmol kgmol kgmol

Y 0.21000 0.79000

MASA 145600.00 269360.00 886643.33

kg kg kg

AIRE

40083.33

kgmol

1

1156003.33

kg

M3, Base húmeda

Y

MASA

CH4

5.00

kgmol

0.00012

80.00

kg

C 2 H6

15.00

kgmol

0.00036

450.00

kg

C 3 H8

20.00

kgmol

0.00048

880.00

kg

C4H10 O2 N2

10.00 4223.25 31665.83

kgmol kgmol kgmol

0.00024 0.10051 0.75361

580.00 135144.00 886643.33

kg kg kg

CO2

2308.50

kgmol

0.05494

101574.00

kg

CO

256.50

kgmol

0.00610

7182.00

kg

H2 O

3515.00

kgmol

0.08365

63270.00

kg

42019.08

kgmol

1.00000 1195803.33

kg

seca kgmol kgmol kgmol kgmol kgmol kgmol kgmol kgmol kgmol

Y MASA 0.00013 80.00 0.00039 450.00 0.00052 880.00 0.00026 580.00 0.10968 135144.00 0.82240 886643.33 0.05995 101574.00 0.00666 7182.00 1.00000 1132533.33

kg kg kg kg kg kg kg kg kg

TOTAL

CH4 C 2 H6 C 3 H8 C4H10 O2 N2 CO2 CO TOTAL

M3, Base 5.00 15.00 20.00 10.00 4223.25 31665.83 2308.50 256.50 38504.08

conversión eria.

ienen los resultados en forma inmediata. GASES DE CHIMENEA 42019.083333 kgmol Yi CH4 C 2H 6 C 3H 8 C4H10 O2 N2 CO2

0.000119 0.000357 0.000476 0.000238 0.1005079 0.753606 0.0549393

CO H 2O

0.0061044 0.0836525

A la Trocio se tiene que la Pparcial = Pv = Trocio =

59.3180 438.6523

K

BALANCE DE MASA M1+M2=M3 M1+M2 = 1195803.33 kg M3 = 1195803.33 kg DATOS A

ANTOINE B

H2 O C

16.5362

3985.44

-38.9974

O2 necesario =

4550.00

kgmol

O2 en exceso =

3867.50

kgmol

O2 alimentado =

8417.50

kgmol

N2 alimentado =

31665.83 40083.33

kgmol kgmol

Aire alimentado = O2 necesario =

145600.00

kg

O2 en exceso =

123760.00

kg

O2 alimentado = N2 alimentado = Aire alimentado =

X 0.04020 0.22613 0.44221 0.29146 1.00000

Pparcial = Pv kPa

269360.00 kg 886643.33 kg 1156003.33 kg

X 0.23301 0.76699

1.00000 X 0.00007 0.00038 0.00074 0.00049 0.11302 0.74146 0.08494 0.00601 0.05291 1.00000

X 0.00007 0.00040 0.00078 0.00051 0.11933 0.78288 0.08969 0.00634 1.00000

Combustión de 4 hidrocarburos, con una conve y una selectividad

Se llenan las celdas amarillas con los datos solicitados. Se obtienen lo

Base de cálculo: M1 (kgmol) Y CH4 Y C2H6 Y C3H8 Y C4H10

1000.00 0.100 0.300 0.400 0.200 1.000

QUEMADOR

n= S=

M1

95.00 90.00

% %

M3

M2 Presion (Kpa)

709.100 EXCESO

Reacciones posibles:

AIRE SECO 85.00 %

CH4 + 2O2 CH4 + 2O2

CO2 + 2H2O CO + 2H 2O

C2H6 + 3.5O2 C2H6 + 2.5O2

2CO2 + 3H2O 2CO + 3H2O

C3H6 + 5O2 C3H6 + 3.5O2

3CO2 + 4H2O 3CO + 4H2O

C4H10 + 6.5O2 C4H10 + 4.5O2

4CO2 + 5H2O 4CO + 5H2O

Balance de materia

CH4 C 2H 6 C 3H 8 C4H10 TOTAL

M1 100.00 300.00 400.00 200.00 1000.00

kgmol kgmol kgmol kgmol kgmol

Y 0.10000 0.30000 0.40000 0.20000 1.00000

MASA 1600.00 9000.00 17600.00 11600.00 39800.00

kg kg kg kg kg

ESTQ. O2 ESTQ N2 ESTQ AIRE

M2 4550.00 17116.67 21666.67

M2 = M2

ESTQ

kgmol kgmol kgmol

Y 0.210 0.790 1.000

MASA 145600.00 479266.67 624866.67

kg kg kg

MASA 269360.00 886643.33

kg kg kg

*(1 + % de Exceso/100)

O2 ALIM N2 ALIM

M2 8417.50 31665.83

kgmol kgmol

Y 0.210 1.462

AIRE

40083.33

kgmol

1.672

1156003.33

Y

MASA

M3, Base húmeda CH4 C 2 H6 C 3 H8

5.00 15.00 20.00

kgmol kgmol kgmol

0.00012 0.00036 0.00048

80.00 450.00 880.00

kg kg kg

C4H10

10.00

kgmol

0.00024

580.00

kg

O2

4223.25

kgmol

0.10051

135144.00

kg

N2

31665.83

kgmol

0.75361

886643.33

kg

CO2 CO H2 O TOTAL

2308.50 256.50 3515.00 42019.08

kgmol kgmol kgmol kgmol

0.05494 101574.00 0.00610 7182.00 0.08365 63270.00 1.00000 1195803.33

kg kg kg kg

CH4 C 2 H6 C 3 H8 C4H10 O2 N2 CO2 CO TOTAL

M3, Base 5.00 15.00 20.00 10.00 4223.25 31665.83 2308.50 256.50 38504.08

seca kgmol kgmol kgmol kgmol kgmol kgmol kgmol kgmol kgmol

Y MASA 0.00013 80.00 0.00039 450.00 0.00052 880.00 0.00026 580.00 0.10968 135144.00 0.82240 886643.33 0.05995 101574.00 0.00666 7182.00 1.00000 1132533.33

kg kg kg kg kg kg kg kg kg

conversión

ienen los resultados en forma inmediata. GASES DE CHIMENEA kgmol Yi Compuesto CH4 C 2H 6 C 3H 8 C4H10 O2 N2 CO2

0.000119 0.000357 0.000476 0.000238 0.1005079 0.753606 0.0549393

CO H 2O

0.0061044 0.0836525

Relación Ci/C4

Yi

0.50000 1.50000 2.00000 1.00000 5.00000

= = = = = Total =

A la Trocio se tiene que la Pparcial = Pv = Trocio =

59.3180

0.100000 0.300000 0.400000 0.200000 1.000000

Pparcial = Pv kPa

438.6523

K

Balance de N2 = ( 17116.667 )*(1 + % exceso) = ( Balance de H2O = ( 100.000 ) *η* ( 2 ( ( ( Balance de C3H8

300.000 400.000 200.000

) ) )

*η* *η* *η*

( ( (

( 3700.0000 ) * η kgmol = ( 400.0000 ) * ( 1 - η )

Dividiendo la Ec. (2) entre la Ec. (3) se tiene que: ( 9.250000 )*(η/( 1 - η ))

3 4 5 =

(

=

(

= ( η =

Sustituyendo el valor de η en la Ec. (2) se tiene que:

X 0.04020 0.22613 0.44221 0.29146 1.00000

Sustituyendo el valor de M3 en la EC. (1) se tiene que: Balance de CO2 = ( *S* ( 95.0000 ) 1 *S* ( ( 285.0000 ) 2 *S* ( ( 380.0000 ) 3 *S* ( ( 190.0000 ) 4 ( 2565.0000 ) * η kgmol = Sustituyendo el valor de M3 en la EC. (4) se tiene que:

(

X 0.23301 0.76699 1.00000

X 0.23301 1.41893

BALANCE DE MASA M1+M2=M3 M1+M2 = 664666.67 kg M3 = 1195803.33 kg DATOS A 16.5362

ANTOINE B 3985.44

H2 O C -38.9974

O2 necesario =

4550.00

kgmol

O2 en exceso =

3867.50

kgmol

X

O2 alimentado =

8417.50

kgmol

0.00007 0.00038 0.00074

N2 alimentado =

31665.83 40083.33

kgmol kgmol

0.00049

O2 necesario =

145600.00

kg

0.11302

O2 en exceso =

123760.00

kg

0.74146

O2 alimentado =

269360.00

kg

0.08494 0.00601 0.05291 1.00000

N2 alimentado =

1.65194

X 0.00007 0.00040 0.00078 0.00051 0.11933 0.78288 0.08969 0.00634 1.00000

Aire alimentado =

Aire alimentado =

886643.33 kg 1156003.33 kg

0.753606

)*M3

Ec. (1)

0.083652

)*M3

Ec. 2

0.000476

)*M3

Ec. 3

) + ) + ) + ) =

175.750000 ) 95.0000 % M3 = 42019.083 kgmol % exceso = ) ) ) )

+ + + = 0.054939 S =

85.000

)*M3 90.000

Ec. 4 %

Combustión de 4 hidrocarburos, con una y una selectividad. Balances de materia

Se llenan las celdas amarillas con los datos solicitados. Los resultado

Una conversión y una selectividad

COMBUSTIÓN Aire seco

ε

=

T, °C

120.00

= 70.00

Combustible Flujo =

68.631

(kgmol)

V

CH4

=

0.000

% molar

C 2 H6

=

0.000

% molar

C 3 H8

=

35.000

% molar

C4H10 =

65.000

% molar

100.000

% molar

T, °C

=

>

QUEMADOR

η

=

no adiabático

S

=

70.00 T, °C

Gases de chimenea

=

1121.91

V

Para el caso de quemador adiabático: -0.12 Q =

Tmáxima 1121.90877

Flujo molar y másico CH4

=

0.00

kgmol

0.00

kg

C 2 H6

=

0.00

kgmol

0.00

kg

C 3 H8

=

0.72

kgmol

31.71

kg

C4H10 =

1.34

kgmol

77.62

kg

CO2

=

225.98

kgmol

9943.07

kg

CO H2 O

= =

17.01

kgmol

476.26

kg

309.56

kgmol

5572.08

kg

O2

=

512.89

kgmol

16412.51

kg

N2

=

3393.82 4461.32 4151.76

kgmol kgmol kgmol

95026.94 127540.19 121968.11

kg kg kg

Total = Total seco =

Gases de chimenea húmedos CH4

=

0.00000

% molar

0.00000

% peso

C 2 H6

=

0.00000

% molar

0.00000

% peso

C 3 H8

=

0.01615

0.02486

% peso

C4H10 =

0.03000

% molar

0.06086

% peso

CO2

=

CO H2 O

= =

5.06530 0.38126

% molar % molar

7.79603 0.37342

% peso % peso

6.93876

% molar

4.36888

% peso

O2

=

11.49640

% molar

12.86850

% peso

N2

=

76.07213 100.00000

% molar % molar

74.50745 100.00000

% peso % peso

Total =

-1195083

Gases de chimenea secos CH4

=

0.00000

% molar

0.00000

% peso

C 2 H6

=

0.00000

% molar

0.00000

% peso

C 3 H8

=

0.01736

% molar

0.02600

% peso

C4H10 =

0.03223

% molar

0.06364

% peso

CO2

=

CO O2

= =

5.44297 0.40969

% molar % molar

8.15219 0.39048

% peso % peso

12.35359

% molar

13.45640

% peso

N2

=

81.74417

% molar

77.91130

% peso

Total =

100.00000

% molar

100.00000

% peso

Calores de formación ΔHf,CH4

= -74851.760 kJ/kgmol

ΔHf,C2H6

= -84684.160 kJ/kgmol

ΔHf,C3H8

= -103846.880 kJ/kgmol

ΔHf,C4H10

= -126147.600 kJ/kgmol

ΔHf,CO2

= -393505.200 kJ/kgmol

ΔHf,CO

= -110541.280 kJ/kgmol

ΔHf,H2O

= -241826.414 kJ/kgmol

QR = QP =

-5942117.33

kJ

163727720.76

kJ

ΔHR° =

-157785603.56

kJ

carburos, con una conversión ances de materia y energía.

atos solicitados. Los resultados se obtienen de forma inmediata.

Reacciones: CH4 + 2 O2 CH4 + 1.5 O2

CO2

----->

+

CO

2 H2O

+

2 H2O

2 CO2

+

3 H2O

(3)

C2H6 + 2.5 O2

----->

2 CO

+

3 H2O

(4)

----->

3 CO2

+

4 H2O

----->

3 CO

C4H10 + 6.5 O2

----->

4 CO2

+

5 H2O

(7)

C4H10 + 4.5 O2

----->

4 CO

+

5 H2O

(8)

%

93.000

%

+

4 H2O

(5)

C3H8 + 3.5 O2

97.000

Alimentación:

(6)

Oxígeno necesario:

CH4

=

0.00

kgmol

0.00

kgmol

C2 H 6

=

0.00

kgmol

0.00

kgmol

C3 H 8

=

24.02

kgmol

120.10

kgmol

C4H10 =

44.61

kgmol

289.97

kgmol

68.63

Total

410.07

kgmol

410.07

kgmol

492.08 902.15 3393.82 4295.97

kgmol kgmol kgmol kgmol

Total

=

Oxígeno estequiométrico = 1121.90877

(2)

----->

C3 H 8 + 5 O 2

en °C =

(1)

C2H6 + 3.5 O2 %

1121.91

----->

Oxígeno en exceso = Oxígeno alimentado = Nitrógeno alimentado = Aire alimentado =

=

CH4

--->

CO2

0.00

kgmol

CH4

--->

CO

0.00

kgmol

C 2 H6

--->

CO2

0.00

kgmol

C 2 H6

--->

CO

0.00

kgmol

C 3 H8

--->

CO2

21.67

kgmol

C 3 H8

--->

CO

1.63

kgmol

C4H10

--->

CO2

40.24

kgmol

C4H10

--->

CO

3.03

kgmol

66.57

kgmol

Total que reaccionó = Masa total de entrada = Masa total de entrada = Diferencia =

s

127540.190 127540.190 0.000

Balance de energía ΔHR = QR

% peso

+

ΔHR°

+

QP

% peso % peso

Fracción mol yi Nombre

% peso

Num.

% peso % peso

77 41

METHANE ETHANE

0.00000 0.00000

3.83870E+01 -7.36639E-02 3.38339E+01 -1.55175E-02

% peso

128

PROPANE

0.35000

4.72659E+01 -1.31469E-01

% peso

89

N-BUTANE

0.65000

6.67088E+01 -1.85523E-01

1.00000

5.99038E+01 -1.66604E-01

% peso % peso

a

b

Temp. Inicial, K

Fracción mol yi Nombre

% peso

Num.

% peso

115

NITROGEN

0.79000

2.94119E+01 -3.00681E-03

% peso

121

OXYGEN

0.21000

2.98832E+01 -1.13842E-02

1.00000

2.95109E+01 -4.76606E-03

% peso

a

% peso % peso

b

Temp. Inicial, K

% peso % peso % peso

Num. 77 41 128

Fracción mol yi Nombre a b METHANE 0.00000 3.83870E+01 -7.36639E-02 ETHANE 0.00000 3.38339E+01 -1.55175E-02 PROPANE 0.00016 4.72659E+01 -1.31469E-01

89

N-BUTANE

0.00030

16

CARBÓN DIOX 0.05065

6.67088E+01 -1.85523E-01 1.90223E+01

7.96291E-02

18

CARBÓN MON 0.00381

2.90063E+01

2.49235E-03

148

WATER

0.06939

3.40471E+01 -9.65064E-03

121

OXYGEN

0.11496

2.98832E+01 -1.13842E-02

115

NITROGEN

0.76072

2.94119E+01 -3.00681E-03

1.00000

2.92740E+01 -2.99690E-04 Temp. Inicial, K

ΔHR

=

-0.12

kJ

0.00

kg

0.00

kg

1056.92

kg

2587.39

kg

3644.31

kg

13122.25

kg

15746.70 28868.94 95026.94 123895.88

kg kg kg kg ΔHR,1 =

-802306.27

kJ/kgmol

0.00

ΔHR,2 =

-519342.35

kJ/kgmol

0.00

ΔHR,3 =

-1427805.48

kJ/kgmol

0.00

ΔHR,4 =

-861877.64

kJ/kgmol

0.00

ΔHR,5 =

-2043974.37

kJ/kgmol

-44291307.47

ΔHR,6 =

-1195082.61

kJ/kgmol

-1949198.52

ΔHR,7 = ΔHR,8 =

-2657005.27

kJ/kgmol

-1525149.588 kJ/kgmol

-106925374.95 -4619722.61 -157785603.56

kg kg kg

a

+

QP Tinicial

Tfinal

Cpmedia

e

K

K

kJ/kgmol.K

2.90981E-04 -2.63849E-07 3.76892E-04 -4.11770E-07

8.00679E-11 1.38890E-10

343.150 343.150

298.150 298.150

36.847 55.513

1.17000E-03 -1.69695E-06

8.18910E-10

343.150

298.150

78.125

1.52844E-03 -2.18792E-06

1.04577E-09

343.150

298.150

103.305

1.40299E-03 -2.01608E-06 343.150 Temp. Final, K

9.66369E-10 298.150

343.150 343.150

298.150 298.150

94.492 94.492

Tinicial

Tfinal

Cpmedia

c

d

c

d

e

K

K

kJ/kgmol.K

5.45064E-06

5.13186E-09

-4.25308E-12

343.150

298.150

29.134

4.33779E-05 -3.70082E-08

1.01006E-11

343.150

298.150

29.582

1.34154E-05 -3.71755E-09

-1.23881E-12

343.150

298.150

29.228

298.150

343.150

298.150

29.228

Tinicial

Tfinal

Cpmedia

343.150

Temp. Final, K

c d 2.90981E-04 -2.63849E-07 3.76892E-04 -4.11770E-07 1.17000E-03 -1.69695E-06

e 8.00679E-11 1.38890E-10 8.18910E-10

K 298.150 298.150 298.150

K 1395.059 1395.059 1395.059

kJ/kgmol.K 63.568 107.650 218.629

1.52844E-03 -2.18792E-06

1.04577E-09

298.150

1395.059

280.676

3.74572E-08

-8.13304E-12

298.150

1395.059

50.653

-7.37067E-05

4.79892E-08

-2.87266E-11

298.150

1395.059

29.561

3.29983E-05 -2.04467E-08

4.30228E-12

298.150

1395.059

39.366

4.33779E-05 -3.70082E-08

1.01006E-11

298.150

1395.059

33.531

5.45064E-06

-4.25308E-12

298.150

1395.059

31.645

-1.85118E-12 1395.059

298.150 298.150

1395.059 1395.059

33.457 33.457

-1.86440E-05

5.13186E-09

8.26593E-06 -6.19598E-10 298.150 Temp. Final, K

kJ kJ kJ kJ kJ kJ

kJ kJ kJ

Cp.∆T

Moles

Q

kJ/kgmol

kgmol

kJoules

-1658.103 -2498.089

0.000 0.000

0.000 0.000

-3515.604

24.021

-84447.789

-4648.716

44.610

-207379.900

-4252.126 -4252.126

68.631 68.631

-291827.689 -291827.689

Cp.∆T

Moles

Q

kJ/kgmol

kgmol

kJoules

-1311.017

3393.819

-4449355.978

-1331.184

902.154

-1200933.659

-1315.252

4295.974

-5650289.637

-1315.252

4295.974

-5650289.637

Cp.∆T

Moles

Q

kJ/kgmol 69728.193 118082.586 239816.478

kgmol 0.000 0.000 0.721

kJoules 0.000 0.000 172817.870

307876.417

1.338

412032.394

55562.084

225.979

12555858.224

32425.446

17.009

551529.732

43180.750

309.560

13367038.526

36780.819

512.891

18864549.379

34711.304

3393.819

117803894.639

36699.411 36699.411

4461.317 4461.317

163727720.764 163727720.764

Combustión de 4 hidrocarburos, con una y una selectividad. Balance de mat

Llenar las celdas amarillas con los datos solicitados. Los resultados se obt

Varias conversiones y selectividades

COMBUSTIÓN Aire seco

ε

=

85.00

Combustible Flujo =

51350.000

(kgmol)

V

CH4

=

45.000

% molar

C 2 H6

=

15.000

% molar

C 3 H8

=

20.000

% molar

C4H10 =

20.000

% molar

η2 =

100.000

% molar

S2

=

η3

=

S3

=

η4

=

>

REACTOR Estequiométrico

V

η1

=

S1 =

S4 =

Flujo molar y másico CH4

=

693.23

kgmol

11091.60

kg

C 2 H6

=

385.13

kgmol

11553.75

kg

C 3 H8

=

308.10

kgmol

13556.40

kg

C4H10 =

205.40

kgmol

11913.20

kg

CO2

=

103094.37

kgmol

4536152.19

kg

CO

=

4098.76

kgmol

114765.20

kg

H2 O

=

156951.28

kgmol

2825122.95

kg

O2

=

170246.30

kgmol

5447881.71

kg

N2

=

###

kgmol

###

kg

Total =

###

kgmol

###

kg

Gases de chimenea, húmedos CH4

=

0.03923

% molar

0.02207

% peso

C 2 H6

=

0.02179

% molar

0.02299

% peso

C 3 H8

=

0.01743

% molar

0.02698

% peso

C4H10 =

0.01162

% molar

0.02371

% peso

CO2

=

CO H2 O

= =

5.83380 0.23194

% molar % molar

9.02791 0.22841

% peso % peso

8.88140

% molar

5.62260

% peso

O2

=

9.63372

% molar

10.84244

% peso

N2

=

75.32907 100.00000

% molar % molar

74.18289 100.00000

% peso % peso

Total =

Gases de chimenea, secos CH4 C2H6 C3H8 C4H10 CO2 CO O2 N2 Total

= = = = = = = = =

0.04305 0.02392 0.01913 0.01276 6.40242 0.25454 10.57273 82.67145 100.00000

% % % % % % % % %

molar molar molar molar molar molar molar molar molar

0.02339 0.02436 0.02859 0.02512 9.56575 0.24201 11.48839 78.60238 100.00000

% % % % % % % % %

peso peso peso peso peso peso peso peso peso

carburos, con una conversión d. Balance de materia.

citados. Los resultados se obtienen automáticamente.

idades Reacciones: CH4 + 2 O2 CH4 + 1.5 O2

-----> CO2

+ 2 H 2O

(1)

-----> CO

+ 2 H 2O

(2)

C2H6 + 3.5 O2

-----> 2 CO2

+ 3 H2O

(3)

C2H6 + 2.5 O2

-----> 2 CO

+ 3 H 2O

(4)

-----> 3 CO2

+ 4 H 2O

(5)

C3H8 + 3.5 O2

-----> 3 CO

+ 4 H 2O

(6)

C4H10 + 6.5 O2

-----> 4 CO2

+ 5 H 2O

(7)

97.000

% C4H10 + 4.5 O2

-----> 4 CO

+ 5 H2O

(8)

96.000

%

95.000

%

98.000

%

CH4

=

23107.50

kgmol

46215.00

kgmol

97.000

%

C 2 H6

=

7702.50

kgmol

26958.75

kgmol

97.000

%

C 3 H8

=

10270.00

kgmol

51350.00

kgmol

98.000

%

C4H10 =

10270.00

kgmol

66755.00

kgmol

95.000

%

Total

51350.00

Total

191278.75

kgmol

Oxígeno estequiométrico =

191278.75

kgmol

Oxígeno en exceso = Oxígeno alimentado =

162586.94 353865.69

kgmol kgmol

1331209.01

kgmol

1685074.70

kgmol

%

C 3H 8 + 5 O 2

Alimentación:

=

Oxígeno necesario:

Nitrógeno alimentado = Aire alimentado

=

=

CH4

---> CO2

21517.70

kgmol

CH4

---> CO

896.57

kgmol

C2 H 6

---> CO2

7171.03

kgmol

C2 H 6

---> CO

146.35

kgmol

C3 H 8

---> CO2

9663.04

kgmol

C3 H 8

---> CO

298.86

kgmol

C4H10

---> CO2

9561.37

kgmol

C4H10

---> CO

503.23 49758.15

kgmol kgmol

Total que reaccionó =

Masa total de entrada Masa total de entrada % peso % peso % peso % peso % peso % peso % peso % peso % peso % peso

% % % % % % % % %

peso peso peso peso peso peso peso peso peso

Diferencia

= = =

50245889.417 50245889.417 0.000

369720.00

kg

231075.00

kg

451880.00

kg

595660.00

kg

1648335.00

kg

6120920.00

kg

5202782.00 11323702.00

kg kg

37273852.42

kg

###

kg

kg kg kg

Dos cilindros que se ponen en contacto, al equilibrio, y luego se enfría Balance de energía. Cálculo del calor eliminado de los cilindros

Cilindro A P, kPa = 750.00 T, °C

=

V, litros = Sr =

Cilindro B P, kPa =

45.00

T, °C

1300.00

V, litros = Sr =

0.75

=

Benceno Porcentaje molar N2 = 65.000 O2 = 14.000 CO2 = CO = Total =

Porcentaje molar N2 = O2 = CO2 =

15.000 6.000 100.000

CO = Total =

Temperatura final de enfriamiento =

30.000 303.150

NA =

368.907

NB =

gmol

Constantes

Clave

Compuesto

A

de Antoine

12

BENZENE

14.1603

@T= @T=

318.150 358.150

Porcentaje molar de A N2 = 63.087 O2 = 13.588 CO2 =

14.559

K

Pv =

29.432

K

Pp = Pv = Pp =

22.074 116.385 104.747

Porcentaje molar de B N2 = O2 = CO2 =

CO = Vapor = Total =

5.823 2.943 100.000

CO = Vapor = Total =

Dos cilindros que se ponen en contacto, al equilibrio, y luego se enfría Cálculo de la temperatura de saturación y de% de condensación Balance de energía. Cálculo del calor eliminado de los cilindros

Cilindro A P, kPa = 750.00 T, °C = 45.00 V, litros = Sr =

1200.00 0.75

Cilindro B P, kPa = T, °C = V, litros = Sr =

Benceno Porcentaje molar N2 = 65.000 O2 = 14.000 CO2 = CO = Total =

15.000 6.000 100.000

Porcentaje molar N2 = O2 = CO2 = CO = Total =

NA = Constantes de Antoine

340.529 Clave 12

@T= @T=

318.150 358.150

NB =

gmol Compuesto BENZENE K

Pv =

29.432

K

Pp = Pv = Pp =

22.074 116.385 104.747

Porcentaje molar de A N2 = 63.087 O2 = 13.588 CO2 = CO = Vapor = Total =

A 14.1603

Porcentaje molar de B N2 = O2 = CO2 =

14.559 5.823 2.943 100.000

CO = Vapor = Total =

Temperatura final de enfriamiento = Temperatura final de enfriamiento =

35.000 308.150

Tabla de resultados para llenar a mano SR en %

% condensa

Calor eliminado en J

69.3395 69.0000 67.0000 66.7393

92.356 93.312 99.200 100.000

0.000 0.000 0.000 0.000

0.000 -9,546.815 -65,731.271 -73,047.860

66.0000 65.0000 63.0000 61.0000 59.0000 57.0000 55.0000 53.0000 51.0000 45.0000 40.0000 35.0000

100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000

2.262 5.259 11.040 16.545 21.782 26.761 31.490 35.977 40.231 51.679 59.832 66.855

-137,358.322 -223,279.609 -391,516.900 -555,040.103 -713,962.009 -868,396.661 -1,018,459.160 -1,164,265.484 -1,305,932.294 -1,707,268.705 -2,016,351.477 -2,304,326.223

Tfinal

en °C

Num. 12 16 18 121 115 1000 1000 1000 1000 1000

Num. 12 12 12

Nombre BENZENE CARBÓN DIOXIDE CARBÓN MONOXIDE OXYGEN NITROGEN VACÏO VACÏO VACÏO VACÏO VACÏO

Compuesto BENZENE BENZENE BENZENE

Fracción mol yi 0.07552 0.12404 0.05059 0.11967 0.63017 0.00000 0.00000 0.00000 0.00000 0.00000 1.00000

Peso molecular 78.108 78.108 78.108

a 1.85868E+01 1.90223E+01 2.90063E+01 2.98832E+01 2.94119E+01 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 2.73415E+01 Temp. Inicial, K

Tb

λb

K 353.261 353.261 353.261

KJ/Kgmol 30763.400 30763.400 30763.400

Contenido molar de A

o, y luego se enfrían.

N2 =

232.732

gmol

o de los cilindros

O2 =

50.127

gmol

CO2 =

53.707 21.483

gmol gmol

10.858 368.907

gmol gmol

CO = Vapor = Total = Cilindro B 925.00

Juntando ambos cilindros

85.00 1450.00

N2 =

516.559

gmol

0.90

O2 =

98.098

gmol

CO = Vapor =

101.678 41.471 61.906

gmol gmol gmol

Total =

819.711

gmol

Vtotal =

2750.00

litros

CO2 =

Benceno

Porcentaje molar 71.000 12.000 12.000 5.000 100.000

Balance de energía -Qp,A = Qg,B

Ahora, utilizando la hoja de capacidades caloríficas de los g se procede a calcular la temperatura final de equilibrio, de

°C K

dos cilindros. Tfinal =

450.805

-Qp,A = Qg,B =

gmol

342.4895

-2686791884.756

B

C

Procederemos a calcular si se presenta la condensación de

2948.78

-44.5633

vapor, al enfriarse los cilindros. Si existe condensación, se calculará la cantidad condensada del vapor.

kPa kPa kPa kPa

Pequilibrio =

848.070

kPa

'No condensa'

rcentaje molar de B 62.960

Pfinal =

750.658

10.641 10.641

'Sí condensa'

kPa

4.434 11.324 100.000

Moles de vapor que permanecen en la fase gaseosa, saturada = Moles de vapor que condensaron, dejando la mezcla saturada =

Cálculo del calor eliminado del cilindr

Usando la página de capacidad calorífica de los gases, se calcula e Usando la página de propiedades generaleses, se calcula el calor laten Calor sensible = -1374.972 Calor latente = -33377.208 Calor sensible = -1127080.212 Calor latente = -1492207.637 Q

o, y luego se enfrían. de condensación

o de los cilindros

=

-2619287.849

Contenido molar de A N2 = 232.732 gmol O2 = 50.127 gmol CO2 = 53.707 gmol CO = Vapor = Total =

Cilindro B 925.00 85.00

21.483 10.858 368.907

gmol gmol gmol

Juntando ambos cilindros

1450.00

N2 =

516.559

gmol

0.90

O2 =

98.098

gmol

CO = Vapor =

101.678 41.471 61.906

gmol gmol gmol

Total =

819.711

gmol

Vtotal =

2650.00

litros

Benceno

Porcentaje molar 71.000

CO2 =

12.000 12.000 5.000 100.000

Balance de energía -Qp,A = Qg,B

Ahora, utilizando la hoja de capacidades caloríficas de los g se procede a calcular la temperatura final de equilibrio, de dos cilindros.

Tfinal = 450.805 B 2948.78

-Qp,A = Qg,B =

gmol C -44.5633

342.4895

-2686791884.756

Procederemos a calcular si se presenta la condensación de vapor, al enfriarse los cilindros. Si existe condensación, se calculará la cantidad condensada del vapor.

kPa kPa kPa kPa

Pequilibrio =

849.606

kPa

'No condensa'

rcentaje molar de B 62.960 10.641 10.641 4.434 11.324 100.000 °C K Pfinal =

764.421

kPa

'Sí condensa' Moles de vapor que permanecen en la fase gaseosa, saturada = Moles de vapor que condensaron, dejando la mezcla saturada = Porcentaje del vapor que condensó =

Cálculo del calor eliminado del cilindr

Usando la tabla de capacidad calorífica de los gases, se calcula el Usando la tabla de propiedades generales, se calcula el calor latente Calor sensible = -1199.337 Calor latente = -33131.315 Calor sensible = -949076.301 Calor latente = -1380392.560 Q

=

-2329468.861

b -1.17439E-02 7.96291E-02 2.49235E-03 -1.13842E-02 -3.00681E-03 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 5.85927E-03 342.490

c 1.27514E-03 -7.37067E-05 -1.86440E-05 4.33779E-05 5.45064E-06 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 9.48415E-05 Temp. Final, K

d -2.07984E-06 3.74572E-08 4.79892E-08 -3.70082E-08 5.13186E-09 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 -1.51195E-07 308.150

Tc

Pc

Treal

Tr1

Tr2

λreal

K 562.611 562.611 562.611

Kpa 4924.410 4924.410 4924.410

K 308.150 308.150 308.150

K 0.627896 0.627896 0.627896

K 0.547714 0.547714 0.547714

kJ/kgmol 33131.315 33131.315 33131.315

Contenido molar de B N2 =

283.827

gmol

O2 =

47.971

gmol

CO2 =

47.971 19.988

gmol gmol

51.049 450.805

gmol gmol

CO = Vapor = Total =

Llenar las celdas amarilla, café, rosa

V = 22.4 �/���� ∗�, ���� ∗��������/273.15�∗(101.3 Calcular V

V

=

n = Tsistema =

55.234 320.150

Psistema =

500.000

N2 =

63.017

% mol

O2 =

11.967

% mol

CO2 =

12.404 5.059 7.552

% mol % mol % mol

Calcular n V =

n = 600.000

100.000

% mol

Tsistema =

285.150

Psistema =

850.000

CO = Vapor = Total = Ntotal =

819.711

gmol

ergía -Qp,A = Qg,B

pacidades caloríficas de los gases, ratura final de equilibrio, de los

Calcular T V = n =

T 293.796 55.234

Psistema =

500.000

K

2686791884.756

J

Calcular p V = n = Tsistema =

presenta la condensación del

. Si existe condensación, se d condensada del vapor. Pv =

70.995

kPa

Pp =

56.691

kPa

Pv =

15.750

kPa

P = 6000.000 3400.000 306.656

gaseosa, saturada = la mezcla saturada =

17.199 44.707

gmol gmol

eliminado del cilindro

ca de los gases, se calcula el calor sensible. ses, se calcula el calor latente de condensación. J/gmol J/gmol J J J

Contenido molar de B N2 = 283.827 gmol O2 = 47.971 gmol CO2 = 47.971 gmol CO = Vapor = Total =

19.988 51.049 450.805

N2 =

63.017

% mol

O2 =

11.967

% mol

CO2 =

12.404 5.059 7.552

% mol % mol % mol

Total =

100.000

% mol

Ntotal =

791.334

gmol

CO = Vapor =

ergía -Qp,A = Qg,B

pacidades caloríficas de los gases, ratura final de equilibrio, de los

gmol gmol gmol

K,

°C

2686791884.756

69.3395 J

presenta la condensación del . Si existe condensación, se d condensada del vapor. Pv =

70.995

kPa

Pp =

57.731

kPa

Pv =

19.554

kPa

SR

=

gaseosa, saturada = la mezcla saturada = apor que condensó =

295.242 20.242 41.664 67.302

% gmol gmol

eliminado del cilindro

a de los gases, se calcula el calor sensible. s, se calcula el calor latente de condensación. J/gmol J/gmol J J J

e 1.05329E-09 -8.13304E-12 -2.87266E-11 1.01006E-11 -4.25308E-12 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 0.00000E+00 7.56132E-11

λreal kJ/kg 424.173 424.173 424.173

Masa kgmol 41.664 41.664 41.664

Tinicial

Tfinal

Cpmedia

Cp.∆T

K 342.490 342.490 342.490 342.490 342.490 342.490 342.490 342.490 342.490 342.490 342.490 342.490

K 308.150 308.150 308.150 308.150 308.150 308.150 308.150 308.150 308.150 308.150 308.150 308.150

kJ/kgmol.K 89.899 38.321 29.175 29.611 29.140 0.000 0.000 0.000 0.000 0.000 34.926 34.926

kJ/kgmol -3087.094 -1315.924 -1001.870 -1016.820 -1000.667 0.000 0.000 0.000 0.000 0.000 -1199.337 -1199.337

∆Hv kJ 1380392.560 1380392.560 1380392.560

∆Hv kcal 329775.783 329775.783 329775.783

Ecuación de los gases ideales

amarilla, café, rosa y verde, según el caso. Los resultados se obtienen en la celda gris.

�/���� ∗�, ���� 73.15�∗(101.3 ���)/�������� 293.7963 litros gmol

V = 359 ���3/�����∗ °�) ∗(14.7 ����)/���� Calcular V

K

n = Tsistema =

kPa

Psistema =

215.2983 gmol litros

Calcular n V =

K

Tsistema =

kPa

Psistema =

320.1500 K litros gmol

Calcular T V = n =

kPa

Psistema =

1443.5618 kPa litros gmol

Calcular P V = n = Tsistema =

K

Moles

Q

kgmol 59.763 98.158 40.035 94.702 498.676 0.000 0.000 0.000 0.000 0.000 791.334 791.334

kJoules -184494.958 -129168.600 -40109.923 -96294.464 -499008.356 0.000 0.000 0.000 0.000 0.000 -949076.301 -949076.301

∆Hv BTU 1308634.058 1308634.058 1308634.058

ideales

V = 359 ���3/�����∗�,����� ∗��������/(492 °�) ∗(14.7 ����)/�������� V

=

5363.1098 pie3

125.000

lbmol

600.000

°R

150.000

psia

n = 17.657 636.000 58.050 T = 5363.110 125.000 150.000 P = 5363.110 125.000 600.000

0.1503

lbmol pie3 °R psia

600.0000 °R pie3 lbmol psia 150.0000 psia pie3 lbmol °R

Otras leyes de los gases Ley de Charles

V1/T1 = V2/T2 V1 =

100.000

litros

Dato forzado

T1 = V2 =

320.000 120.000

K litros

Dato forzado Dato opcional 1

T2 = T2 = V2 =

384.000 384.000 120.000

K K litros

Resultado 1 Dato opcional 2 Resultado 2

Ley de Boyle

P1*V1 = P2*V2 P1 = V1 =

150.000 300.000

kPa litros

Dato forzado Dato forzado

P2 =

200.000

kPa

Dato opcional 1

V2 =

225.000

litros

Resultado 1

V2 = P2 =

225.000 200.000

litros kPa

Dato opcional 2 Resultado 2

Ley de Gay-Lussac

P1/T1 = P2/T2 P1 =

300.000

kPa

Dato forzado

T1 = P2 = T2 =

350.000 500.000 583.333

K kPa K

Dato forzado Dato opcional 1 Resultado 1

T2 = P2 =

583.333

K kPa

Dato opcional 2 Resultado 2

Destilación multicomponente por métodos cortos de Destilación multicomponente Métodos cortos Alimentación =

1000.00 kgmol Zi, %molar Flujo molar

Clave

Componente

1 2

Propano n-Butano

40.000 40.000

400.000 400.000

3 4 5 6 7 8 9 10

iso-Pentano n-Pentano vacío vacío vacío vacío vacío vacío

10.000 10.000 0.000 0.000 0.000 0.000 0.000 0.000 100.000

100.000 100.000 0.000 0.000 0.000 0.000 0.000 0.000 1000.000

Total = Relación de reflujo Composición del destilado, ligero % Recuperación del ligero, en D Presión de la columna, en psía

= = = =

Componente clave ligero = Componente clave pesado = Destilado =

5.00 98.00 98.00 214.70 1 2 400.00 kgmol Xi, %molar Flujo molar 0.980 392.000 0.020 8.000 0.000 0.000 0.000 0.000 0.000 0.000

Clave 1 2 3 4 5

Componente Propano n-Butano vacío vacío vacío

6

vacío

0.000

0.000

7 8 9 10

vacío vacío vacío vacío

0.000 0.000 0.000 0.000 1.000

0.000 0.000 0.000 0.000 400.000

Total = Producto de fondos = Clave 1

Componente Propano

600.00 kgmol Xi, %molar Flujo molar 0.013 8.000

2 3 4 5 6 7 8

n-Butano iso-Pentano n-Pentano vacío vacío vacío vacío

0.653 0.167 0.167 0.000 0.000 0.000 0.000

392.000 100.000 100.000 0.000 0.000 0.000 0.000

9 10

vacío vacío

0.000 0.000 1.000

0.000 0.000 600.000

Total =

os cortos de Fenske- Underwood -Gilliland Condensador

Total Yi,1 = Xi,D

Equilibrio

Yi,1 = Ki * Xi,1

Equilibrio

Xi,1 = Yi,1 / Ki

suponiendo

T1 , en °F =

Clave 1 2 3 4 5 6 7 8 9 10

K 1.030 0.340 0.150 0.122 ### ### ### ### ### ### Total =

104.00

suponiendo

X1

Clave 1 2 3 4 5 6 7 8 9 10

0.95146 0.05882 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1.01028

Clave 1

(α)1

(α)B

(α)pr

3.029

2.288

2.633

2 3

1.000 0.441

1.000 0.517

1.000 0.478

4 5 6 7 8 9

0.359 ### ### ### ### ###

0.458 ### ### ### ### ###

0.405 ### ### ### ### ###

10

###

###

###

(α)i = Ki / Kj

(α)pr = [(αi )1*(αi )B ]1/2

SUMA(((α)pr Zi,F )/((α)p

SUMA(((α)pr X,iD )/((α)pr

Clave 1 2 3

Factor 0.915 -0.830 -0.048

Clave 1 2 3

Factor 2.242 -0.041 0.000

4 5

-0.038 0.000

4 5

0.000 0.000

6 7 8 9 10 1-q =

0.000 0.000 0.000 0.000 0.000 0.000

6 7 8 9 10 Suma =

0.000 0.000 0.000 0.000 0.000 2.201

θ = q= 1-q =

1.482 1.00 0.00

Rm =

1.201

Yi,B = Ki * Xi,B TB , en °F = K 2.700 1.180 0.610 0.540 ### ### ### ### ### ### Total =

222.00 X1 0.03600 0.77093 0.10167 0.09000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.99860

α)i = Ki / Kj = [(αi )1*(αi )B ]1/2

(((α)pr Zi,F )/((α)pr - θ))) = 1 - q

(α)pr X,iD )/((α)pr - θ))) = Rm + 1

Destilación multicomponente Métodos cortos Catálogo Clave

Componente

Clave

1 2

Metano Etileno

5 7

3 4 5 6

Etano Propileno Propano Isobutano n-Butano Isopentano n-Pentano n-Hexano n-Heptano n-Octano n-Nonano n-Decano

8 9 1000 1000

7 8 9 10 11 12 13 14

1000 1000 1000 1000

LK HK

Clave 5 7 8 9 1000 1000 1000 1000 1000 1000

LK HK

Clave 5 7 8 9 1000 1000 1000 1000 1000 1000

Fenske - Unde

n multicomponente todos cortos Alimentación = Componente

100.00 kgmol Zi, %molar Flujo molar

Propano n-Butano

40.000 40.000

40.000 40.000

Isopentano n-Pentano n-Decano n-Decano

10.000 10.000 0.000 0.000

10.000 10.000 0.000 0.000

n-Decano n-Decano n-Decano n-Decano

0.000 0.000 0.000 0.000 100.000

0.000 0.000 0.000 0.000 100.000

Total = Relación de reflujo Composición del destilado, ligero % Recuperación del ligero, en D Presión de la columna, en psía Componente clave ligero Componente clave pesado

= = = = = =

Destilado = Componente Propano n-Butano Isopentano n-Pentano Vacio Vacio Vacio Vacio Vacio Vacio

5.00 98.00 98.00 200.00 5 7 40.00 kgmol Xi, %molar Flujo molar 0.980 39.200 0.020 0.800 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

Total =

1.000

40.000

Producto de fondos =

60.00

kgmol

Componente Propano n-Butano Isopentano n-Pentano Vacio Vacio Vacio Vacio Vacio Vacio Total =

Xi, %molar Flujo molar 0.013 0.800 0.653 39.200 0.167 10.000 0.167 10.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.000 60.000

Fenske - Underwood - Gilliland

at1

at2

at3

ap1

ap2

ap3

-970689.000 -1280557.000

0.000 0.000

7.151 7.950

-0.770 -0.965

0.000 0.000

6.902 0.000

-1481583.000 -1524891.000 0.000 0.000

0.000 0.000 0.000 0.000

7.581 7.331 0.000 0.000

-0.932 -0.891 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000

Clave 5 7 8 9 1000 1000 1000 1000 1000 1000

(α)1

(α)B

(α)pr

3.029 1.000 0.441 0.359 0.000 0.000 0.000 0.000 0.000 0.000

2.288 1.000 0.517 0.458 0.000 0.000 0.000 0.000 0.000 0.000

2.633 1.000 0.478 0.405 0.000 0.000 0.000 0.000 0.000

LK HK

Ver Graficas K, Tops

K, Bottom

Destilado

1.012 0.288

2.773 1.090

0.125 0.105 1.000 1.000

0.583 0.512 1.000 1.000

Clave 5 7 8

Propano n-Butano Isopentano

1.000 1.000 1.000 1.000

1.000 1.000 1.000 1.000

9 1000 1000 1000 1000 1000 1000

n-Pentano Vacio Vacio Vacio Vacio Vacio Vacio

suponiendo

Valores de q liq sat (α)i = Ki / Kj (α)pr = [(αi )1*(αi )B ]1/2

SUMA(((α)pr Zi,F )/((α)pr - θ))) = 1 - q SUMA(((α)pr X,iD )/((α)pr - θ))) = Rm + 1

vap sat liq sub vAP sob liq-vap

Condensador

Total Yi,1 = Xi,D Yi,1 = Ki * Xi,1

Ver Graficas

Ver Graficas

Xi,1 = Yi,1 / Ki T1 , en °R = P1, en psia=

560.00 200.00 Xi

K 1.030 0.340 0.150

0.95146 0.05882 0.00000

0.122

0.00000

Total =

Fondos suponiendo Clave 5 7 8

Propano n-Butano Isopentano

9 1000 1000 1000 1000 1000 1000

n-Pentano Vacio Vacio Vacio Vacio Vacio Vacio

1.01028 1 0

1 0 Valores de q q=1 q=0 q>1 q