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• ajiménez_20

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Calcular los coeficientes de fugacidad de una mezcla etanol (1) / agua (2) a una T= 500K y P= 5,5 atm. (Y1=0,3 / Y2= 0,7) T (K) 500

P (bar) 5.572875

Etanol (1) Tc (K) 513.92 Pc (Bar) 61.48 Vc (cm^3/mol) 167 Tr 0.9729 ω 0.649 µ (debye) 1.7 µr 67.2729795 a 0.0878 b 0.05588181 f(0) -0.35491113 f(1) -0.05369275 f(2) 0.03391602 B11 -247.302517 B11real -258 error (%) 4.14631111 Lnφ1 -0.04150814 φ1 0.95934152

R (bar cm^3/mol K) 83.14

Y1

Y2

K12

0.3

0.7

0

Agua (2) Tc (K) 647.14 Pc (Bar) 220.64 Vc (cm^3/mol) 55.95 Tr 0.7774 ω 0.344 µ (debye) 1.8 µr 0 a -0.0109 b 0 f(0) -0.53946808 f(1) -0.34544041 f(2) -0.04938093 B22 -172.568393 B22real -171.2 error (%) 0.799295 Lnφ2 -0.0298459 φ2 0.97059509

Cruzado (12) Tc (K) 576.695924 Pc (Bar) 110.867597 Vc (cm^3/mol) -----Tr 0.86700804 ω 0.4965 µ (debye) ---------µr ---------a 0.03845 b 0.02794091 f(0) -0.44083462 f(1) -0.16726774 f(2) 0.00301316 B12 -225.258673 B12real -191 error (%) 17.936478 Bmezcla -154.12006