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Etanol H2O

Constantes de antoine Temp.Eb(°C) a b 78.37 5.33675 100 5.11564

Temp.(°C)

Psat etanol 72 73 74 75 76 77 77.5 78 78.37 79.4 80 81 82 83 84 85 86 87 88 89 90 91 92 92.4 92.5 92.7 92.8 92.88 98 99 100

c 1648.22 1687.537

Psat H2O 0.7863348297 0.8194280698 0.8536831917 0.8891322144 0.9258077634 0.9637430752 0.9831936967 1.0029720016 1.0178214534 1.0601315236 1.0854492087 1.1287683096 1.1735226736 1.2197492941 1.267485805 1.3167704847 1.3676422595 1.4201407073 1.4743060613 1.5301792134 1.5878017171 1.6472157911 1.7084643222 1.733487117 1.7397900947 1.7524530942 1.7588132045 1.7639150663 2.1169656671 2.1923129386 2.2698621432

0.33955713 0.35426967 0.3695166 0.3853133 0.40167545 0.41861905 0.42731397 0.4361604 0.44280552 0.46175422 0.47310317 0.49253882 0.51264066 0.53342662 0.55491496 0.57712428 0.60007349 0.62378188 0.64826904 0.67355494 0.69965987 0.72660447 0.75440974 0.7657776 0.76864178 0.77439694 0.77728797 0.77960726 0.94053578 0.97498342 1.01047254

230.918 230.17

K1 etanol 1.00820443 1.05063515 1.09455558 1.14000678 1.18703058 1.23566959 1.26060834 1.28596722 1.30500654 1.35925468 1.39171592 1.44725779 1.5046399 1.56390967 1.62511535 1.68830603 1.75353162 1.82084285 1.89029132 1.96192945 2.03581053 2.11198868 2.19051889 2.22260203 2.23068344 2.24691939 2.25507404 2.26161543 2.71428161 2.81088861 2.91031884

Grafico 100 95 90

Grafico 100 95 90 85 Temperatura (°C)

80 75 70 65 60 0

P sistema (bar) P sistema (mmHg) 0.7799359 585

K2 H2O

x

0.4353654374 0.454229207 0.4737781629 0.4940320111 0.5150108552 0.5367351997 0.5478834529 0.5592259542 0.5677460354 0.5920412469 0.6065923765 0.6315119189 0.6572856271 0.6839364864 0.7114879072 0.7399637281 0.769388219 0.7997860845 0.8311824661 0.863602946 0.8970735492 0.9316207469 0.9672714587 0.9818468432 0.9855191681 0.9928981867 0.9966049363 0.9995786367 1.2059141996 1.2500814787 1.2955840803

y 0.9856775982 0.9150995243 0.8476819908 0.7832627726 0.7216888541 0.6628158601 0.6343493235 0.6065075236 0.5862974615 0.5317408879 0.5010773485 0.451719209 0.4044522869 0.3591740298 0.3157874627 0.2742008564 0.2343274177 0.1960849996 0.1593958292 0.1241862535 0.0903865007 0.0579304564 0.0267554547 0.0146307321 0.0116296558 0.0056632322 0.0026977728 0.0003338756 -0.1365146175 -0.1602257406 -0.1830542624

0.99376452 0.96143572 0.92783505 0.89292487 0.85666674 0.8190214 0.79966604 0.77994879 0.76512202 0.72277129 0.69735732 0.65375415 0.60855505 0.56171574 0.51319105 0.46293496 0.41090054 0.35703997 0.30130455 0.24364467 0.18400979 0.12234847 0.05860833 0.03251829 0.02594208 0.01272483 0.00608368 0.0007551 -0.37053912 -0.45037671 -0.53274627

x 0.9856776 0.91509952 0.84768199 0.78326277 0.72168885 0.66281586 0.63434932 0.60650752 0.58629746 0.53174089 0.50107735 0.45171921 0.40445229 0.35917403 0.31578746 0.27420086 0.23432742 0.196085 0.15939583 0.12418625 0.0903865 0.05793046 0.02675545 0.01463073 0.01162966 0.00566323 0.00269777 0.00033388

Grafico del Equilibrio Líquido Vapor Mezcla Etanol/Ag 100 95 90

Grafico del Equilibrio Líquido Vapor Mezcla Etanol/Ag 100 95 90 85 Temperatura (°C)

80 75 70 65 60 0

0.1

0.2

0.3

0.4

0.5 Fraccion molar

0.6

0.7

Grafica de punto de rocio a P = c 100

y 0.99376452 0.96143572 0.92783505 0.89292487 0.85666674 0.8190214 0.79966604 0.77994879 0.76512202 0.72277129 0.69735732 0.65375415 0.60855505 0.56171574 0.51319105 0.46293496 0.41090054 0.35703997 0.30130455 0.24364467 0.18400979 0.12234847 0.05860833 0.03251829 0.02594208 0.01272483 0.00608368 0.0007551

Temp.(°C) 72 73 74 75 76 77 77.5 78 78.37 79.4 80 81 82 83 84 85 86 87 88 89 90 91 92 92.4 92.5 92.7 92.8 92.88

90 Tíemperatura (°C)

80 70 60 0

0.2

0.4

0.6

0.8

1

1.2

Fraccion molar

Grafico de punto de burbuja a P = 100 90 Temperatura (°C)

Mezcla Etanol/Agua a P = cte.

80 70 60 0

0.2

0.4

0.6

0.8

Fraccion molar

1

1.2

Mezcla Etanol/Agua a P = cte.

x y

0.5

on molar

0.6

0.7

0.8

0.9

1

o de rocio a P = cte.

Column L

0.4

0.6

0.8

1

1.2

Fraccion molar

de burbuja a P = cte.

Column L

0.4

0.6

0.8

Fraccion molar

1

1.2

Etanol H2O

Constantes de antoine Temp.Eb(°C) a b 78.37 8.1122 100 8.0713

A12 Van Laar Margules

c 1592.864 1730.63

226.184 233.426

A21 1.6939 1.6432



0.9076 0.6923 

Van Laar Margules Ki Temp.(°C)

Psat etanol 72 73 74 75 76 77 77.5 78 78.37 79.4 80 81 82 83 84 85 86 87 88 89 90 91 92 92.4 92.5 92.7 92.8

589.2738048713 614.0050980954 639.5991224069 666.0793455805 693.4696669538 721.7944203002 736.3149327487 751.0783766268 762.1615844096 793.735462375 812.62518467 844.9397886779 878.3171053024 912.7841309881 948.3683145693 985.0975595161 1023.0002260986 1062.1051334699 1102.441561664 1144.039253512 1186.9284164733 1231.1397243819 1276.7043191084 1295.3161424667 1300.0039592313 1309.4216501173 1314.1515884978

Psat H2O 254.107507 265.160614 276.617873 288.49104 300.792115 313.533342 320.072907 326.727213 331.726211 345.983381 354.524102 369.153361 384.287749 399.94103 416.127225 432.860623 450.155774 468.027497 486.490881 505.561284 525.254338 545.585952 566.572309 575.153858 577.31615 581.661136 583.843864

K1 etanol 755.541327 787.250719 820.066268 854.018062 889.136744 925.453515 944.071087 963.000135 977.210543 1017.6932 1041.91278 1083.34517 1126.14012 1170.33224 1215.95674 1263.04939 1311.64654 1361.78516 1413.50278 1466.83754 1521.82816 1578.51398 1636.93493 1660.7982 1666.80872 1678.88368 1684.9482

92.88 98 99 100

1317.9456931662 1580.3142071495 1636.2634063673 1693.8320477389

585.594974 707.181739 733.228103 760.068868

1689.81283 2026.21037 2097.94601 2171.75802

Grafico 100 95 90 85 Temperatura (°C)

80 75 70 65 60 0

P sistema (bar) P sistema (mmHg) 0.7799359 565

Ki K2 H2O 325.8056302561 339.97744447 354.6674447962 369.8907051171 385.662610337 401.9988594495 410.3836055318 418.9154685696 425.3249669595 443.6048917753 454.5554348153 473.3124365154 492.7170931573 512.7870505557 533.5402889953 554.9951259732 577.1702188969 600.0845677356 623.757517625 648.2087614245 673.4583422255 699.5266558114 726.4344530663 737.4373436009 740.2097404003 745.7806930205 748.5792918491

x -0.7558265062 -0.7578754728 -0.7599233766 -0.7619703784 -0.7640166283 -0.7660622654 -0.767084895 -0.7681074191 -0.7688640278 -0.7709700493 -0.7721967482 -0.7742411383 -0.7762854759 -0.7783298497 -0.7803743418 -0.7824190282 -0.7844639792 -0.7865092593 -0.7885549284 -0.7906010414 -0.7926476488 -0.7946947969 -0.7967425281 -0.7975617926 -0.7977666246 -0.7981763078 -0.7983811591

y

x

-571.058161 -596.638011 -623.187527 -650.736466 -679.315258 -708.955016 -724.18267 -739.687548 -751.342034 -784.610977 -804.561663 -838.770396 -874.206216 -910.904519 -948.901441 -988.233873 -1028.93947 -1071.05664 -1114.62458 -1159.68328 -1206.27351 -1254.43685 -1304.21568 -1324.58919 -1329.72437 -1340.04517 -1345.23089

-0.75582651 -0.75787547 -0.75992338 -0.76197038 -0.76401663 -0.76606227 -0.76708489 -0.76810742 0.58629746 0.53174089 0.50107735 0.45171921 0.40445229 0.35917403 0.31578746 0.27420086 0.23432742 0.196085 0.15939583 0.12418625 0.0903865 0.05793046 0.02675545 0.01463073 0.01162966 0.00566323 0.00269777

750.824489372 906.717769347 940.1132877033 974.5273524799

-0.7985450448 -0.809043106 -0.8110958283 -0.8131493596

-1349.39166 -1639.29153 -1701.63525 -1765.96365

0.00033388

Grafico del Equilibrio Líquido Vapor Mezcla Etanol/Ag 100 95 90 85 Temperatura (°C)

80 75 70 65 60 0

0.1

0.2

0.3

0.4

0.5 Fraccion molar

0.6

0.7

Grafica de punto de rocio a P = c 100 95 90 85 Tíemperatura (°C)

y -571.058161 -596.638011 -623.187527 -650.736466 -679.315258 -708.955016 -724.18267 -739.687548 0.76512202 0.72277129 0.69735732 0.65375415 0.60855505 0.56171574 0.51319105 0.46293496 0.41090054 0.35703997 0.30130455 0.24364467 0.18400979 0.12234847 0.05860833 0.03251829 0.02594208 0.01272483 0.00608368

75

Temp.(°C) 72 73 74 75 76 77 77.5 78 78.37 79.4 80 81 82 83 84 85 86 87 88 89 90 91 92 92.4 92.5 92.7 92.8

80

70 65 60 0

0.2

0.4

0.6

0.8

1

1.2

Fraccion molar

Grafico de punto de burbuja a P = 100 90 Temperatura (°C)

80 70 60 0

0.2

0.4

0.6

0.8

Fraccion molar

1

1.2

0.0007551

92.88

Mezcla Etanol/Agua a P = cte.

x y

0.5

on molar

0.6

0.7

0.8

0.9

1

o de rocio a P = cte.

Column L

0.4

0.6

0.8

1

1.2

Fraccion molar

de burbuja a P = cte.

Column L

0.4

0.6

0.8

Fraccion molar

1

1.2