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U.S. Department of Homeland Security

United States Coast Guard

Chemical Data Guide for Bulk Shipment by Water

1990 CIM 16616.6A

U!illepartment cl Transportotk>n

Commandant ( G-MTH-1) United States toast Guard

MAILINC ADDRI!S$:

Washington, DC 20593 Phone: ( 202) 267-1577

llnhciSiales Coast Guard

COMDINST M16616.6A

0 8 NOV 1990

COMMANDANT INSTRUCTION Ml6616.6A Subj:

1.

Chemical Data Guide for Bulk Shipment By Water

PURPOSE.

This manual has been prepared to assist Coast

Guard personnel and others involved in bulk chemical shipment by water. 2.

DIRECTIVES AFFECTED. The Chemical Data Guide for Bulk Shipment by Water, dated January 28, 1982, is cancelled.

3.

CHANGE. Recommendations, comments, additional data and suggestions for improving this guide are requested by the Commandant (G-MTH-1).

~~ Rear Admiral, U.S. Coast Guard Chief, Office of Harine Safety,

Security and Environmental Protection

DISn..lllmON SDL No. 12 9 a b c d f h

•

1 1 1 8 5 1 2 8 20 1 1 1 10 D 1 3 1 1 1 E F G A

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1 1

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1

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5

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1 1

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1 1 1

1

10 1 1

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1 1 1 1 1

H NON.STA.NOA.FlO 01STFl1BUT1QJ\I

B:c MLCs (6 extra); CG-21

For sale by the Superintendent of Documentll, U.S. Govemment Printing Office Wuhington, D.C. 20ezing Point ..

___ ., ., ·c

______21'C _____l2"F

·c

-121"C ----=..!ll§"F

Vapor Pressure 200C (68'F) (mmHgJ. Reid Vapor Pressure (psia) ... Vapor_ Preuure 46'C (115"FJ (psia) Vapor Dem;ity (Air "" 1.()). Solubility in Water ..

Chemical Famil) -Aldehyde

C_ Pollution Catet~ur~-l'SJ-:PA _ _ C_ IMO _ _ Applicable Bulk Ret~. 46 \t'R Subchapter

__o_

_I&_

--ZlL __]£JL_

__LOL Complete

FIRE & EXPLOSION HAZARD DATA Grade-A. Flammable l1qu•d Ell'(:trical Gmup-C General-Produces .mtat,ng vapor when heated If pressure 1s used to unload tank, nitrogen or other inert gas must be used A1r pressure may cause e~plos1ve pero~1des to form Flashback along vapor trail may occur. Vapor may e~plorle il 1gn.ted m an enclosed area F1ash Point ("Fl 36 (CC) 40to57~o F1ammable l.imits Autoignition Temp. t"FI 365 Extinguishing Agents COo, dry chem1cal, alcohol loam. water fog Avo1d e~posure to vapors Wear self-contained breathing apparalus. u.. Special !''ire Procedures water log on large fires Use hose streams at max1mum range to cool exposed tanks Fight fire from a sale distance or from a protected location

HEALTH HAZARD DATA Health Ha1Jll'd Ratings 3. 1, 2

Odor Thruhold (ppm)

PEL/TWA (ppm)

TLV/TWA (ppml

100

100

2.3

General-Suspected carcinogen Vapor irritating, liquid causes skin and eye burns. Symptoms-Burn1ng of eyes. nose and throat, headache, rapid heartbeat: possible drowsiness with prolonged exposure. Short Exposure Tolerance-1100 ppm lor 2 hours IS severly 1rr1tat1ng to mucous membranes: 11,000 ppm for 1-2 hours has been reported as fatal t:xposure Procedures-Vapor-remove v1ct1m to fresh a1r; if breathmg stops, apply artificial respiration. Skin or eye contact-remove contammated cloih1ng and gently flush affected areas with water for 15 minutes. Get medical advice or attention

REACTIVITY DATA Stability-Highly reactive Can form explosive peroxides under air pressure. Slowly polymerizes to paraldehyde. Can react vigorously With oxidizing matenals Explodes when m1xed with iodine Compatibility-Material: Negligible corros1on to m1ld steel May d1ssolve rubber.

Cargo: Group 1g of compallbill\y chart.

SPILL OR LEAK PROCEDURE If possible, wear rubber gloves, self-contained breathing apparatus and protective clothing. Cover spill with sodium bisulfite (NaHSO,) Add small amount of water and mht Scoop up. Wash site with soap solution. Secure ignition sources

If a spill occun, call the National Response Center, 800-424-8802. Remarks:

2

ACETIC ACID (Glacial) s,-,.__ Acetic acid glacial; Ethanoie acid: Glacial

UnJted Natlou N11111ber. ,10%-80%

Glacial, >BO%

acetic aclcl; Methane carboxylic acid; Vinegar acid CHRIS Code ... Fonnula-CH,COOH

_____jJJ'C ____lli'F

BoiUD& Polllt .. ~Ofi88S

·c ____u·c

liquid; pungent vinegar-like

Freeztna PoJ.at ..

"""'

·c

Spedftc Grmty-1.05

_ _ _ 'F ____§,\l'F

_ _ _ 'F

___l1.L Vapor Preuure lO'C (68'F) (mmHI) .. ___Q&Q_ Reid Vapor Prellure (pda) .... _Q,iL Vapor Preaure 46'C (ll5'F) (p!lla) ... Vapor Deul.ty (Air = 1,0)... Complete SolubWty Ia Water ..

Cbemleal F...tiJ-Organic acid

-=-

PoUatlon c.tqory-USEPA ___.1L_ IMO _{L_ AppUable hlk R. . 46 CFR Subebpter ...... ____Q__

f1RE 4 EXPLOSION HAZARD DATA Grade-D: Combustible liQUid Eleetrkal G1'011p-0 Guenll-lgoited by heat and by some oxidizing agents. Vapor may explode If ignited In an enclosed area.

Flull PtNDt ('FJ ..

110 Flam-ble Umlls .. 5.4 to 16% at 212'F Autolpltloa Temp, ('F) .. 1050 Ex~Aplltl .. CO., dry chemical, alcohol foam, water fog SpeeW fl1n ProeediU'el ... Use personal protective equipment when contact with liquid is likely. Skin or clothing contact can cause serious burns. Wear self-contained breathing apparatus. Cool exposed tanks with water.

HEALTH HAZARD DATA Hellllb Hazarcl Ratinp

Odor 'Illrftbold (ppm)

2, 3, 2

PEVIWA 10

1.0

(ppm)

TLV/TWA

(ppm)

10

Geaerai-Vapor extremely irritating. Uquld causes severe burns. Symptoms-Burning of skin in cootact with liquid. Irritation of eyes and respiratory system.

Short EJ:ponre Toleraaee--40 ppm lor 5 minutes.

Eipotlll'e ProcedllJ'ei-Vapor-remove victim to fresh air; II breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently nush affected areas with water for 15 minutes. Get medical attention. Wash contaminated clothing, including shoes, before reuse.

REAcrJVITY DATA Stdllity-Can react vigorously with Oxidizing materials. Reacts violently with potassium hydroxide (caustic potash) and sodium hydroxide (caU8tlc soda).

Complltlbillty-M.terlal: Highly corrosive to metals when dilute. 316 and 318 stainless steels and aluminum are

satisfactory construction materials.

c.rso: Group 4 of compatibility chart. See also Appendix !-Exceptions to the Chart.

SPILL OR LEAK PROCEDURE Secure Ignition source&. If poSSible, wear rubber gloves, face shield, and protective clothing. Body shield and self-contained breathing apparatus should be available. Cover spill with soda ash or sodium bicarbonate. Mix, and add water II neceaaary for mixing. Scoop up sluny. Wash site with soda ash solution. Flush spills with large quantities ol water. Usually a spill into a navigable waterway woold quickly dilute to a harmless coocentration for humans. If a ~p~li oeeun, ea11 the NatioDal Rfiiiiii!IR Cealer, 800-4l4-880l. ReJIW'b: Below 62"F the ac1d may lreeze and expand enough to burst its containar.

3

ACETIC ANHYDRIDE S,W.)'IU: Acetic acid anhydride; Acetic oxide: Acetyl

UaUed N.OO. N . .ber...

oxide: Ethanoic anhydride

CHRIS Code .. F-ula-(CH,CO)tO

BcHIInl Pohlt .. A.~lorlessllqOO; pungent, highly

Freeztq Pohll...

irritating odor Spldftc: Gl"llYit)'-1.08

~·c --..ZIY'F

·c 'F _z:rc ___ ·c --:j'jii·F ___·F

Vapor Pre.llre lO'C (61'F') (mmHI) .. ~ Reid Vapot" Prea1are (pita) ......................... _.o..a...._ VaptQ" Pre.11n .t6'C (115'F') (pii'-J... ____g.!_ Vapor D...aty (Air = 1.0).......................... _ U SolllbWty Ia Water.. . 12% Apgraclllbl!

PoDudoll C.teawJ-USEPA ----'L_ IMO ----'L_ Applkable Bulk Rea. .t6 CFR S11beiaapm- ....... __Q__

FIRE It EXPLOSION HAZARD DATA Grade-D: Combustible liquid

Electrical Gro11p-D Galeral-Aeacts violently with water generating dangerous heat and pressure In confined spaces. Ignited by heat. Vapor may explode if Ignited in an enclosed space.

Flub Point

('F) .. 121 (CC) 2.7 to 10% Alltolpltloa Temp. ('F) .. 734 btlnpiAina: A.pa.tl ... CO:!, alCohol foam, water fog' or dry chemical. Cool outside of tanks with water spray. Apply water cautiously. DO NOT Spec:laJ F:lre Proeed- .. contaminate anhydride system with water. Usa self-contained respiratory protection and protective clothing.

n-....Weu.u•..

HEALm HAZARD DATA H•lth Huud Rr.tlap

-Stable up

to tempef'8tures

near the flash point.

c-.,.tlbftlty-Mtlterial: Compatible with steel, wood, most rubbers.

Carao: Group 37 of compatibility chart.

SPILL OR LEAK PROCEDURE If possible, wear long rubber gloves and protective clothing. Add an excess of strong calcium hypochlorite lution to the spill. Scoop up sluny. Wash site of spill with soap solution containing some hypochlorite.

It 1 spill

0tt11r1,

Clll tile N.tiODII RelpoMe Center, 800-4:Z4 880:Z

Remark&:

11

ALKYLBENZENESULFONIC ACID Synon,..._ decylbenzeneaultonlc acid; Un-, Do-, Tfi..,

UnJtM NM:IIIIQI Nlllllber...

Tetra-, Penta- or Hexa-: Oodecytbenzenaaultonic odd CHRIS Code .•.

Appearance-Odor-While to yellow liquid; odorless

Bouma Pot.t....

·c ___ 'F

Freezln& Pot.t..

---.C ---,F

Spedtk Gra'rit)'-1.0 to 1.4

·c

'F

==·c_·F

VlfOJ' PrlaiU'e lO'C (QI"F) ............... El:tlnpillaiq Apatl ..... ... .......... ...............

--'

.............

................... 1, 3, 1 General-Causes

98V8f8

275 15.0 to 27.0% 695 Carbon dioxide, dry chemical or alcohol foam Coot exposed tanks with water. Water or loam may cause frothing.

--.-

HEALTH HAZARD DATA PEL/TWA (ppm) Unavailable

Unavailable eye initatlon.

TI.VII'WA q,p.) Unavailable

s,...,._Uquid causes skin irritation with poSSibiWty o1 burns or prolOnged contact. Vapor causes mild resplratcMy IrritatiOn.

Shrt EllJ101'1111 TolenuH:e-Unavailable Ellpoare Procedllra-ln case ol eye contact, Immediately flush eyes with plenty of low-pressure water for 15 minutes. If discomfort persists or reappears, see a physician.

REACI'IVITY DATA StUWty-Stable.

Comp~t~WU~y-Matertal:

Incompatible with copper, copper alloys, aluminum and zinc.

c.rao: Group e ol compatlbiMty chart.

SPll.L OR LEAK PROCEDURE Avok:l contact with liquid. It possible, wear butyl rubber gloves, lace shield, and protective clothing. Cover spill with sodium bisulfite. Spray with water and wash away with large excess o1 water.

If a .,W. GCe111'1, caJJ tbe Ndoul 1te1po.e Ceatel", IIJ0....424-8802. Remarb:

+UnaS81Qned

IS

AMMONIA ANHYDROUS United Natto111 Nlllllller...

Synonyaa-Ammonia: Ammonia gas: H.N: Liquid

ammonia CHRIS Code .. Fonnulii-NHs

BoJilna: Pomt ... AppUf'811Ce·Odcu-Colorless liquid or gas: pungent, highly irritating odor

Specific Graflty-0.77 at

Freez.lag PoJat..

o·c

~·c ---=..2G'F

·c 'F -78'C -108'F ___ ·c ___ .F

Vapor Preuure lO'C (68'F) (••HI) .. . ....MIL ReJd Vapor ~re (...I)... . ...2ll...L_ Vapor P~re WC (115'F) (piU).. ~ Vapor De.Wty (AJr = 1.0).. ...................... ..Jl.aL

Cbemie.l Family-Ammonia

Pollutioa C.lqory-USEPA ____Jl_ IMO ____gu_ Applleable Bulk Reg, 46 CFR Subduipter .. ... __Q____

SoluWiity Ill Water....

Apprecjlb!a

FIRE & EXPLOSION HAZARD DATA Grade-liquefied Compressed Gas (LCG)

Electrical Group-O GeMrai-F1re hazard when in h1gh concentrations and at high temperature. Oil 01' other combustible vapors increase the fire hazard Flub Point ("F). lndeltrlite, below 32'F (sometimes difficult to ignite). Not flammable under conditions likely to be encountered Flammable Limits 16 to 25°'o Autolpltlon Temp. ("1-'l 1204 Stop the flow of gas (lighter than air); cool tanks with water spray. Extlnruiahlng Agents. Speclal Fire Procedurn Use respiratory and body protection when approaching ammonia-contaminated atmosphere liberal use of water fog, where possible, will reduce vapor concentration.

HEALTH HAZARD DATA HeaJth Haunt Ratinp 4, 2, 2

Odor

PEL/1WA (ppm)

(ppm) approK. 50

Thre~~hold

Unavailable

TLV/fWA (ppm)

25

General-Vapor extremely nritating. Liquid causes bums; will cause frostbite.

Symptoms-Coughing; burning sensation, eye irritation or pain. Frozen areas turn white. Short Exposure Tolerllll(e-A 2500 ppm (0.25%) concentration of ammonia in air may be fatal within 30 minutes. Exposure Pr~~«dures-Remove victim to fresh air. Gall a physician at once. If not breathing, apply artificial respiration, oxygen. If breathing is difficult, administer oxygen. Flush affected areas of body with plenty of water for 15 minutes. DO NOT FLUSH FROZEN AREAS. If the liquid has spilled onto the skin, points of contact may be frostbitten; handle gently and protect from mechanical damage. DO NOT RUB. Remove contaminated clothing and shoes. Get prompt medical attention. Low-velocity fog Is effective for decontaminating the atmosphere.

REACTIVITY DATA Stability-Normally stable. Reacts with acidic matEifials.

Compatlbllity-MiteriaJ: Corrosive to galvanized surfaces, copper and copper alloys. Iron and steel are suitable for the construction of containers, fittings and piping. Forms explosive compounds with mercury. CarKO: Groop 6 of compatibility chart.

SPILL OR LEAK PROCEDURE Evacuate area in case of large leaks or tank rupture. Shut off leak if without risk. Wear sell-contained breathing apparatus. If necessary to enter spill area, wear full protective clothing Including boots. Water spray is extremely effective in abscrbing ammonia gas and shoold be used around leaks of gas only. DO NOT PUT WATER ON LIQUID AMMONIA.

If a ..m oceun, eaU tbe National Rnpoaae Ceater, 800-4l4-880l,

Remarb:

16

AMMONIA SOLUTIONS United Nations Number.. 10-35%

__..2§Z2_

Ammonium hydroxide; Aqua ammonia; Household

35-50%

.....2QZL_

ammonia; Spirit of Hartshorn

50%ormore

~

Synonym&- Ammonia, aqueous; Ammonia water;

CHRIS Code. Formula-NH.OH Boiling Point ...

~·c~·F

·c 'F yarjes"F ·c ___ .,

AppearaJK:e-Odor-Colortess liquid; pungent odor

Freeziq Point .. Spe~:ific

Yaries·c

GriYity-0.88 at 20'C (liquid)

Vapor Pressure 20"C (68"F) (mmHg) .. Reid Vapor Pressure (psiaL Vapor Pressure (,.).. ____!__ Deul.t)' (Air = 1.0) ....................... ~ SoluWUty ID Water.. S!jghl

v.,.,..

___a_

A,uc.bte Balk R. . 46 CPR S.llcllapter ....... ___Q_

FIRE .t EXPWSION HAZARD DATA Grade-D: Combustible liquid Eledrlcal Grollp-0 GeDei'III-Moderate fire hazard when exposed to heat. The solid often evaporates without first melting.

Plull. Polllt ('F) .. FlMaaiWe U.ttl .. Aatolpitioll T•P· ('FJ •. Extblpilhj.. Apatl ..... Spedal Fire Proee11un1 ..

117 (cc) Unavailable 466'C

Foam, carbon diOxide or dry chemical Cool exposed tanks with water.

HEALTH HAZARD DATA TLV ITW A (ppm) PEL/1WA (ppm) Unavailable Unavailable Unavailable GeDeral-Vapors are nonirritating to the eyes and throat. If spilled on clothing and allowed to remain, smarting and reddening of the skin may result. Health Hazard lllltblp 0, 1, 1

Sympto~u-After

Odor 'Illrelllold (,...)

swallowing, nausea and vomiting; headache, confusion; jerky movements.

Sbort ExpoAre Toleraaee--Reliable data unavailable.

Elr;poNre Proeedare.-ln case ol contact, flush skin or eyes with plenty of low-pressure water. Get medical attention lor eye contact.

REACfiVITY DATA St.WHty-Stable. Can react with oxidizing materials.

Com,.ubility-Materlal: Carao; Group 18 ol compatibility chart.

SPIU. OR LEAK PROCEDURE Wear rubber gloves, lace shield, protective clothing. Avoid Shut.()fl leak. Flush area with watet.

contact with liquid.

Secure ignition sources.

If • llill oeean, call tile Nadellal ..,.._ CenterI 800-4l4-I801.

Re...-b: t Unavailable

53

CAPROLACTAM SOLUTION, 80% Ullltell N.U.. NUIIIer...

SyiHmflll'- Aminocaproic lactam; epailoo-Caprolac:tam; 2-Ketohexamethylenimine; 2-0xohexamethylenimine

CHRIS CWe ....

Formllla-C.H,,NQ Botllq: Pol•t .... . Appearance-Odor-Clear light yellow, liquid; odorless

Fl-eeziD1 Pot.t .. .

Spedftc Grnlty-1.06 ~ :ZO'C (61'FJ (.mfla) .... Rdd Vapor Pre.ure (pita)... VIIJIOI' Pr-.re 46'C (115'F> (piW .. Vapor Delll'ty (Air = 1.0) .•

VIIJIOI'

Che•kal Family-Cyclic amide Pollution Cateaory-USEPA - - - IMO ~ Applleable Balk Rea. 46 CFR Subebapter ....... ___IL_

SoluWllty Ia W.ter ..

FIRE & EXPWSION HAZARD DATA Grade-E: Combustible liqutd Electric:al Group-NA General-Toxic O)(ides of nitrogen may be formed in fire. Negligible hazard polymerization below 200'F.

Flull Point ('F) fhmlllable Umils Autolpition Temp. ("Fl E~:tinguilhina Alflltl .. Special Fire PTocfllurn

230 LEL= 1.84% UEL-Unavailable Greatet than 264 Water, dfY chemical, foam, CO,

HEALTH HAZARD DATA Odor lbre~:bold (ppm) PEL/I'W A (ppm) TLV/IWA (.,m) Healtb Huard Ratinp 0.3 mg/m• 5 0. 0. 4 5 GeneraJ-SIIght nazard, however, toxic vapors result from thermal decomposition above 400•F. Possibility of

thermal burns from hot liquid if carried at elevated temperature. Symptoms-Inhalation causes coughing or mild irritation. Sbort

Expo~~urt

Toltranct-Not pertinent.

Expo.AJrt Procedurm-lnh«lation-remove patient to fresh air. Eyes-wash with Skin-wash with soap and water.

water for 15

minutes.

REACTIVITY DATA StabUlty-Stable.

Co111p~~tiblllty-M•terial:

CarJo:

Non-corrosive to steel, wood, rubber, paint, cloth, or other common materials.

Group 22 of compatibility chart.

SPILL OR LEAK PROCEDURE Sect.Jre ignition sources. Spills may be ltushed with water.

If 1 apJII occura, eall tbe Narioul ReM~tb:

a.,.._ Ceale,

.:t: Unasalgned

54

II00-4l4-8101.

CARBON DISULFIDE Uldled NadoM N ...ber...

SJ11CM1r--Carbon bisulfide; carbon blsulphlcle; carbon dlsulphlde; Dithlocarbonlc anhydride

CHRIS Code ..

-

~lorleas

---.llli"F

Bolli-.:Polllt ...

~·c

Fretzbaa PoJIIt .•.

----=..1.1.1"C ---=.!AZ'F ·c _ _ _ •F

___ ·c

liquid; strong disagreeable

Spedfk: Grol.ty-1.28

_ _ _"F

Vapor Preaure lO'C (68'Fl C••HJ) ..

.....2&L_

ClleJmeal F...Uy--Sulfide

ReW Va,or Preaure

Polladoll Catqory-USEPA __a__ IMO ____a_

Vapcw Pre.ure 46'C (115'F> (pita) ... Vapor Dellalty (Air = 1.01 ... SolubiUty Ia Wlller ..

...1Q.L .....l.2.L

A.,uc:nte Bulk Rea. 46 CFR S.bcbapter ....... _Q__

c..-)...

_2M_ 02?%

FIRE 4 EXPLOSION HAZARD DATA GrMe-B: Flammable liquid Eleetrieal Gnmp-No electrical equipment allowed. Gelleni-Highly flammable liquid with unusually low autoignition temperature; contact with steam line or hot, bare electric light bulb can cause ignition. Burning releases irritating and toxic sulfur dioxide gas (SO!!).

!1l.dl Pol•t C'F> .. FWa.ab1e Umib ... Av.tolpidoa Te.p. ('F). EJ:dquilllbla A . .ls ...

~22 (cc) 1.3 to 44% 212

CO. or dry chemical A self-contained breathing apparatus is recommended. When burning, carbon Spedal Fire Prvcedarel .. disulfide produces sulfur dioxide, which Is toxic and highly irritating. Wear full protective clothing. Fight fire from a safe ::liatance or from a protected location.

HEALTH HAZARD DATA Odor Tbrfthohl (ppm) Hellldl Hazard Ratlap 2, 2, 3 0.21 General-Vapor harmful. Avoid skin contact with liquid.

PEL/1WA (ppm)

nvnwA (ppm)

4/Skin

10/Skin

SynqKo.-lighl·headedness, dizziness; prolonged contact with skin may ceuse burns.

tor 1/2 hour may cause severe symptoms and unconsciousness; 4,815 ppm for 1 hour has been reported as fatal.

Short Ez,aRre Tolennee-1,100 ppm

EllpoN111 ~Remove to fresh air. Give artificial respiration if unconscious. Get medical attention as soon as possible. It breathing Is difficult, administer oxygen.

REACfiVITY DATA StlbWty--Cargo tanks shOuld be isolated from high temperature fluids. Under conditions encountered on tankships and barges, carbon disulfide is not dangerously reactive. Must be shipped with pad of inert gas. eom,.tfWHty-M.aertal: May be slightly corrosive to metals of construction due and many plastics.

to

imporltles. Softens rubber

Carao: Group 38 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, safety glasses, protective clothing and self-contained breathing apparatus. Have carbon dioxide fire extinguisher available. Eliminate flammables and a" sources of Ignition. Note the low autoignitlon temperature {212'F). H 1 lpill Oftlln, c:all tile Na"-1.

Jlel...-e Ce•ter, 800-4l4-I801.

55

CARBON TETRACHLORIDE Sy-ymt- Benzinolorm; carbon tet; Methane,

United

N~OQ

NuMber ...

tetrachloro-; Necatorina: Perohloromethane;

Tetrachloromethane

CHRIS Code .. Fonnu!1-CCI• __2!!"C ____JB"F

·c

AppearaacH>dor-Colorless liquid; sweetish odor

Specific Gra.tty-1.59

\'1por Preaure 20"C (68"F) ..

FJa.-ble Ual.tl ..

Alltot&DitlOJl

Extiqailld.. Apntl ....

Spec:lal Ftre Procediii'M .. be ineffective. The vapors of cymene are more toxic than those of petroleum products.

HEALTH HAZARD DATA H..atb Huard IW:Iap 0, 1,1

PEUI'WA~l

Odor Threshold (ppm) Unavailable

Unavailable

TLV!TWA (ppm) Unavailable

General-High vapoJ concentrations are intoxicating.

s,-,._Dizziness, headache, and nausea. The victim may act as if drunk. Sbort ExpoMre Toleranee-Unavailable

Expollll'e Proceii-Vapor-remove victlm to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

REACTIVITY DATA Stabillty-Stable.

CompatiiNIIty-MIIterlal: Cymene will cause rubber to swell and soften.

Carao: Group 32

of compatibUty chart

SPILL OR LEAK PROCEDURE Wear rubber gloves, faca shield, protective clothing. Have all-purpose canister mask available. Secure Ignition

"""""''· If a 11pJU

Remarkl:

oc:eun~,

eall the N.ttoa.l Retp01111e Cellter, II00-4l4-880l.

Pollution category C 01l-l1ke, 33 CFR 151.49.

81

lso-DECALDEHYDE s,._,....._ lsodecaldehyde, mixed Isomers; UaUed NatiHI N . .ber... Trimethylheptanola

CHRIS Code .... Fonnula-C,H,.CHO, mixture of isomers

BoUIII& Polllt.. A~r-Colorless

liquid with a pleasant fruity

odol Spec:lftc Gna,lly-0.83

FNedq Polllt..

Cbemkal F&adly-Aldehyde

Reid v.,.,.. Vapor

____JJZ"C _ w " F

·c 'F -M'C ---=TI2'F

___ ·c ---·• v..- rr..ur. .zo·c C61'FJ c-HJ).. ~

v.,

Pollati1111 C.teaorY-USEPA - - - IMO ____@_Q_ A~lable Balk Re,:. 46 CFR Subdu;pter ...... ---'2.....Q...

rr-te (flta).

rr-re •·c Cll!I'F) C,u.J...

De.lly Wr = 1.0)..

SoliiWIIty In Water

.....2JlL..

_Q.QD_ ············ -A.B..... ln112!ubft

FIRE & EXPLOSION HAZARD DATA Grade-E: Combtlstible liqu1d

Electrical Group-C General-This matenal IS more of a health hazard than a fire hazard.

Flub Point

E~:tiaguit;bina A~nU.

185 Unavailable 375 Carbon dioxide, foam and dry chemical

Special Fire Procftura

Cool container surfaces with water.

('f}

Flam~Uble Limlu Autoip.ition Temp. ('f)

HEALTH HAZARD DATA Health Huard Ratlnp

1.1.1

Odor lbrabold (ppm) Unavailable

PEL/IWA C,.J

nvIIWA ()Ilia) ............ ~ ne-ll)' (Air .. 1.0)........................ .....J&..._ Sol"aWHiy Ia W.ter .... Sllqb!

Pollution Catep~ry-USEPA - - - IMO _____c__ Applkdlle Blllk Rq. 46 CFR Su~ ....... _.Q._

FIRE .t EXPLOSION HAZARD DATA Gndr-0: Combustible liquid E~lcal

Group-C

General-Highly dangerous when exposed to heat or flame

Flab. Point ('F)..

84

Flam-ble Umltl .. AutolpltJon Temp, ('F) .. EsdnpiMin& Allflltl ... Special Fire Proced!lrts ..

Unavailable Unavailable Alcohol foam, CO., dry chemical Full respiratory protection as well as body protection.

HEALTH HAZARD DATA Healtb Huard Ratinp 3, 4, 3

Odor 'l1lrelhold (ppm) Unavailable

PEL/IWA (ppm)

11.V/I'WA (pfm)

UnavaNable

unavailable

Geueral-Uquicl causes burns and eye injury.

Symptome-lrritation of lungs and respiratory

tract. Skln·llght irritation to burns.

Sbort Expo1ure Toleruce-E)(pOsures greater than 100 ppm will produce irritation of respiratory edema may resuh.

tract. Pulmonary

ExJIOillrt Proced• ee--Remove to fresh air. Give artificial respiration Of oxygen ae necessary. Skin, eyes-fluah immediately with water tor at least 15 minutes. Remove contaminated clothing at once.

REACJ'IVITY DATA Stability-Stable.

Comp.tjbUity-Miterlal: Will dissolve paint and most plastic materials.

Carto:

Group 7 Of compatibility chart.

SPILL OR LEAK PROCEDURE Wear seH·contained breathing apparatus. lull protective clothing and rubber gloves. Avoid contact with liquid. Secure ignitiOn sources.

If • .,W

occwn. eaJ1 tbe Nsdoul lteuoue c.ter, 100-424

109

8102.

DIISOBUTYL CARBINOL Ullited Natloq Number ...

Syncmr-- 2,6-Dimethyl-4-heptanol; aec-Nonyl alcohol

CHRIS Code .... F-uJ•-((CHa)JCHCH,)sCHOH ~lor1ea&. oily

liquid with.

characteristic odor Specltk Gra"rity-0.81

BoUiq; PoiDt....

____!Z&'C ~·F ·c 'F

Freezma Polllt...

-65'C -85'F ___ ·c ___ .,

Vapor ~- lfi'C (68'F) (laiDHa)..

v.,.., 1>eD1ftJ......_re (pita).. __2&L_ Vapor Denl.lty lAir = 1.0) .......................... ____!.i_ Solubility ln Water.. Negl"lqj'ple

Poll1tl011 Catesory-USEPA ------- IMO _.lL_ Appllc:roble Built Rea, 46 CFR Sabdaapter ....... --'2.........

FIRE & EXPWSION HAZARD DATA Grade-D: Combustible liquid Elec:trleal Group-O GeaeraJ-Moderate fire hazard when exposed to heat or flame.

Flath PoiDt ("F) .. Flammable Limits ....

140 0.8 to 6.2% 745 Carbon dioxide, dry chemiCal, alcohol fOam

AutolpJtlon Temp. ('FJ .. EJ:tfnguilbial Apntl .. Wear self-contained breathing apparatus. Cool fire-exposed tanks with water. Spedal Fire Proced~ .. Water may be ineffective on fire.

HEALTH HAZARD DATA Health Hazard lbltlnp 2, 1, 1

Odor 'I'hreQoJd (ppm) Unavailable

PEL/TWA (ppm)

25

TL V/TWA (ppm)

25

General-Fairly toxic if inhaled; minor skin irritation.

Symptoms-Redness or irritation of skin; irritation of eye, nose and throat. Sbort Ell:ponre ToleriUlCe-Animal tests show minor skin irritation, traces of eye injury. Inhalation resulted in 33% death rate in 8 hours, on test. Exposure Proc:edarea-lnhalation: Remove victim to fresh air, if breathing stops, apPly artificial respiration. Skin or eye contact: Flush affected areas lor 15 minutes with water. Get medical advice or attention.

REACI'IVITY DATA St.ltlllty-Stable. Can react with oxidizing materials.

ColllJIIItlltillty-Material: Mild steel can be used.

Carao:

Group 18 of compatibility chart.

SPILL OR LEAK PROCEDURE II possible, wear rubber gloves, lace shield, and protective clothing. Secure ignition sources. Have all-purpose canister mask available. Keep unprotected personnel upwind of contaminated area. Flush with water.

II 1 spill ooeura, call tbe N1Uoul Relpoue

Remarb:

112

Ceacer, 100-4l4-88Ql,

DIISOPROPANOLAMINE United Natioa Na•ber.............................. .

SyltOII)'DII- 2,2' -Dihydroxydlpropylamina; DIPA; 1,1 '-lminodi-2-propanol

CHRIS Code ..

Fona.uJa-(CH,CHOHCH.).NH BoUiq Point.. .. A~While

crystalline sotid or colorless

Freezhla Poblt..

monen liquid; ammonia-like odor Spedfte Graflty-0.98 at 42'C

__2!i'C ____410'F ·c 'F __...U'C ----l.QI'F

___ ·c ---·•

Vapor Preuure lG'C (61'F) eposed to heat or name; mOderate explosion hazard when vapor exposed to heat or flame. Flula ..,__ble

Polat ('F) .• U.ib ..

AatoJpldoa t-p. ('F') .. E:.:tblrpdal;q Alftlls ... Spedal Fire Procedllrel ..

75 1.2 to 8.0% at 200'F 858 CO., dry chemical, alcohol loam, water fog Fire parties rT)Ust wear respiratory protection. Water may be ineffective on f1re.

HEALTH HAZARD DATA PEL/IWA (ppm) Health Huanl Rati~~p Odor Tbl'elbohl (ppta) TLVnwA()I..-l 50 50 1, 1,1 0.47 GeDeral-Vapor causes eye, nose, throat irritation. Aspirated methyl isobutyl ketone may cause severe lung damage and present a significant hazard. Repeated or prolonged skin contact may cause defatting of the skin with Plimary irritation resuning. SymptOIQ-Headache, dizziness and nausea. Sltort E~:potun Toleruee-200-400 ppm for 5 minutes has produced eye irritation; 400 ppm lor 5 minutes may pioduce nasal irritation. EJ:)IOIUI"i! Procedur-Vapor-femove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes. II swallowed, do not induce vomiting. Get medical attention.

REACfiVITY DATA Stllbillty-Stable.

Co.INitlbillty-Mtlterlal: Will soften many plastics.

Carao:

Group 18 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact with liquid. Secure ignition sources.

If a IP'U oc:eun, call the N.Uoaal Rspoue Caller, 800-4l4-880:Z.

204

METHYL METHACRYLATE Synonym~-

Crystalite; Methacrylate monomer: Methacryllc acid, methyl ester; Methyl methacrylate monomer, inh.; Methyl alpha-methacrylate; Methyl-2-methyl propenoate; 2-Methylpropenoic acid; 2-Propenoic acid, 2-methyl-, methyl ester

Formula-CHo =

United Nation• Number ...

CHRIS Code ..

C(CH~)COOCH,

Boilln1 Point .. Appearance-Odor-Colorless liquid;

a~rid

odor

Free:d111 Point .. Spedftc Grnity--0.94

--ll!!l·c ·c -4B'C ___ ·c

Vapor Preaure :zo•c (68'F) (mmHg) .. Reid Vapor PreRure (ll'if.l ... Vapor Preuure 46'C (lHi'F) (psja) .. Vapor Delllity (Air = 1.01 ... Solultlllty In Water ..

Cbemlcal Famlly-Acrylates

Pollution CateiJOI')'-USEPA _____c__ IMO _____Q__ Applicable Bulk Res. 46 CFR Subchapter ....... ____Q__

--=.I!.L

~ ___ML

Slight

FIRE & EXPLOSION HAZARD DATA Grade-C: Flammable liquid

Eleetrieal Group-O General-Ignited by heat, sparks, or open flame. Fire may cause violent rupture of tank because of polymerization.

F1aeh Point

55 2.1 to 12.5% 790 Foam, carbon dioxide and dry chemicals Edlnpillllq Alents .. Cool exposed tanks with water. Wear eye protection, self-contained breathing Special Fire Procedurn ... apparatus and protective clothing. ('F) ..

Flammable Umlts .. Autolpltlon Temp. ("F) ..

HEALTH HAZARD DATA Odor 'I'IIrnhold (ppm) 0.05

Health Hazard Ratlnp 3, 2, 3

PEL/TWA (ppm)

TLV!TWA (piJIII)

100

100

General-Vapor irritating.

Symptoms--Smarting of the skin and first-degree burns on short exposure and may cause second-degree bums on long exposure. Sbort Expo11ure Tolenmee-200 ppm

Exposure Protedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and flush affected areas with water for 15 minutes. Get medical advice or attention.

REACI1VITY DATA StaiHIIty-Polymerizes readily. Methyl methacrylate will not decompose on prolonged storage if properly inhibited. Compatibility-Material: Noncorrosive to steel, aluminum or stainless steel.

Carao: Group 14 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact with liquid. Secure ignition sources.

If a

..W

occurs, call tbe Nadoaal Retponaa ee.ter, 800-4l4-810:Z.

Remarlu: • Vapor Pressure: 40 mmHg at 2s.s•c.

205

alpha·METHYLSTYRENE Synooyn~s-AMS;

lsopropenylbenzene; 1-Methyl-1-phenylethylene; Phenylpropylene

United Nations Number .....

CHRIS Code ..

Bollin1 Point .. Appeanmce-04or-Ciear yellow liquid; characteristic aromatic odor Specific: Gral'ity-0.89

Freezin& Point ..

..l.§B12'C

~·F

-23'C

-9'F ___ ·c ___ ·F

O.emical Family--Olefin

Vapor Pressllll.' ltl'C (68'FJ (mmH&) ..

-4.l!L

Reid Vapor Pressure {plia)... Vapor Preaure 46'C (ltS'F) (plla).

___2.2L _ML

Pollution Category-USEPA - - - IMO ___A__ Applicable Bulk Rea- 4(i CFR Subchapter ....... ____Q__

Vapor Denaity (Air = 1.0) .... Solubility In Water ..

-4.l!L lnsotyb!e

FIRE & EXPLOSION HAZARD DATA Gnute-D: Combustible liquid Electriul Group-O

General-Moderate fire hazard when exposed to heat or flame.

12510 135 1.9 to 6.1% 1066 Dry chemical, foam, CO., water log Water may be ineffective on lire.

Flash Point ("F) .. Flammable Limits .. Autolgnltlon Temp. ('F) .. Extlnpl•hlna Apnts. Special Fire Proeedures .

HEALTH HAZARD DATA Health Hazard Ratlnp Unavailable

Odor Threshold (ppm) Less than 10

PELJTW A (ppm)

50

TLV;TWA (ppm)

50

General-Avoid skin contact. Not known to be absorbed.

Symptom1--Will cause skin irritation if not removed promptly. Breathing considerable quantities may cause headache and/or dizziness. Short Exposure Toleram;:e--Unavailable

Exposure Procedures-Skin contact-flush body splashes with plenty of water. Inhalation-remove victim to fresh air. Administer artificial respiration if necessary.

REACTIVITY DATA Stability-Stable. Can react with oxidizing materials

Compauibility-Material: May cause rubber to swell.

CarKO: Groop 30 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, face shield al"ld protective clothing. Have all-purpose canister mask available. Secure all soorces of ignition.

If a tpJII

oca~n,

call the National ReapoaM Center, 800-4l4-880l,

206

METHYL TERT-BUTYL ETHER UnUed Nadmq Numbel' ...

Synoay-tert·Butyl methyl ether; MTBE

CHRIS Code •. ~·c

Bonlq Point .. A~~lear.

colOrless liquid; sharp,

Freeziaa: Point ...

terpene-like odor Spec:lfte Gnlrity-0.74 at 20'C

Vapor Pr-.re

ClemJeal F.Uy-Aikyl ethers

_m·F

·c ---·• -109'C ---=.l§!'F

zo·c (68'F> ..

·c ---·•

Reid VlpOJ' Pr-.re (plill)... . _L!_ VllfOI' 1"..- 46'C (115'F) (pU) ..... . Vapor Delll'ty £Air ,.. 1.01 ................... ____a.t_ SohlbilftJ la W.ter .. ComPlete

PoUiltloa Cateaoey-USEPA - - - IMO ----'L_ Applbble Blllk Rea. 46 CPR Sabdaapter ....... _Jl._

F1RE & EXPWSION HAZARD DATA ~:

Aammable liquid

Ehetrkal Grou.-G Geaerai-Fiammabla and, when confined, explosive. Flashback along vapor trail may occur.

-14 (cc) 1.6 to 8.4% 797

Flub. Pobl.t ('F) ..

na...ble Liala .. Alltotpkloa Temp. ('F) .•

Extlftald*ial: Apab .....

Alcohol foam, dry chemical, CO. Cool exposed tanks with water spray.

Spec.WI Fire PfoeediiJ'el ..

HEALTH HAZARD DATA Odor 11arabo&d (ppll) Unavailable

HaJtb. Huard Ratblp Unavailable

PEL/IWA (ppm) UnavaHable

TLV IIWA (pfm)

0.25

General-Not too toxic, similar to gasoline. S,.,._lrritates eyes, akin, mucous membranes. InhalatiOn: For prolonged exposure, coughing, shortness of breath, dizziness, Intoxication. For short exposure, dizziness. Sllort Ex)IOIIIJ'e Toleruce-

ExpoRre Proc:elbuw-lnhalation: Remove to fresh air, give oxygen or artificial respiration as needed. Eyes: Flush with water tor at least 15 minutes, hold eyelids open, call physician. Skin: Wash with water. Ingestion: Do not induce vomiting.

REAcrJVITY DATA Sta11Wt1-Generally stable. Forms peroxides at much slower rate than most ethers. Reacts with mineral acids, organic acids, other oxidizers.

CompadbWty-Material: Compatable with steel, iron, aluminum, copper, magnesium, zinc, neoprene, polyethylene, polypropylene. Incompatible with viton elastomer.

Carp; Group 41 ol compatibility chart. See also Appendix !-Exceptions to the Chart.

SPILL OR LEAK PROCEDURE Stop release, remove aH ignition sources. Dyke to prevent apNI from entering sewers (explosion hazard, poUution) and waterways. Remove spill wtth inert absorbent. Wear goggles or face Shield, boots, and use sell (]*Ia).. _.2&_ Vapor DeuUy (Air = 1.0).. ................... _j.2i.._ Solubility In Water.. at 16'C 6 7%

Chemical Family-Phenol Pollutlot1 Category-USEPA __Q__ IMO ____fL_ Applicable Bulk Rea. 46 CFR SubcUpter ...... _____Q_

at 66'C complete

FIRE & EXPLOSION HAZARD DATA Gnule-E: Combustible ElectrlcaJ Group-O General-When heated, it emits toxic and irritating fumes. Moderate tire hazard when exposed to heat Of !lame.

F1uJa Point ("F) Flammable Limitli .. Autoipition Temp, ("F) . Extlnguiallina A1ents .. Special Ftre Procedures . resprratory protectron should

185 1.710 8.6% 1319 CO., dry chemical, alcohol foam, water fog Where there is danger of skin contact, provide full body protection. Full be wom by fire parties at all times.

HEALTH HAZARD DATA Health HII.ZIIrd Ratings 2. 3, 3

PEL/TWA (ppm) 5/Skin

Odor Thrallold (ppm) 0.047

TLV!TWA (ppm) 5/Skin

General-Causes severe bums. Poisonous by skin absorption. Class B poison.

Symptoms-Headache, weakness, ringing of the ears, and irregular breathing. Skin contact will cause white, wrrnkled. soft sk1n at site of contact. Absorption through skin is rapid and can cause death within 30 minutes alter exposure Short f:xprniure Tolerance-Unavatlable Exposur~ Procedures-Vapor-remove victim to fresh air: if breathing stops, apply artificial respiration. Skin or

eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Ge1 v1ct1m to a hospital or treatment center as soon as possible. All exposure victims should get medical a"ent1on

REACI'IVITY DATA Stability-Stable.

Compatibility-Material: Rubber, aluminum and its alloys, zinc and lead are allacked by phenol.

Cargo: Group 21 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Do not permit anyone near spill unless suitably protected.

If a spill oc:cun, caU the National RetpOn.e Ceater, 1100-4l4-810l. Remarks: Normally transported at elevated temperatures. See 46 CFR 36-Eievated Temperature Cargoes. • Vapor Pressure: 30.6 mmHg at 25"C.

240

PHOSPHORIC ACID SyDOayms- Metaphosphoric acid; Orthophosphoric acid; meta-Phosphoric acid; ortho-Phosphoric acid;

United Natlont Nu111ber ...

White phosphoric acid

CHRIS Code ...

Fonnula-H,PO, Appeanmee-Odor-Ciear. syrupy liquid; practically odorless

___., ___.,

Boillq Point..

~·F

Free:dlla PoiDt ..

____j_Qj!•F

Vapor Pretllllf'e :zo·c (68'F> (mmlfa) .. Reid Vapor Prelsure (Pilla) ... Vapor f're.lli'C! 46'C (115'F) (peUI) .. Vapor Density (Air = t,O) .. Solubility iD Water ..

___LQlL_ ___LQlL_ ___LQlL_

Specific Gravity-1.83 Chemical FIUilily-lnorganic acid

Pollution Category-USEPA ____Q__ IMO ____Q__ Applicable Bulk Reg. 46 CFR Subehapter ...... ____Q__

__ilL Complete

FIRE & EXPLOSION HAZARD DATA Grade-Non-flammable. Classified as corrosive liquid. Electrlclll. Group-S (based upon possible hydrogen gas (H$) generation shoold a leak or spill occur) Gellera1-Phosphoric acid will not bum. tt will react with many metals, giving off hydrogen gas which is highly

flammable. If hydrogen is trapped in a confined space, it can form an explosive mixture with air. See data sheet for hydrogen. Flub PoJnt ('F) .. Non-flammable Flammable Undts .. Non-flammable Autoignition Temp, ("F) ... Non-flammable Elr:tlnplsbing Agents .. Non-flammable Keep tank cool with water spray. Since toxic fumes of oxides of phosphorous Special Fire Proeediii1!S ... are evolved when phosphoric acid is heated to decomposition, fire fighters should be provided with self-contained breathillQ apparatus.

HEALTH HAZARD DATA Healtll Hazard Ratlnp 0, 3, 1

PEL/TWA (ppm) 1 mg/m"

Odor 1'1u-e.bold {ppm)

Nooo

nvnwA CPfllll) 1 mg/m 3

General-Causes burns.

Symptoms-Irritation of skin in contact with liquid; burnillQ of eyes. Short Expoaure Tolerance-Unavailable

Expo~~w-e

Proc:edures-Skin contact-remove contaminated clothillQ and flush affected areas gently with large amounts of water. Eye contact-immediately flush eyes gently with water; continue to flush for 15 minutes. Get medical attention.

REACTIVITY DATA Stability-Stable over a wide temperature range

Compatibility-Material: V9f'/ corrosive to ordinary ferrous metals and alloys particularly at temperatures above 160"F. Cargo: Group 1 of compatibility chart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, protective clothing. Have body shield available. Avoid contact with liquid. Secure ignition sources. Flush spills with large amounts of water or, if possible, COV9f contaminated surface and spill with sodium bicarbonate, or a soda ash-slaked lime mixture (5Q-50). Mix and add water, If necessary to form a slurry. Scoop up slurry. Wash site with soda ash solution. In the neat of a IQjOl" spiU. eall the Nau-t Rnpo~~M Center, 800-4l4-810l. Remarks: The information provided is for 100% phosphoric acid.

241

PHOSPHORUS (White) United Natlo... Number ...

5)'11011flll8- White phosphorus: WP; Yellow phosphorus

CHRIS Code ...

_,

BoU1a1 PoUlt...

Appearllllce-Odor-Waxy, pale-yellow solid; garlic-like

Freezi•l Pofat..

Specific Gra'fity-1.82

--..2Zi'C ~'F ·c 'F ____M'C ___.lll'F ___·c ___.F

Vapor ~re :zo•c (68'F> (DunH&).. ~ Reid V~~p~~r Preuun (pN.).... ~ Vapor ~re 46'C (115'F) (pala).. ~ Vapor Denalty (Air = 1.0).. ........................ ~ SolubUity In Water.. Nag!jglblo

Pollutfoa Catei}Ory-USEPA ____x__ IMO ----A_ AppJh:able Bulk Res;. 46 CFR Subcbpter ..... __Q__

FIRE & EXPLOSION HAZARD DATA Grade-Pyrophoric solid EJeetrical Group--NA Generai-Pyrophoric-ignites spontaneously when exposed to air and burns vigorously. When shipped In bulk, air is kept away by a water blanket. Burning releases dense irritating fumes; intense white smoke Is fonned. F1uh Point ('F') .. Ignites spontaneously in air Flammable Limits Ignites spontaneously in air Autoignition Temp. ('F) .. 86 E:ottingui!hing Agenb .. EXCLUDE AIR: use water spray, sand, or earth Special Fire Procedures. Use suitable respiratory protection. DO NOT use high-pressure water stream. as it may spread molten phosphorus over a wider area. Do not use carbon dioxide e)(tingulaher. Try to smother ·,n lne with sand. Wear full protective clothing.

HEALTH HAZARD DATA Odor Tbrabold

Health Hazard R1tings NA. 4, 4

(pplll)

Unavailable

PEL/IWA (ppm)

nvnwA (plfa)...

v.,..

Polludoa CateaorY-USEPA·--- IM().___liL_ A..,Ibble Balk Rea. 46 CFR Sabdaapter ....... ___D__

Deuif;J (Air = 1.0).. SolublUty bl Waer .......

===·F - ..

FIRE .t EXPLOSION HAZARD DATA

General-Mild fire hazard when exposed to heat or flame. 215 to 470 Unavailable Unavailable CO:!, dry chemical or foam Water may be Ineffective on fire. Cool exposed tanks with

('F) •.

na-aa.~cl..bail8

........

r-.. 3% ortho

Sfllony11111- o-Cresyl phosphate; Phosphoric acid, tris(methy1phenyl)ester; TCP; TOCP;

~

Tolylphosphate; Tri-o.cresyl phosphate; Tri-o-tolyl phosphate: Tritolyl phosphate

CHRIS Code ............